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41.
One‐Pot Synthesis of New 1,5‐Disubstituted Tetrazoles Bearing 2,2‐Bis(trimethylsilyl)ethenyl Groups via The Ugi Four‐Component Condensation Reaction Catalyzed by MgBr2·2Et2O 下载免费PDF全文
Kazem D. Safa Tohid Shokri Hassan Abbasi Reza Teimuri‐Mofrad 《Journal of heterocyclic chemistry》2014,51(1):80-84
A simple one‐pot Ugi four‐component condensation reaction has been developed for the synthesis of tetrazoles bearing 2,2‐bis(trimethylsilyl)ethenyl groups from the synthesized 4‐[2,2‐bis(trimethylsilyl) ethenyl]benzaldehyde ( 1 ), various amines, isocyanides, and trimethylsilylazide at room temperature, without solvent, and in the presence of catalytic amounts of MgBr2·2Et2O as catalyst. 相似文献
42.
3-Chloro-N-(8′-quinolyl)benzo[b]thiophene-2-carboxamide was synthesized from 3-chlorobenzo[b] thiophene -2-carboxyl chloride and 8-aminoquinoline in the presence of triethylamine. The single crystal X-ray structure
determination confirmed the earlier proposed structure and also characterized by 1HNMR, and Mass spectroscopy. Crystallographic study reveals that the structure crystallizes in monoclinic system, a = 14.878(4) ?, b = 8.4292(15) ?, c = 25.461(7) ?, β = 112.022(18)°, Z = 8, V = 2960.20(12) ?3 with space group C2/c (No. 15). In the structure packing, three kinds of interactions are responsible for the stability of the structure. Infinite
two-dimensional stair-like layered chains are formed by relatively strong intermolecular hydrogen bonds [C14—H14...O1]. These
parallel chains are connected by several π—π and CH—π interactions, alternatively. There are two such parallel chains with
70.53°, which are in contact by van der Waals interactions. 相似文献
43.
Abbasi A Skripkin MY Eriksson L Torapava N 《Dalton transactions (Cambridge, England : 2003)》2011,40(5):1111-1118
The two dimethyl sulfoxide solvated rhodium(III) compounds, [Rh(dmso-κO)(5)(dmso-κS)](CF(3)SO(3))(3) (1 & 1* at 298 K and 100 K, respectively) and [Rh(dmso-κO)(3)(dmso-κS)(2)Cl](CF(3)SO(3))(2) (2), crystallize with orthorhombic unit cells in the space group Pna2(1) (No. 33), Z = 4. In the [Rh(dmso)(6)](3+) complex with slightly distorted octahedral coordination geometry, the Rh-O bond distance is significantly longer with O trans to S, 2.143(6) ? (1) and 2.100(6) ? (1*), than the mean Rh-O bond distance with O trans to O, 2.019 ? (1) and 2.043 ? (1*). In the [RhCl(dmso)(5)](3+) complex, the mean Rh-O bond distance with O trans to S, 2.083 ?, is slightly longer than that for O trans to Cl, 2.067(4) ?, which is consistent with the trans influence DMSO-κS > Cl > DMSO-κO of the opposite ligands. Raman and IR absorption spectra were recorded and analyzed and a complete assignment of the vibrational bands was achieved with support by force field calculations. An increase in the Rh-O stretching vibrational frequency corresponded to a decreasing trans-influence from the opposite ligand. The Rh-O force constants obtained were correlated with the Rh-O bond lengths, also including previously obtained values for other M(dmso)(6)(3+) complexes with trivalent metal ions. An almost linear correlation was obtained for the MO stretching force constants vs. the reciprocal square of the MO bond lengths. The results show that the metal ion-oxygen bonding of dimethyl sulfoxide ligands is electrostatically dominated in those complexes and that the stretching force constants provide a useful measure of the relative trans-influence of the opposite ligands in hexa-coordinated Rh(III)-complexes. 相似文献
44.
Abstract This article proposes a silicon-based arrayed waveguide grating operating in two wavelength bands simultaneously with central wavelengths of 1,550.12 nm and 1,310.12 nm. If input light to an arrayed waveguide grating consists of wavelengths around 1,550.12 nm, the proposed system will act as a four-channel demultiplexer with channel spacing of 0.8 nm. On the other hand, when input wavelengths are distributed around 1,310.12 nm, the same arrayed waveguide grating will divide the input to seven channels with channel spacing of 0.33 nm. 相似文献
45.
Abbasi Mohammad Hossein Iapichino Laura Schilders Wil van de Wouw Nathan 《Nonlinear dynamics》2022,107(4):3729-3748
Nonlinear Dynamics - This paper proposes a data-based approach for model order reduction that preserves incremental stability properties. Existing data-based approaches do typically not preserve... 相似文献
46.
The natural broadening of hydrogen atom spectrum based on the minimal length uncertainty is calculated. We will show that the natural broadening of hydrogen atom spectrum receives any correction. 相似文献
47.
48.
The growth of silver iodide nanoparticles on silk fiber was achieved by sequential dipping in an alternating bath of potassium iodide and silver nitrate under ultrasound irradiation. Some parameters such as effect of pH, concentration and numerous sequential dipping in growth of the nanocrystal have been studied. The samples were characterized with powder X-ray diffraction (XRD), scanning electron microscopy (SEM), ICP, TGA and solid state UV–vis spectroscopy. 相似文献
49.
Nano-structures of AgI have been prepared by reaction between AgNO3 and KI under ultrasound irradiation. Some of parameters such as effect of stirring, temperature, sonicating time in growth and morphology of the nano-structures have been studied. The sizes distributions depend slighter on reaction conditions. But, morphology of nano-structure depends strongly on reaction parameters. With change of solvent concentration and sonicating time, nanoparticles structures changed to nanowires. An increasing of temperature results in an increasing of solubility. As a result, nuclei with small sizes become unstable and dissolve back into the solution. Attendance or non-attendance of stirring is another parameter that effects on morphology of nano-structures. In some conditions, non-attendance of stirring led to nanowires structure and in the other conditions, nanoparticles structures were prepared. The samples were characterized with powder X-ray diffraction (XRD), scanning electron microscopy (SEM). 相似文献
50.
In this paper thermally induced entanglement between a two-level atom and photons inside a bimodal nonlinear coupler is studied. The interaction occurs in the presence of a centrosymmetric medium which couples the two photonic modes via the first and third order susceptibilities. Such effects on the atom–photons interaction, however, are assumed negligible so that the linear Jaynes–Cummings model applies. It is further assumed that the coupler is held at a temperature T, so that each of the combined atom–photon states, with a definite, T dependent, probability, is present. The partially transposed density matrix and, consequently, the negativity, as a measure of entanglement, are determined as functions of temperature. The negativity so calculated shows that the system of a two-level atom and photons is separable at zero temperature, becomes more entangled, reaching the maximal at a certain temperature and asymptotically disentangles. Effect of medium characteristics on such behavior is also discussed. 相似文献