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81.
New Polydentate Trimethylsilyl Chalcogenide Reagents for the Assembly of Polyferrocenyl Architectures 下载免费PDF全文
Mahmood Azizpoor Fard Bahareh Khalili Najafabadi Mahdi Hesari Prof. Dr. Mark S. Workentin Prof. Dr. John F. Corrigan 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(23):7037-7047
A series of polychalcogenotrimethylsilane complexes Ar(CH2ESiMe3)n, (Ar=aryl; E=S, Se; n=2, 3, and 4) can be prepared from the corresponding polyorganobromide and M[ESiMe3] (M=Na, Li). These represent the first examples of the incorporation of such a large number of reactive ?ESiMe3 moieties onto an organic molecular framework. They are shown to be convenient reagents for the preparation of the polyferrocenylseleno‐ and thioesters from ferrocenoyl chloride. The synthesis, structures, and spectroscopic properties of the new silyl chalcogen complexes 1,4‐(Me3SiECH2)2(C6Me4) (E=S, 1 ; E=Se, 2 ), 1,3,5‐(Me3SiECH2)3(C6Me3) (E=S, 3 ; E=Se, 4 ) and 1,2,4,5‐(Me3SiECH2)4(C6H2) (E=S, 5 ; E=Se, 6 ) and the polyferrocenyl chalcogenoesters [1,4‐{FcC(O)ECH2}2(C6Me4)] (E=S, 7 ; E=Se, 8 ), [1,3,5‐{FcC(O)ECH2}3(C6Me3)] (E=S, 9 ; E=Se, 10 ) and [1,2,4,5‐{FcC(O)ECH2}4(C6H2)] (E=S, 11 illustrated; E=Se, 12 ) are reported. The new polysilylated reagents and polyferrocenyl chalcogenoesters have been characterized by multinuclear NMR spectroscopy (1H, 13C, 77Se), electrospray ionization mass spectrometry and, for complexes 1 , 2 , 3 , 4 , 7 , 8 , and 11 , single‐crystal X‐ray diffraction. The cyclic voltammograms of complexes 7 – 11 are presented. 相似文献
82.
Inside Cover: Seeding Molecular Rotators on a Passivated Silicon Surface (ChemPhysChem 2/2014) 下载免费PDF全文
83.
Synthesis,Characterization, and Photoluminescence Properties of Silver(I) Metal‐Organic Polymers with Nanochannels Based on 2‐Sulfoterephthalic Acid and Di(pyridin‐2‐yl)amine Ligands 下载免费PDF全文
Hui Huang Mahmood Payehghadr Jie Wang Hong‐Ping Xiao Ai‐Yin Wang Xin‐Hua Li Ali Morsali 《Helvetica chimica acta》2014,97(3):345-354
Two new silver(I) 3D coordination polymers, namely [Ag3(2‐stp)(dpa)]n ( 1 ) and {[Ag2(2‐stp)(H2O)]?Hdpa}n ( 2 ) (2‐NaH2stp=sodium 2,5‐dicarboxysulfonate, dpa=di(pyridine‐2‐yl)amine) were synthesized. The complexes were characterized by elemental analysis, FT‐IR spectra, thermogravimetric analyses (TGA), and single‐crystal X‐ray diffraction. In complex 1 , three neighboring Ag ions are bridged by N‐ and O‐atom, forming a 3D coordination network. The molecular structure of 2 is cation? anion species, forming 3D host? guest supramolecular network with the [Hdpa]+ cations encapsulated in the nanochannels. The photoluminescence properties of the complexes were also investigated in the solid state at room temperature. 相似文献
84.
The irradiation effects of Ar+, He+, and S+ with energy from 10 eV to 180 eV on n-InP(100) surface are analyzed by X-ray photoelectron spectroscopy and low energy electron diffraction. After irradiation on the n-InP surface, damage on the surface, displacement of the Fermilevel and formation of sulfur species on S+ exposed surface are found and studied. Successive annealing is done to suppress the surface states introduced by S+ exposure. However, it is unsuccessful in removing the damage caused by noble ions. Besides, S+ ions can efficiently repair the Ar+ damaged surface, and finally form a fine 2×2 InP surface. 相似文献
85.
Dr. Oliver Guillermet Dr. Ather Mahmood Dr. Jianshu Yang Dr. Jorge Echeverria Judicael Jeannoutot Dr. Sebastien Gauthier Dr. Christian Joachim Dr. Frederic Chérioux Prof. Dr. Frank Palmino 《Chemphyschem》2014,15(2):271-275
Thermally activated rotation of single molecules adsorbed on a silicon‐based surface between 77 and 150 K has been successfully achieved. This remarkable phenomenon relies on a nanoporous supramolecular network, which acts as a template to seed periodic molecule rotors on the surface. Thermal activation of rotation has been demonstrated by STM experiments and confirmed by theoretical calculations. 相似文献
86.
87.
An efficient and simple synthesis of α‐hydroxyphosphonates via reaction of aldehydes and ketones with dimethylphosphite in the presence of MgCl2/Et3N base system is reported. The use of readily available and easy to handle reagent MgCl2/Et3N makes this method simple, convenient, and practical. 相似文献
88.
An analytical method is described for the analysis of antazoline [2-(N-benzylanilinomethyl) imidazoline] using pmr. The procedure provides good quantitative results together with a very specific mean for identification of antazoline 相似文献
89.
Ratiometric fluorescent chemosensors based on the position of ring annulation of the naphthol–thiazole moiety for quantification of zinc ions in aqueous ethanol were synthesized and investigated. It was found that sensor 3 exhibited a remarkably large red shift of 140 nm in emission upon complexation with Zn2+. A TD-B3LYP/6-31G (d,p) calculation was performed to characterize the nature of the fluorescence behavior of sensor 3 upon Zn2+ complexation. The combination of experimental and computational analyses provides a more complete understanding of the molecular level origin of these unique photophysical properties of this type of chemosensor. 相似文献
90.
We comment on the paper [Song et al., J. Comput. Chem. 2009, 30, 399]. and discuss the efficiency of the orbital optimization and gradient evaluation in the Valence Bond Self Consistent Field (VBSCF) method. We note that Song et al. neglect to properly reference Broer et al., who published an algorithm [Broer and Nieuwpoort, Theor. Chim. Acta 1988, 73, 405] to use a Fock matrix to compute a matrix element between two different determinants, which can be used for an orbital optimization. Further, Song et al. publish a misleading comparison with our VBSCF algorithm [Dijkstra and van Lenthe, J. Chem. Phys. 2000, 113, 2100; van Lenthe et al., Mol. Phys. 1991, 73, 1159] to enable them to favorably compare their algorithm with ours. We give detail timings in terms of different orbital types in the calculation and actual timings for the example cases. © 2012 Wiley Periodicals, Inc. 相似文献