全文获取类型
收费全文 | 478篇 |
免费 | 5篇 |
国内免费 | 1篇 |
专业分类
化学 | 252篇 |
晶体学 | 2篇 |
力学 | 48篇 |
数学 | 87篇 |
物理学 | 95篇 |
出版年
2020年 | 9篇 |
2019年 | 5篇 |
2018年 | 5篇 |
2017年 | 7篇 |
2016年 | 8篇 |
2015年 | 5篇 |
2014年 | 3篇 |
2013年 | 22篇 |
2012年 | 18篇 |
2011年 | 31篇 |
2010年 | 14篇 |
2009年 | 9篇 |
2008年 | 18篇 |
2007年 | 10篇 |
2006年 | 19篇 |
2005年 | 20篇 |
2004年 | 21篇 |
2003年 | 14篇 |
2002年 | 51篇 |
2001年 | 20篇 |
2000年 | 22篇 |
1998年 | 5篇 |
1997年 | 9篇 |
1996年 | 7篇 |
1995年 | 10篇 |
1994年 | 3篇 |
1993年 | 5篇 |
1992年 | 6篇 |
1991年 | 5篇 |
1990年 | 5篇 |
1989年 | 4篇 |
1988年 | 3篇 |
1987年 | 4篇 |
1985年 | 8篇 |
1984年 | 4篇 |
1983年 | 2篇 |
1982年 | 4篇 |
1981年 | 11篇 |
1980年 | 8篇 |
1979年 | 6篇 |
1978年 | 2篇 |
1977年 | 2篇 |
1976年 | 6篇 |
1974年 | 4篇 |
1973年 | 4篇 |
1971年 | 4篇 |
1969年 | 3篇 |
1968年 | 2篇 |
1966年 | 2篇 |
1965年 | 2篇 |
排序方式: 共有484条查询结果,搜索用时 15 毫秒
41.
MD. Daloar Hossain Le Thi Bao Tran Jong Myung Park Kwon Taek Lim 《Journal of polymer science. Part A, Polymer chemistry》2010,48(22):4958-4964
A new, efficient method for synthesizing stable nanoparticles with poly(ethylene oxide) (PEO) functionalities on the core surface, in which the micellization and crosslinking reactions occur in one pot, has been developed. First, amphiphilic PEO‐b‐PS copolymers were synthesized by reversible addition fragmentation chain transfer (RAFT) radical polymerization of styrene using (PEO)‐based trithiocarbonate as a macro‐RAFT agent. The low molecular weight PEO‐b‐PS copolymer was dissolved in isopropyl alcohol where the block copolymer self‐assembled as core‐shell micelles, and then the core‐shell interface crosslink was performed using divinylbenzene as a crosslinking agent and 2,2′‐azobisisobutyronitrile as an initiator. The design of the amphiphilic RAFT agent is critical for the successful preparation of core‐shell interface crosslinked micellar nanoparticles, because of RAFT functional groups interconnect PEO and polystyrene blocks. The PEO functionality of the nanoparticles surface was confirmed by 1H NMR and FTIR. The size and morphology of the nanoparticles was confirmed by scanning electron microscopy, transmission electron microscopy, and dynamic laser light scattering analysis. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2010 相似文献
42.
MD. Anwarul Hasan Carlos F. Lange Malcolm L. King 《ournal of non Newtonian Fluid Mechanics》2010,165(21-22):1431-1441
The effect of viscoelastic properties and surface tension of artificial mucus simulant samples on the size distribution and volume concentration of bioaerosol droplets generated during simulated coughing was investigated through in vitro experiments. The mucus simulant samples had viscoelastic properties in a similar range as those of real human airway mucus. The mucus simulant gels were prepared by mixing various proportions of 0.5–1.7% locust bean gum solution and 0.1 M sodium tetraborate (XLB) solution. Surface tension of one set of samples was varied by adding different amounts of SDS (sodium dodecyl sulfate) surfactant while the measurement of surface tension was performed using ADSA (axisymmetric drop shape analysis) method. The viscoelastic properties of the samples were measured using a Bohlin Gemini 200 HR (Malvern, UK) nano-rheometer with peltier plate assembly. An artificial cough machine was used to simulate human cough, generating aerosol droplets in a model trachea attached to the front of the cough machine. The size distribution and volume concentration of the droplets generated through simulated cough were measured using a laser diffraction particle sizer (SprayTec, Malvern, USA). The surface tension was found to have negligible effect on the characteristic of generated droplets within the range of this investigation. The experimental results showed a decrease in particle size as the samples changed from a viscous fluid type to a viscoelastic to an elastic solid type sample. The volume concentration also changed significantly as the viscoelasticity of the samples was varied. 相似文献
43.
We consider the onset of convection in an inclined anisotropic porous layer heated from below. To date the principle axes
of the permeability and diffusivity tensors have been assumed to be aligned with the coordinate directions. Therefore particular
emphasis is laid upon how the basic flow and criteria for the onset of convection are altered by the presence of oblique principle
axes. When these axes are not aligned with the coordinate directions and when the ratios of the principle permeabilities or
diffusivities are not too large or too small, we find that there is always a smooth transition in the orientation of the most
dangerous mode of instability as the inclination increases from the horizontal. In more extreme cases there may be sudden
changes in the orientation, Darcy–Rayleigh number and wavenumber. 相似文献
44.
It is well known that the onset of convection in an inclined porous layer heated from below takes the form of longitudinal
vortices when Darcy’s law is valid. In this paper we consider briefly how the onset criterion alters when form drag, as modelled
by the Forchheimer terms, is significant. In general, the critical Rayleigh number increases substantially as form drag effects
strengthen, but the wavenumber rises by only a small amount. This numerical study is supplemented by a brief asymptotic analysis
of the case when the Forchheimer terms dominate and it is shown that the critical Rayleigh number increases in direct proportion
with the form drag parameter. 相似文献
45.
This paper presents a study of velocity fluctuations occurring in the stably stratified atmospheric boundary layer over an Antarctic ice shelf. The approach is based on wavelet analysis which has advantages over conventional Fourier analysis. Two case studies are presented, comprising: pure turbulent flow and a large amplitude solitary wave. 相似文献
46.
47.
Williams GR Moorhouse SJ Prior TJ Fogg AM Rees NH O'Hare D 《Dalton transactions (Cambridge, England : 2003)》2011,40(22):6012-6022
This paper reports a number of recent developments in the intercalation chemistry of Al(OH)(3). From Rietveld refinement and solid-state NMR, it has been possible to develop a structural model for the recently reported [M(II)Al(4)(OH)(12)](NO(3))(2)·yH(2)O family of layered double hydroxides (LDHs). The M(2+) cations occupy half of the octahedral holes in the Al(OH)(3) layers, and it is thought that there is complete ordering of the metal ions while the interlayer nitrate anions are highly disordered. Filling the remainder of the octahedral holes in the layers proved impossible. While the intercalation of Li salts into Al(OH)(3) is facile, it was found that the intercalation of M(II) salts is much more capricious. Only with Co, Ni, Cu, and Zn nitrates and Zn sulfate were phase-pure LDHs produced. In other cases, there is either no reaction or a phase believed to be an LDH forms concomitantly with impurity phases. Reacting Al(OH)(3) with mixtures of M(II) salts can lead to the production of three-metal M(II)-M(II)'-Al LDHs, but it is necessary to control precisely the starting ratios of the two M(II) salts in the reaction gel because Al(OH)(3) displays selective intercalation of M nitrate (Li > Ni > Co ≈ Zn). The three-metal M(II)-M(II)'-Al LDHs exhibit facile ion exchange intercalation, which has been investigated in the first energy dispersive X-ray diffraction study of a chemical reaction system performed on Beamline I12 of the Diamond Light Source. 相似文献
48.
A new nonlinear evolution equation is derived for surface solitary waves propagating on a liquid-air interface where the wave motion is induced by a harmonic forcing. Instead of the traditional approach involving a base state of the long wave limit, a base state of harmonic waves is assumed for the perturbation analysis. This approach is considered to be more appropriate for channels of length just a few multiples of the depth. The dispersion relation found approaches the classical long wave limit. The weakly nonlinear dispersive waves satisfy a KdV-like nonlinear evolution equation with steeper nonlinearity. 相似文献
49.
The Platt electrostatic model of a diatomic hydride is modified by the introduction of a scale factor which depends on the internuclear distance. This has the theoretical advantage of enabling the molecular virial theorem to be satisfied and the practical advantage, as shown by some examples, of improving the agreement with experiment particularly for the lighter molecules. The calculation of the scale factor requires two more integrals but the equilibrium internuclear distance and the force constant can still be interpreted electrostatically. 相似文献
50.
The cellular structure of Norway spruce (Picea abies) was transformed via a simple, single‐step carbonization process into a carbon monolith with molecular‐sieve properties. The monolith exhibited a genuine honeycomb structure derived from the original intrinsic H2O channels of the wood. The micropores formed during carbonization from the walls of the channels were shown to have a high adsorption capacity. The honeycomb monolith was tested for air separation. Micropore diffusion of N2 and O2 was found by the frequency‐response (FR) technique to be the rate‐controlling process of mass transport. 相似文献