The rhodium-catalyzed addition of arylboronic acids to N-Boc imines generated in situ from stable and easily prepared alpha-carbamoyl sulfones has been developed. High enantioselectivities are observed for additions of arylboronic acids with a variety of steric and electronic properties. 相似文献
We present a design study of 3D photonic poly‐Si microarchitectures on 2 µm periodically textured glass substrates for application as absorber layers in crystalline Si thin‐film solar cells. Different arrays of microholes and microcones were fabricated in a low‐cost process, by combining high rate electron beam evaporation, nanoimprint technology and self‐organized solid phase crystallization. Two promising designs exhibiting strong absorption enhancement were identified by optical analysis. High angular acceptance and calculated maximum achievable short‐circuit current density of 27.6 mA/cm2 for an effective Si thickness of 1.1 µm highlight the optical potential of these microarchitectures as broadband absorbers in polycrystalline Si thin‐film solar cells.
We investigate the characteristics of intra‐grain and grain boundary defects in polycrystalline Si films, by employing quantitative electron paramagnetic resonance measurements on liquid phase crystallized layers with an average grain size of 200 µm and tailored solid phase crystallized Si layers with similar intra‐grain morphology but systematically varied grain sizes between 0.25 µm and 1 µm. The defect characteristics are found to be composed of two distinctive g ‐values of g = 2.0055 and 2.0032, which are attributed to grain boundary defects and intra‐grain defects, respectively. Additional hydrogenation leads to a reduction of the overall defect concentration, while a rapid thermal annealing process primarily heals intra‐grain defects.
We investigate changes in periodicity, and even its suppression, by external periodic forcing in different two-dimensional maps, namely the Hénon map and the sine square map. By varying the amplitude of a periodic forcing with a fixed angular frequency, we show through numerical simulations in parameter-spaces that changes in periodicity may take place. We also show that windows of periodicity embedded in a chaotic region may be totally suppressed. 相似文献
Paramagnetic coordination defects in undoped hydrogenated amorphous silicon (a-Si:H) are studied using multifrequency pulsed electron-paramagnetic resonance (EPR) spectroscopy at S-, X-, Q- and W-band microwave frequencies (3.6, 9.7, 34, and 94 GHz, respectively). The improved spectral information extractable from a multifrequency fitting procedure allows us to conclude that the g tensor exhibits a rhombic splitting instead of axial symmetry. Our methods allow for precise and accurate determination of the g tensor principal values gx = 2.0079(2), gy = 2.0061(2) and gz = 2.0034(2) and their distribution parameters (g strain). 相似文献
This paper reports on numerically computed parameter plane plots for a dynamical system modeled by a set of five-parameter, four autonomous first-order nonlinear ordinary differential equations. The dynamical behavior of each point, in each parameter plane, is characterized by Lyapunov exponents spectra. Each of these diagrams indicates parameter values for which hyperchaos, chaos, quasiperiodicity, and periodicity may be found. In fact, each diagram shows delimited regions where each of these behaviors happens. Moreover, it is shown that some of these parameter planes display organized periodic structures embedded in quasiperiodic and chaotic regions. 相似文献