全文获取类型
收费全文 | 342篇 |
免费 | 21篇 |
国内免费 | 2篇 |
专业分类
化学 | 243篇 |
晶体学 | 1篇 |
力学 | 22篇 |
数学 | 38篇 |
物理学 | 61篇 |
出版年
2023年 | 2篇 |
2022年 | 12篇 |
2021年 | 24篇 |
2020年 | 23篇 |
2019年 | 17篇 |
2018年 | 22篇 |
2017年 | 24篇 |
2016年 | 40篇 |
2015年 | 7篇 |
2014年 | 26篇 |
2013年 | 37篇 |
2012年 | 21篇 |
2011年 | 18篇 |
2010年 | 21篇 |
2009年 | 14篇 |
2008年 | 10篇 |
2007年 | 7篇 |
2006年 | 7篇 |
2005年 | 7篇 |
2004年 | 4篇 |
2003年 | 1篇 |
2001年 | 3篇 |
2000年 | 1篇 |
1998年 | 1篇 |
1996年 | 2篇 |
1994年 | 1篇 |
1991年 | 2篇 |
1986年 | 1篇 |
1980年 | 2篇 |
1979年 | 1篇 |
1978年 | 1篇 |
1976年 | 5篇 |
1969年 | 1篇 |
排序方式: 共有365条查询结果,搜索用时 15 毫秒
361.
Yasar Arafat Abbasi Akbar Ali Muhammad Haleem Khan Muhammad Mufazzal Saeed Kashif Naeem 《Journal of Radioanalytical and Nuclear Chemistry》2012,292(1):277-283
The extraction behavior of nalidixic acid (HNA) in CH2Cl2 has been studied for various di- and trivalent metal ions such as Cu(II), Fe(II), Ni(II), Mn(II), Sb(II), Co(II), Sc(III),
Y(III), Nd(III) and Eu(III) from aqueous buffer solutions of pH 1–7 with 0.1 mol dm−3 nalidixic acid in dichloromethane. Separation factors of Sc(III) from these metals has shown that its clean separation is
possible at pH 3.4–4. The parameters affecting the extraction of Sc(III) were optimized. The composition of the extracted
adduct was determined by slope analysis method that came out to be Sc(NA)3. Extraction of Sc(III) was studied in the presence of various cations and anions. Among the anions studied only fluoride,
citrate and oxalate have significant interference whereas, Fe(III) has reduced the extraction to 53% that can be removed by
using ascorbic acid as reducing agent. The proposed extraction system proved good stability up to six extraction-stripping
stages for the extraction of Sc(III). 相似文献
362.
The growth of Cu3(BTC)2 (BTC = 1,3,5-benzenetricarboxylate), also known as CuBTC and HKUST-1, Metal-Organic Framework (MOF) nanostructures on silk fibers were achieved by layer-by-layer technique in alternating bath of Cu(OAc)2·2H2O and H3BTC solutions under ultrasound irradiation. The effect of pH, reaction time, ultrasound irradiation and sequential dipping steps in growth of the CuBTC Metal-Organic Framework nanostructures has been studied. These systems depicted a decrease in the size accompanying a decrease in the sequential dipping steps. In addition, dense coating of silk fibers with CuBTC MOF results in decrease the emission intensity of silk fibers. The silk fibers containing CuBTC Metal-Organic Framework exhibited high antibacterial activity against Escherichia coli and Staphylococcus aureus. The samples were characterized with powder X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) spectra and scanning electron microscopy (SEM). XRD analyses indicated that the prepared CuBTC MOF nanostructures on silk fibers were crystalline. 相似文献
363.
The growth of silver bromide nanoparticles on polyester fiber was achieved by sequential dipping steps in alternating bath of potassium bromide and silver nitrate under ultrasound irradiation. The effects of ultrasound irradiation, concentration and sequential dipping steps in growth of the AgBr nanoparticles have been studied. Particle sizes and morphology of nanoparticle are depending on power of ultrasound irradiation, sequential dipping steps and concentration. These systems depicted a decrease in the particles size accompanying an increase in the sonication power. Results suggest that an increasing of sequential dipping steps and concentration led to an increasing of particle size. The physicochemical properties of the nanoparticles were determined by powder X-ray diffraction (XRD) and scanning electron microscopy (SEM). 相似文献
364.
The polyethylene fibers containing Ag nanoparticles were prepared through the chemical reduction under ultrasound irradiation. The effect of reducing reagent, power of ultrasound irradiation, reaction time and temperature in growth of the nanometric Ag were studied. Particle sizes and morphology of nanoparticle are depending on power of ultrasound irradiation. Results show a decrease in the particles size as increasing power of ultrasound irradiation. Also, an increase in temperature led to increase of particle size. The polyethylene fibers containing Ag nanoparticles were characterized with powder X-ray diffraction (XRD) and scanning electron microscopy (SEM). 相似文献
365.