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991.
Gianluigi Luppi Rodrigo J. Corrêa Angelo C. Pinto Quirinus B. Broxterman Claudia Tomasini 《Tetrahedron》2006,62(51):12017-12024
The first total synthesis of (R)-convolutamydine A has been achieved by the organocatalytic addition of acetone to 4,6-dibromoisatin. The absolute configuration was determined by single crystal X-ray diffraction. DFT studies were used to model the transition states for the aldol reaction and equilibrium geometries of the post-aldol reaction intermediates. The DFT study revealed that the aldol bond forming reaction was considerably endothermic. 相似文献
992.
In this paper, we re-examine a series of gedanken welcher Weg (WW) experiments introduced by Scully, Englert and Walther that contain the essential ideas underlying the quantum eraser. For this purpose we use the Bohm model which gives a sharp picture of the behaviour of the atoms involved in these experiments. This model supports the thesis that interference disappears in such WW experiments, even though the centre of mass wave function remains coherent throughout the experiment. It also shows exactly what it means to say ‘that the interference can be restored by manipulating the WW detectors long after the atoms have passed’. It does not support Wheeler’s notion that ‘the past is undefined and undefinable without the observation (in the present)’. 相似文献
993.
F.J. Olmo A. Quirantes A. Alcntara H. Lyamani L. Alados-Arboledas 《Journal of Quantitative Spectroscopy & Radiative Transfer》2006,100(1-3):305-314
There is experimental evidence that the non-sphericity of certain atmospheric particles can cause scattering properties different from those predicted by standard Mie theory. Numerous studies indicate the need to consider the presence of non-spherical particles in modeling the optical properties of atmospheric aerosols. On the other hand, natural aerosols show a great variety of shapes, making difficult a realistic choice of a particle shape (or shape mixture) model. In this paper, we test a parameterization of the particle shape in the retrieval of size distribution, phase function, single scattering albedo and asymmetry parameter from direct and sky-radiance measurements. For this purpose we have substituted the Kernel based on the Mie theory included in the model SKYRAD.PACK by one derived for non-spherical particles. The method is applied under different atmospheric conditions, including Saharan dust outbreak, polluted and local mineral episodes. We compare the results with those obtained by the well known spheroids algorithm used in the AERONET network. 相似文献
994.
995.
J. Freudenberger 《Discrete Applied Mathematics》2006,154(2):294-304
We consider bounded distance list decoding, such that the decoder calculates the list of all codewords within a sphere around the received vector. We analyze the performance and the complexity of this suboptimum list decoding scheme for the binary symmetric channel. The reliability function of the list decoding scheme is equivalent to the sphere-packing bound, where the decoding complexity is asymptotically bounded by 2nR(1-R). Furthermore, we investigate a decision feedback strategy that is based on bounded distance list decoding. Here, any output with zero or many codewords will call for a repeated transmission. In this case the decoding complexity will be of the order 2nR(1-C), where C denotes the channel capacity. The reliability function is close to Forney's feedback exponent. 相似文献
996.
The von Neumann cellular automaton appears in many different settings in Operations Research varying from applications in Formal Languages to Biology. One of the major questions related to it is to find a general condition for irreversibility of a class of two-dimensional cellular automata on square grids (σ+-automata). This question is partially answered here with the proposal of a sufficient condition for the irreversibility of σ+-automata. 相似文献
997.
It is shown that the condition υ > υp (ω), which is necessary in order to trigger the Vavilov-Cherenkov effect, determines the interval of radiated frequencies
and it alone cannot establish a strong restriction to the velocity of the particle. It is exhibited that it is possible to
define a general lower bound for the velocity of the particle, which does not depend on the frequency when both, a specific
response of the medium is taken into account and the mentioned condition is considered. The minimum value of the phase velocity
of light in the medium determines the existence of such general lower bound. 相似文献
998.
For the methylsilsesquioxane film whose optical birefringence is almost zero, it was recently reported that its vertical thermal expansion coefficient (CTE) was approximately one order of magnitude larger than the lateral CTE. Though the birefringence is not an absolute predictor of anisotropic behavior, the discrepancy in both the CTEs was so remarkable that it was essential to investigate whether the anisotropy was intrinsic property or not. If the effect of Poisson's ratio is considered in the calculation of the vertical CTE and when elastic modulus measured by surface acoustic wave spectroscopy is used in the assessment of the lateral CTE, both the CTEs are coincident with each other. Therefore, it can be concluded that the discrepancy in the CTEs can be attributed to a higher in‐plane polymer chain orientation but it can also arise from the misleadingly assumed modulus and Poisson's ratio. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 3109–3120, 2006 相似文献
999.
A new method for one-electron propagator calculations of molecular inization potentials is proposed, using a large matrix technique The results of some trial calculations on molecular nitrogen are given. 相似文献
1000.
Optimum experimental conditions for the brittle fracture technique applied in trace metal analysis of biological material are described. The efficiency of the technique was tested by sieve and radio-tracer experiments. Numerical results are presented for human placenta submitted to eight different grinding procedures. 相似文献