Dendritic structures of poly(ethylene glycol) on silicon nitride and gold surfaces

A hydrophilic silicon nitride surface was grafted with poly(ethylene glycol) monomethyl ether (average formula weight of 5000 Da) in a one-step protocol. The domains of stable dendritic structures of self-assembled monolayer islands on a silicon nitride surface were observed with atomic force microscopy. The moduli of elasticity of these dendritic structures in air and in KCl aqueous solution were compared. The value of the Young's modulus of these structures is reduced by more than 3 orders of magnitude, from approximately 12 GPa measured in air to approximately 5 MPa in KCl solution. This dramatic reduction in elasticity was attributed to the swelling of the dendritic structures in aqueous solution, which was verified by the increased film thickness. These dendritic structures were not stable in the aqueous environment and could be removed by soaking in water for 22 h because of the hydrolysis of the silicate bonds. This fact was confirmed by the reduction of the C1s signal in the X-ray photoelectron spectroscopy experiments. These morphologies are not unique to silicon nitride substrate; similar features were also observed for thiolated poly(ethylene glycol) monomethyl ether molecules absorbed on a gold surface.     

Transition metal ions in black tea: an electron paramagnetic resonance study

Tea (Camellia Sinensis) is the most widely consumed beverage in the world and is known to have therapeutic, antioxidant and nutritional effects. It contains dimeric flavanols and polyphenols which are known as the most important organic compounds in tea infusions, and can make strong and stable complexes with metal ions. In this study, we carried out a series of electron paramagnetic resonance experiments on well-known paramagnetic transition metal ions, namely Mn²⁺, Fe³⁺, Cu²⁺, VO²⁺, and Cr³⁺ doped in black tea cultivated along the shore of Black Sea, Turkey, to see the effects and structures formed.     

Combining Step-Growth and Chain-Growth Polymerizations in One Pot: Light-Induced Fabrication of Conductive Nanoporous PEDOT-PCL Scaffold

A novel method based on light-induced fabrication of a poly (3,4-ethylenedioxythiophene)-polycaprolactone (PEDOT-PCL) scaffold using phenacyl bromide (PAB) as a single-component photoinitiator is presented. HBr released from the step-growth polymerization of EDOT is utilized as an in situ catalyst for the chain-growth polymerization of ε-caprolactone. Detailed investigations disclose the formation of a self-assembled nanoporous electroconductive scaffold (1.2 mS cm⁻¹). Fluorescence emission spectra of the fabricated scaffold exhibit a mixed solvatochromic behavior, indicating specific interactions between the self-assembled scaffold and solvents with varying polarities, as evidenced by transmission electron microscopy (TEM). Moreover, the same light-induced technique can also be applied for bulk photopolymerization showcasing the versatility and wide-ranging scope of the originated method. In brief, this study introduces a novel approach for light-induced polymerization reactions that is merging step-growth and chain-growth mechanisms. This innovative approach is promising to facilitate in situ polymerization of monomers possessing diverse functionalities.