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11.
Kristian K. Müller-Nedebock Shaul M. Aharoni Sam F. Edwards 《Macromolecular Symposia》1995,98(1):701-717
Networks of rigid molecules do not fit into the paradigm of classical theories of rubber elasticity. Some experimental properties of rigid polyamide networks are summarised, and the basis for a theoretical understanding of such systems is discussed and elaborated in terms of the properties such as the existence of several conformational states and twist of such network elements. 相似文献
12.
Margaux Fresnais Seda Karabulut Yasmin Abou Zeed Johannes Ungermann Julia Benzel Kristian W. Pajtler Stefan M. Pfister Walter E. Haefeli Jürgen Burhenne Rmi Longuespe 《Molecules (Basel, Switzerland)》2022,27(3)
Desorption/ionization mass spectrometry (DI-MS) approaches allow for the rapid quantification of drugs in biological matrices using assays that can be validated according to regulatory guidelines. However, specific adaptations must be applied to create reliable quantification methods, depending on the approach and instrumentation used. In the present article, we demonstrate the importance of the molecular weight, the fragmentation pattern, and the purity of the internal standard for the development of matrix-assisted laser desorption/ionization (MALDI)-ion mobility (IM)-tandem MS and MS/MS methods. We present preliminary results of method development for the quantification of selinexor in microdialysis fluids with a stable isotopically labeled internal standard. In addition, we discuss the selection of internal standards for MALDI-MS assays using different instrumentations. 相似文献
13.
In this paper, we present a framework to construct general stochastic Runge–Kutta Lawson schemes. We prove that the schemes inherit the consistency and convergence properties of the underlying Runge–Kutta scheme, and confirm this in some numerical experiments. We also investigate the stability properties of the methods and show for some examples, that the new schemes have improved stability properties compared to the underlying schemes.
相似文献14.
The polynomial associated with the largest disk of stability of anm-stage explict Runge-Kutta method of orderp is unique. 相似文献
15.
Rocha-Rinza T Sneskov K Christiansen O Ryde U Kongsted J 《Physical chemistry chemical physics : PCCP》2011,13(4):1585-1589
Using advanced QM/MM methods, the surprisingly negligible shift of the lowest-lying bright electronic excitation of the deprotonated p-coumaric acid (pCA(-)) within the photoactive yellow protein (PYP) is shown to stem from a subtle balance between hypsochromic and bathochromic effects. More specifically, it is found that the change in the excitation energy as a consequence of the disruption of the planarity of pCA(-) inside PYP is nearly canceled out by the shift induced by the intermolecular interactions of the chromophore and the protein as a whole. These results provide important insights about the primary absorption and the tuning of the chromophore by the protein environment in PYP. 相似文献
16.
Lubomír Lap?ík Barbora Lap?íková Ivo Krásny Ivana Kupská Richard W. Greenwood Kristian E. Waters 《Plasma Chemistry and Plasma Processing》2012,32(4):845-858
It was found in this study that the air plasma treatment of particular kaolinite has led to the change of its wettability, which was reflected in the decreased values of water contact angles of wetting from 88.7° for virgin kaolinite to 86.3° for 30?min air plasma treated one. Plasma treated samples show higher average surface energies in the wide range of coverage regimes in comparison to the virgin samples as determined by inverse gas chromatography. Results of these measurements confirmed our assumption, that air plasma treatment activates surface energy of the crystal planes of the kaolinite as reflected in the broadened dispersive surface energy distribution after 10?min treatment time. However with prolonged 30?min treatment time the dispersive surface energy distribution profile was decreased. We assume, that the latter decrease reflects the distorsion of the crystal lattice of the kaolinite as confirmed by FTIR analysis as reflected in changes of Si?CO?CSi and Al2O?CH characteristic absorption bands. Calculated dispersive surface free energy for 24?% surface coverage was increased from original 35?mJ/m2 to 40.3 and 40.8?mJ/m2 for 10 and 30?min treatment times. There were determined yield locus and flow function dependencies at different stress levels for virgin and different time plasma treated samples (flow index??ff c , effective angle of internal friction???? e , unconfined yield strength???? c ). It was found that by plasma treatment the character of the flow was shifting from region of very cohesive (ff c ?=?2.39) to the cohesive (ff c ?=?3.19). For untreated samples effective angle of internal friction was decreased with increasing applied consolidation stress, while for plasma treated kaolinite it was increased. 相似文献
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19.
Diana Lindberg Kenneth Aase Kristoffersen Sileshi Gizachew Wubshet Linn Maria Gundersen Hunnes Marte Dalsnes Katinka Riiser Dankel Vibeke Hst Nils Kristian Afseth 《Molecules (Basel, Switzerland)》2021,26(17)
A study of the effects of single and combined protease hydrolysis on myofibrillar versus collagenous proteins of poultry by-products has been conducted. The aim was to contribute with knowledge for increased value creation of all constituents of these complex by-products. A rational approach was implemented for selecting proteases exhibiting the most different activity towards the major protein-rich constituents of mechanically deboned chicken residue (MDCR). An initial activity screening of 18 proteases on chicken meat, turkey tendons and MDCR was conducted. Based on weight yield, size exclusion chromatography (SEC) and SDS-PAGE, stem Bromelain and Endocut-02 were selected. Studies on hydrolysis of four different poultry by-products at 40 °C, evaluated by protein yield, SEC, and SDS-PAGE, indicate that the proteases’ selectivity difference can be utilized in tailor-making hydrolysates, enriched in either meat- and collagen-derived peptides or gelatin. Three modes of stem Bromelain and Endocut-02 combinations during hydrolysis of MDCR were performed and compared with single protease hydrolysis. All modes of the protease combinations resulted in a similar approximately 15% increase in product yield, with products exhibiting similar SEC and SDS-PAGE profiles. This shows that irrespective of the modes of combination, the use of more than one enzyme in hydrolysis of collagen-rich material can provide means to increase the total protein yield and ultimately contribute to increased value creation of poultry by-products. 相似文献
20.
Raman spectroscopy has been evaluated for characterisation of the degree of fatty acid unsaturation (iodine value) of salmon (Salmo salar). The Norwegian Quality Cuts from 50 salmon samples were obtained, and the samples provided an iodine value range of 147.8-170.0 g I2/100 g fat, reflecting a normal variation of farmed salmon. Raman measurements were performed both on different spots of the intact salmon muscle, on ground salmon samples as well as on oil extracts, and partial least squares regression (PLSR) was utilised for calibration. The oil spectra provided better iodine value predictions than the other data sets, and a correlation coefficient of 0.87 with a root mean square error of cross-validation of 2.5 g I2/100 g fat was achieved using only one PLSR component. The ground samples provided comparable results, but at least two PLSR components were needed. Higher prediction errors were obtained from Raman spectra of intact salmon muscle, and this may partly be explained by sampling uncertainties in the relation between Raman measurements and reference analysis. All PLSR models obtained were based on chemically sound regression coefficients, and thus information regarding fatty acid unsaturation is readily available from Raman spectra even in systems with high contents of protein and water. The accuracy, the robustness and the low complexity of the PLSR models obtained suggest Raman spectroscopy as a promising method for rapid in-process control of the degree of unsaturation in salmon samples. 相似文献