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排序方式: 共有454条查询结果,搜索用时 828 毫秒
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Dr. Bidyut B. Sarma Jonglack Kim Jonas Amsler Dr. Giovanni Agostini Dr. Claudia Weidenthaler Norbert Pfänder Dr. Raul Arenal Dr. Patricia Concepción Dr. Philipp Plessow Prof. Dr. Felix Studt Dr. Gonzalo Prieto 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(14):5855-5864
Realizing the full potential of oxide-supported single-atom metal catalysts (SACs) is key to successfully bridge the gap between the fields of homogeneous and heterogeneous catalysis. Here we show that the one-pot combination of Ru1/CeO2 and Rh1/CeO2 SACs enables a highly selective olefin isomerization-hydrosilylation tandem process, hitherto restricted to molecular catalysts in solution. Individually, monoatomic Ru and Rh sites show a remarkable reaction specificity for olefin double-bond migration and anti-Markovnikov α-olefin hydrosilylation, respectively. First-principles DFT calculations ascribe such selectivity to differences in the binding strength of the olefin substrate to the monoatomic metal centers. The single-pot cooperation of the two SACs allows the production of terminal organosilane compounds with high regio-selectivity (>95 %) even from industrially-relevant complex mixtures of terminal and internal olefins, alongside a straightforward catalyst recycling and reuse. These results demonstrate the significance of oxide-supported single-atom metal catalysts in tandem catalytic reactions, which are central for the intensification of chemical processes. 相似文献
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Ruben Canton‐Vitoria Tobias Scharl Anastasios Stergiou Alejandro Cadranel Raul Arenal Dirk M. Guldi Nikos Tagmatarchis 《Angewandte Chemie (International ed. in English)》2020,59(10):3976-3981
Molybdenum disulfide nanosheets covalently modified with porphyrin were prepared and fully characterized. Neither the porphyrin absorption nor its fluorescence was notably affected by covalent linkage to MoS2. The use of transient absorption spectroscopy showed that a complex ping‐pong energy‐transfer mechanism, namely from the porphyrin to MoS2 and back to the porphyrin, operated. This study reveals the potential of transition‐metal dichalcogenides in photosensitization processes. 相似文献
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Bidyut B. Sarma Jonglack Kim Jonas Amsler Giovanni Agostini Claudia Weidenthaler Norbert Pfnder Raul Arenal Patricia Concepcin Philipp Plessow Felix Studt Gonzalo Prieto 《Angewandte Chemie (International ed. in English)》2020,59(14):5806-5815
Realizing the full potential of oxide‐supported single‐atom metal catalysts (SACs) is key to successfully bridge the gap between the fields of homogeneous and heterogeneous catalysis. Here we show that the one‐pot combination of Ru1/CeO2 and Rh1/CeO2 SACs enables a highly selective olefin isomerization‐hydrosilylation tandem process, hitherto restricted to molecular catalysts in solution. Individually, monoatomic Ru and Rh sites show a remarkable reaction specificity for olefin double‐bond migration and anti‐Markovnikov α‐olefin hydrosilylation, respectively. First‐principles DFT calculations ascribe such selectivity to differences in the binding strength of the olefin substrate to the monoatomic metal centers. The single‐pot cooperation of the two SACs allows the production of terminal organosilane compounds with high regio‐selectivity (>95 %) even from industrially‐relevant complex mixtures of terminal and internal olefins, alongside a straightforward catalyst recycling and reuse. These results demonstrate the significance of oxide‐supported single‐atom metal catalysts in tandem catalytic reactions, which are central for the intensification of chemical processes. 相似文献
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L. Raul W. Abramo 《International Journal of Theoretical Physics》2004,43(3):563-573
We investigate tachyon dynamics with an inverse power-law potential V ()
–. We find global attractors of the dynamics leading to a dust behavior for > 2 and to an accellerating universe for 0 < 2. We study linear cosmological perturbations and we show that metric fluctuations are constant on large scales in both cases. In the presence of an additional perfect fluid, the tachyon with this potential behaves as dust or dark energy. 相似文献
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Uncertainty evaluation of the spectral UV irradiance evaluated by using the UVSPEC radiative transfer model 总被引:1,自引:0,他引:1
The radiative transfer models allow calculating the spectral UV irradiance from some set of measured input quantities linked with the surface reflectivity, the solar zenith angle, the ozone column and the characteristics of clouds and aerosols. The spectral irradiance yielded by a model is influenced by errors in the measurement of the input quantities. In this paper, the influences of these errors are characterized and compared with other systematic effects through an uncertainty analysis. We evaluated the uncertainty of the spectral UV irradiance rendered by the UVSPEC model, under cloudless sky conditions. In order to express the uncertainty of the output quantities (the global, direct and diffuse irradiances) in terms of the standard uncertainties of the input quantities, we used a Monte Carlo-based uncertainty propagation technique. We found that the uncertainty of the irradiance in the UV-B part of the spectrum was strongly influenced by the uncertainty attributed to the ozone column datum. Moreover, the uncertainities associated with the aerosol parameters accounted for most of the UV-A global irradiance uncertainty; the latter increased from about 4% under low aerosol conditions, up to about 14% in case of polluted air. We conclude that the UV irradiance evaluation through radiative transfer models requires paying special attention to the assessment of the aerosols properties. 相似文献
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Timothy E. Burrow Raul G. Enriquez William F. Reynolds 《Magnetic resonance in chemistry : MRC》2009,47(12):1086-1094
The effect of various acquisition and processing parameters on the sensitivity of HMBC spectra for typical organic molecules has been systematically investigated. For molecules in the 200–600 molecular weight range, an acquisition time of 0.2 to 0.4 s, a recycle time of no more than 1.0 s, optimization for nJCH = 8 Hz and 512 time increments (with two‐ to fourfold linear prediction) are recommended. Some form of sine bell weighting along f2 and either Gaussian or sine bell weighting along f1 is suggested. The use of a 0.1‐s acquisition time and/or Gaussian or exponential weighting along f2 can result in dramatic sensitivity loss, particularly for correlation peaks involving protons with complex splitting patterns, and should be avoided. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献