Design of dual-core resonant leaky optical fibre based gain flattening filters for erbium doped fibre amplifiers

We propose optical fibre based filters employing dual-core resonant leaky structure for gain equalization of erbium doped fibre amplifier (EDFA). Spectral loss variation of the structure has been utilized to suppress gain peak and, thus, flatten overall gain profile in the C-band. We show 15.7 dB flat gain with ± 1.6 dB ripple in the wavelength range from 1525 nm to 1555 nm using a single filter and 18±0.7 dB gain using two cascaded filters.     

Cu(I)/Fe(III) promoted dicarbonylation of aminopyrazole via oxidative CH coupling with methyl ketones

Cu(I)/Fe(III) promoted C4-dicarbonylation of 5-aminopyrazole is developed. The strategy involved radical triggered direct oxidative coupling of 5-aminopyrazoles with methyl ketones using aerial oxygen as a source of oxygen in newly generated carbonyl group. CuI is used as catalyst and FeCl₃·6H₂O is used as additive and the reaction proceeded at 120?°C in DMSO for 9–12?h. It is found that use of Cu(II) catalyst gives the thiomethylated product by reacting with DMSO instead of oxidative coupling. A plausible mechanism is also given.     

An inverse hyper-spherical harmonics-based formulation for reconstructing 3D volumetric lung deformations

A method to estimate the deformation operator for the 3D volumetric lung dynamics of human subjects is described in this paper. For known values of air flow and volumetric displacement, the deformation operator and subsequently the elastic properties of the lung are estimated in terms of a Green's function. A Hyper-Spherical Harmonic (HSH) transformation is employed to compute the deformation operator. The hyper-spherical coordinate transformation method discussed in this paper facilitates accounting for the heterogeneity of the deformation operator using a finite number of frequency coefficients. Spirometry measurements are used to provide values for the airflow inside the lung. Using a 3D optical flow-based method, the 3D volumetric displacement of the left and right lungs, which represents the local anatomy and deformation of a human subject, was estimated from 4D-CT dataset. Results from an implementation of the method show the estimation of the deformation operator for the left and right lungs of a human subject with non-small cell lung cancer. Validation of the proposed method shows that we can estimate the Young's modulus of each voxel within a 2% error level.     

Multi-layer cladding leaky planar waveguide for high-power applications

We design a multi-layer cladding large-core planar waveguide that supports a single guided mode. The waveguide works on the principle of higher-order mode discrimination. The cladding of the waveguide is formed by alternate low- and high- index regions, which helps leaking out of higher-order modes while retaining the fundamental mode over the entire length of the waveguide. The structure is analyzed by the transfer-matrix method and the leakage losses of the modes have been calculated. We show that a waveguide formed in silica with numerical aperture 0.24 and core width 10 μm can be designed to exhibit single-mode operation at 1550-nm wavelength. Such a structure should find applications in high-power planar waveguide lasers and amplifiers.     

Chemical spray pyrolysis deposition and characterization of p-type CuCr1−xMgxO2 transparent oxide semiconductor thin films

A chemical spray pyrolysis technique for deposition of p-type Mg-doped CuCrO₂ transparent oxide semiconductor thin films using metaloorganic precursors is described. As-deposited films contain mixed spinel CuCr₂O₄ and delafossite CuCrO₂ structural phases. Reduction in spinel CuCr₂O₄ fraction and formation of highly crystalline films with single phase delafossite CuCrO₂ structure is realized by annealing at temperatures ?700 °C in argon. A mechanism of synthesis of CuCrO₂ films involving precursor decomposition, oxidation and reaction between constituent oxides in the spray deposition process is presented. Post-annealed CuCr_0.93Mg_0.07O₂ thin films show high (?80%) visible transmittance and sharp absorption at band gap energy with direct and indirect optical band gaps 3.11 and 2.58 eV, respectively. Lower (∼450 °C) substrate temperature formed films are amorphous and yield lower direct (2.96 eV) and indirect (2.23 eV) band gaps after crystallization. Electrical conductivity of CuCr_0.93 Mg_0.07O₂ thin films ranged 0.6-1 S cm⁻¹ and hole concentration ∼2×10¹⁹ cm⁻³ determined from Seebeck analysis. Temperature dependence of conductivity exhibit activation energies ∼0.11 eV in 300-470 K and ∼0.23 eV in ?470 K region ascribed to activated conduction and grain boundary trap assisted conduction, respectively. Heterojunction diodes of the structure Au/n-(ZnO)/p-(CuCr_0.93Mg_0.07O₂)/SnO₂ (TCO) were fabricated which show potential for transparent wide band gap junction device.     

Through‐space 19F–19F spin–spin coupling in ortho‐fluoro Z‐azobenzene

We report through‐space (TS) ¹⁹F–¹⁹F coupling for ortho‐fluoro‐substituted Z ‐azobenzenes. The magnitude of the TS‐coupling constant (^TSJ_FF) ranged from 2.2–5.9 Hz. Using empirical formulas reported in the literature, these coupling constants correspond to non‐bonded F–F distances (d_FF) of 3.0–3.5 Å. These non‐bonded distances are significantly smaller than those determined by X‐ray crystallography or density functional theory, which argues that simple models of ¹⁹F–¹⁹F TS spin–spin coupling solely based d_FF are not applicable. ¹H, ¹³C and ¹⁹F data are reported for both the E and Z isomers of ten fluorinated azobenzenes. Density functional theory [B3YLP/6‐311++G(d,p)] was used to calculate ¹⁹F chemical shifts, and the calculated values deviated 0.3–10.0 ppm compared with experimental values. Copyright © 2015 John Wiley & Sons, Ltd.     

Variation of wave impedance of shielded suspended dielectric guide

A shielded suspended dielectric guide is a dielectric rectangular slab enclosed by regular metallic side walls from all the sides. This type of structure is used in dual mode phase shifter where the size of the normal rectangular wave guide is reduced at the ends, where a dielectric material is embeded in ferrite core. Hence impedance variation of a phase shifter at its transition may be easily calculated using shielded suspended dielectric guide which is a prime parameter for optimum efficiency of wave launching.     

Shielded rectangular dielectric wave guides for millimeter wave integrated circuits

The dispersion characteristics of Insulated non-radiative dielectric guides are computed using mode matching technique. From the dispersion characteristics the dielectric loss conductor loss and wave impedances are derived. Effect of metallic walls on trapped insulated image guide are also discussed. The dimensions of Insulated non radiative dielectric guide are same as that of rectangular metallic wave guide at ka band.     

Benzonitriles: Survey of their importance and scaling of their vibrational frequencies

This work provides a short survey of the studies carried out on benzonitrile and its derivatives, with special attention on a spectroscopic point of view. The importance and main applications of these molecules are also briefly indicated. For an accurate assignment of their vibrational spectra, the scaling procedures for the wave numbers are described. For this purpose, the performance of semiempirical, ab initio, and density functional methods, with different basis sets, is determined. A “resume” of the main scaling factors to be used in the calculated wave numbers is shown. The results obtained for several benzene derivatives, and in particular for four benzonitriles, are analyzed. © 2003 Wiley Periodicals, Inc. Int J Quantum Chem 94: 189–204, 2003