全文获取类型
收费全文 | 582篇 |
免费 | 40篇 |
国内免费 | 17篇 |
专业分类
化学 | 473篇 |
晶体学 | 3篇 |
力学 | 19篇 |
数学 | 44篇 |
物理学 | 100篇 |
出版年
2024年 | 1篇 |
2023年 | 2篇 |
2022年 | 15篇 |
2021年 | 17篇 |
2020年 | 27篇 |
2019年 | 31篇 |
2018年 | 39篇 |
2017年 | 26篇 |
2016年 | 55篇 |
2015年 | 33篇 |
2014年 | 51篇 |
2013年 | 79篇 |
2012年 | 45篇 |
2011年 | 42篇 |
2010年 | 41篇 |
2009年 | 20篇 |
2008年 | 29篇 |
2007年 | 16篇 |
2006年 | 17篇 |
2005年 | 11篇 |
2004年 | 12篇 |
2003年 | 8篇 |
2002年 | 11篇 |
2001年 | 1篇 |
2000年 | 1篇 |
1998年 | 1篇 |
1993年 | 3篇 |
1992年 | 2篇 |
1990年 | 1篇 |
1986年 | 1篇 |
1981年 | 1篇 |
排序方式: 共有639条查询结果,搜索用时 343 毫秒
71.
A novel SBA-15-functionalized TEMPO confined ionic liquid [BMIm]Br was found to be a highly efficient and recyclable catalyst system for the transition-metal-free aerobic oxidation of a wide range of structurally diverse alcohols. Thanks to the strong physical confinement of the ionic liquid inside the mesochannels of SBA-15-supported TEMPO, the resulting solid catalyst showed improved selectivity in the aerobic oxidation of allylic alcohols. The catalyst can be recovered and re-used for at least 11 reaction runs without significant loss of either activity or confined IL. 相似文献
72.
Cyclofusene is a corona-condensed benzenoid whose graph-theoretic representation consists of hexacycles each having exactly two non-adjacent shared edges. Multilayered cyclofusene is a fused hexacylic system which can be partitioned into successive layers of cyclofusene. In such systems, an edge shared by two consecutive hexacycles in the same layer is termed radial. We present upper bounds for the number of radial π-bonds in a convex k-layered cyclofusene. 相似文献
73.
M. Karimi N. Granpayeh M.K. Morraveg Farshi 《Applied physics. B, Lasers and optics》2004,78(3-4):387-396
A rhodamine-B-doped polymer optical fiber amplifier (RBDPOFA) has been successfully fabricated and tested. In this paper, all parameters affecting the gain of the RBDPOFA are recognized. The time-dependent and time-independent rate equations are solved. By using Runge–Kutta and finite-element methods, different conditions are described and fluctuations of the fiber laser are analyzed. From the time-dependent rate equations, the gain and level-density variations with time can be predicted. These fiber amplifiers have unstable conditions. In experiments, the decay of dye dopants in the high pump power regime has been observed. For example, in a high pump power rhodamine-B is converted from the zwitterion isomer to the colorless lactone isomer [1]. Therefore, for complete coincidence of theoretical and experimental results, this effect must be included in the analysis, which is however beyond the scope of this paper and will be discussed in the near future. PACS 42.60.Da; 42.81.Wg; 31.15.Fx; 33.80.-b; 42.55.WdAn erratum to this article can be found at 相似文献
74.
Functionalization of gold cysteamine (Au? CA) self‐assembled monolayer with 4‐formylphenylboronic acid (BA) via Schiff's base formation, through in situ method to fabricate Au‐CA‐BA electrode is presented and described. The fabricated electrode was used as a novel sensor for accumulation and determination of dopamine (DA). The accumulation of DA as a diol on the topside of Au‐CA‐BA as a Lewis acid, was performed via esterification (Au? CA? BA? DA), and followed for determination of DA. Functionalization, characterization, and determination steps were probed by electrochemical methods like cyclic voltammetry and electrochemical impedance spectroscopy. The data will be presented and discussed from which a new sensor for DA is introduced. 相似文献
75.
This paper presents a chaos synchronization method for a class of uncertain chaotic systems using the combination of an optimal control theory and an adaptive strategy. A quadratic optimal regulator and an adaptive control are used to represent the controller's structure. The asymptotic stability of the corresponding error dynamical system is guaranteed through Lyapunov stability analysis. The proposed controller is employed in two uncertain chaotic Lu systems, and their promising performances are illustrated. 相似文献
76.
77.
78.
The linear and the nonlinear intersubband optical absorption in the symmetric double semi-parabolic quantum wells are investigated for typical GaAs/AlxGa1−xAs. Energy eigenvalues and eigenfunctions of an electron confined in finite potential double quantum wells are calculated by numerical methods from Schrödinger equation. Optical properties are obtained using the compact density matrix approach. In this work, the effects of the barrier width, the well width and the incident optical intensity on the optical properties of the symmetric double semi-parabolic quantum wells are investigated. Our results show that not only optical incident intensity but also structure parameters such as the barrier and the well width really affect the optical characteristics of these structures. 相似文献
79.
Cascade parametric amplification in a regular domain structure is examined theoretically taking the variations in phase of
all the interacting waves in a dissipative medium into account. Analytic expressions are obtained for the conversion efficiency
of the laser energy with low-frequency pumping. The dependence of the parametric amplification efficiency on the number of
layers is given. Ways of increasing the frequency conversion efficiency are discussed. The presence of a nonzero input intensity
at the sum frequency is found to cause a nonlinear increase in the high-frequency signal at the output of the structure. As
the losses of the interacting waves increase, both the frequency conversion efficiency and the optimum domain length decrease. 相似文献
80.