全文获取类型
收费全文 | 196篇 |
免费 | 6篇 |
国内免费 | 1篇 |
专业分类
化学 | 145篇 |
晶体学 | 7篇 |
力学 | 1篇 |
数学 | 10篇 |
物理学 | 40篇 |
出版年
2024年 | 1篇 |
2023年 | 2篇 |
2022年 | 3篇 |
2021年 | 16篇 |
2020年 | 10篇 |
2019年 | 4篇 |
2018年 | 4篇 |
2017年 | 5篇 |
2016年 | 6篇 |
2015年 | 5篇 |
2014年 | 4篇 |
2013年 | 16篇 |
2012年 | 7篇 |
2011年 | 11篇 |
2010年 | 5篇 |
2009年 | 7篇 |
2008年 | 19篇 |
2007年 | 20篇 |
2006年 | 9篇 |
2005年 | 4篇 |
2004年 | 10篇 |
2003年 | 6篇 |
2002年 | 1篇 |
2000年 | 3篇 |
1998年 | 1篇 |
1996年 | 1篇 |
1995年 | 3篇 |
1994年 | 1篇 |
1993年 | 2篇 |
1992年 | 4篇 |
1991年 | 2篇 |
1990年 | 3篇 |
1987年 | 1篇 |
1985年 | 1篇 |
1982年 | 1篇 |
1981年 | 1篇 |
1978年 | 1篇 |
1975年 | 1篇 |
1973年 | 1篇 |
1972年 | 1篇 |
排序方式: 共有203条查询结果,搜索用时 15 毫秒
11.
12.
Charagundla SR Borthakur A Leigh JS Reddy R 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2003,162(1):113-121
Significant artifacts arise in T(1rho)-weighted imaging when nutation angles suffer small deviations from their expected values. These artifacts vary with spin-locking time and amplitude, severely limiting attempts to perform quantitative imaging or measurement of T(1rho) relaxation times. A theoretical model explaining the origin of these artifacts is presented in the context of a T(1rho)-prepared fast spin-echo imaging sequence. Experimentally obtained artifacts are compared to those predicted by theory and related to B(1) inhomogeneity. Finally, a "self-compensating" spin-locking preparatory pulse cluster is presented, in which the second half of the spin-locking pulse is phase-shifted by 180 degrees. Use of this pulse sequence maintains relatively uniform signal intensity despite large variations in flip angle, greatly reducing artifacts in T(1rho)-weighted imaging. 相似文献
13.
We have calculated the one-neutron absorption cross-section and the longitudinal momentum distribution of the core fragment
coming out from the breakup of 11Be and 19C on 9Be target at 63 MeV/A and 88 MeV/A beam energies respectively. The reaction mechanism is treated within the framework of the
eikonal approximation. The effective range of the nuclear interaction between the core and the valence neutron within the
projectile has been determined by comparing the predicted stripping cross-section with the recently measured one. The effective
range for 19C has been found to be smaller than that for 11Be. It qualitatively indicates that 19C is slightly more halo than 11Be. The smaller width, predicted as well as measured, of the LMD of 18C than 10Be also strengthens this fact. The experimental data concerning the LMD of core fragments have been well represented.
相似文献
14.
Rajesh Kharab Pardeep Singh Ravinder Kumar 《中国物理快报》2007,24(3):656-659
We investigate the effects of higher order multipole transitions, in particular electric quadrupole (E2) and El-E2 interference, on the Coulomb dissociation of 19 C within the framework of the first order eikonal approximation. The sensitivity of the total Coulomb breakup cross section and the longitudinal momentum distribution of the core fragment to these effects are checked. The breakup occurs predominately through the dipole transition and the contribution of E2 transition to the total cross section is found to be within the range from 1 to 3% of that of El. It is further observed that the El-E2 interference term contributes nothing to the integrated cross section. On the other hand, the longitudinal momentum distribution is observed to be insensitive to the E2 transition while the El-E2 interference introduces a small asymmetry in its shape. 相似文献
15.
Biswanath Das Kongara Ravinder Reddy Bommena Ravikanth Akella Venkata Subrahmanya Sarma Balasubramanian Sridhar 《Helvetica chimica acta》2008,91(6):1137-1143
Chemical investigation on two samples of the flowers of Parthenium hysterophorus afforded two new pseudoguaianolides (one from each sample) together with several known constituents. The structures of the new compounds were established by extensive spectroscopic (1D‐ and 2D‐NMR) studies. The X‐ray crystallographic analysis of one of these compounds was also accomplished. 相似文献
16.
Rajesh Shobhita Singal Ravinder K. Kotnala 《Applied biochemistry and biotechnology》2017,183(2):672-683
A biofunctionalized reduced graphene oxide (rGO)-modified screen-printed carbon electrode (SPCE) was constructed as an immunosensor for C-reactive protein (CRP) detection, a biomarker released in early stage acute myocardial infarction. A different approach of single frequency analysis (SFA) study was utilized for the biomolecular sensing, by monitoring the response in phase angle changes obtained at an optimized frequency resulting from antigen-antibody interactions. A set of measurements were carried out to optimize a frequency where a maximum change in phase angle was observed, and in this case, we found it at around 10 Hz. The bioelectrode was characterized by contact angle measurements, scanning electron microscopy, and electrochemical techniques. A concentration-dependent response of immunosensor to CRP with the change in phase angle, at a fixed frequency of 10 Hz, was found to be in the range of 10 ng mL?1 to 10 μg mL?1 in PBS and was fit quantitative well with the Hill-Langmuir equation. Based on the concentration-response data, the dissociation constant (K d) was found to be 3.5 nM (with a Hill coefficient n = 0.57), which indicated a negative cooperativity with high anti-CRP (antibody)-CRP (antigen) binding at the electrode surface. A low-frequency analysis of sensing with an ease of measurement on a disposable electroactive rGO-modified electrode with high selectivity and sensitivity makes it a potential tool for biological sensors. 相似文献
17.
Taranjeet Kaur Ravinder Kumar Wanchoo 《International journal of environmental analytical chemistry》2015,95(6):494-507
Photocatalytic degradation of propiconazole, a triazole pesticide, in the presence of titanium dioxide (TiO2) under ultraviolet (UV) illumination was performed in a batch type photocatalytic reactor. A full factorial experimental design technique was used to study the main effects and the interaction effects between operational parameters in the photocatalytic degradation of propiconazole in a batch photo-reactor using the TiO2 aqueous suspension. The effects of catalyst concentration (0.15–0.4 gL?1), initial pH (3–9), initial concentration (5–35 mg L?1) and light conditions were optimised at a reaction time duration of 90 min by keeping area/volume ratio constant at 0.919 cm2 mL?1. Photocatalytic oxidation of propiconazole showed 85% degradation and 76.57% mineralisation under UV light (365 nm/30 Wm?2) at pH 6.5, initial concentration 25 mg L?1 and constant temperature (25 ± 1 °C). The Langmuir–Hinshelwood kinetic model has successfully elucidated the effects of the initial concentration on the degradation of propiconazole and the data obtained are consistent with the available kinetic parameters. The photocatalytic transformation products of propiconazole were identified by using gas chromatography–mass spectrometry (GC/MS). The pathway of degradation obtained from mass spectral analysis shows the breakdown of transformation products into smaller hydrocarbons (m/z 28 and 39). 相似文献
18.
Ravinder Guje Prathapuram Shrujana Naveen Kumar Veldurthi Ravi Gundeboina Nageshwar Rao Kappera Vithal Muga 《Chemical Papers》2015,69(2):269-278
Ag+- and Sn2+-substituted KSbTeO6 were prepared by a facile ion-exchange method at ambient temperature. All the samples were characterised by scanning electron microscopy, energy-dispersive spectra, thermogravimetric analysis, powder X-ray diffraction, Raman spectra and UV-VIS diffuse reflectance spectra. Both Sn2+- and Ag+-substituted KSbTeO6 were crystallised in a cubic lattice with the \(Fd\bar 3m\) space group. The band-gap energy of all the samples was deduced from their UV-VIS diffuse reflectance spectral profiles. The visible light-induced photocatalytic oxidation of the methylene blue (MB) dye was examined in the presence of all the as-prepared materials. The Ag+- and Sn2+-substituted KSbTeO6 exhibited a higher photocatalytic activity than the parent KSbTeO6 in degradation of the MB dye under visible light irradiation. 相似文献
19.
In this paper, we extend one of Erdélyi's classical integrals for the Gauss hypergeometric functions to a special class of generalized hypergeometric functions in which certain pairs of numerator and denomiator parameters differ by positive integers. Our main results are achieved by applying the fractional integration by parts and series manipulation technique. Some special cases are also pointed out which includes a new extension of a Thomae-type transformation. 相似文献
20.
A first example of organo-N-heterocyclic carbene (NHC) catalyzed click-type fast 1,3-dipolar cycloaddition of nitrile oxides with alkynes was developed for the regioselective synthesis of 3,5-di- and 3,4,5-trisubstituted isoxazoles. Triethylamine (Et(3)N) was employed as an effective base to generate both nitrile oxide and the organo-NHC catalyst in situ. This catalytic approach was used to attach a variety of substituents, including other biologically active fragments, onto the isoxazole ring to selectively design multinucleus structures. Further, we have also optimized the conditions for Cu(I)-free Sonogashira cross-coupling to obtain internal alkynes in high yields, which were subsequently used in cycloaddition. A catalytic cycle is proposed and the remarkable regiocontrol in the formation of isoxazoles was ascribed to a beneficial zwitterion intermediate developed by the interaction of the strongly nucleophilic organo-NHC catalyst with alkyne followed by nitrile oxide. 相似文献