Synthesis and characterization of NaA zeolite particle as intumescent fiame retardant in chloroprene rubber system

NaA zeolite with average particle size of 1 m was successfully synthesized by microwave heating. Inu-ences of pre-crystallization time,microwave power and microwave heating time on the synthesis of NaA zeolite were investigated. The as-synthesized sample was characterized by X-ray diffraction(XRD),scanning electron microscopy(SEM) and particle size distribution(PSD) . Thermal and fiame retardant properties as intumescent fiame retardant(IFR) in chloroprene rubber(CR) system,such as thermo-gravimetry(TG),lim...     

瞬态信号的小波变换波达方向估计

针对瞬态信号方位估计问题,提出了基于连续小波变换的多重信号分类测向算法(CWT_MUSIC)。首先由信号特征确定小波尺度参数,构造Morlet小波,对信号进行小波变换,利用获得的小波变换系数建立多分辨时频阵列信号模型,并据此模型设计基于子空间的MUSIC算法以实现瞬态信号的波达方向估计;然后对该算法的多分辨与误差性能进行分析,最后仿真实验和实际爆炸试验验证了所提出的CWT_MUSIC算法能有效地提高空间谱的分辨率和DOA估计性能。     

A novel single phase cathode material for a proton-conducting SOFC

A novel single phase BaCe_0.5Bi_0.5O_3 ? δ (BCB) was employed as a cathode material for a proton-conducting solid oxide fuel cell (SOFC). The single cell, consisting of a BaZr_0.1Ce_0.7Y_0.2O_3 ? δ (BZCY7)-NiO anode substrate, a BZCY7 anode functional layer, a BZCY7 electrolyte membrane and a BCB cathode layer, was assembled and tested from 600 to 700 °C with humidified hydrogen (～3% H₂O) as the fuel and the static air as the oxidant. An open-circuit potential of 0.96 V and a maximum power density of 321 mW cm^?2 were obtained for the single cell. A relatively low interfacial polarization resistance of 0.28Ω cm² at 700 °C indicated that the BCB was a promising cathode material for proton-conducting SOFCs.     

Cluster State Entanglement of Semiconductor Quantum Dots Based on Faraday Rotation

We propose a scheme for a large-scale cluster state preparation of single-charged semiconductor quantum dots utilizing Faraday rotation. Without interaction between quantum dots, the exciton induced Faraday rotation could distribute the spatially separate quantum dots into a quantum network assisted by cavity QED. We obtain the corresponding parameters from the numerical simulation based on the input-output process for the required Faraday rotation and some discussion is made in view of experimental feasibility.     

含1,2,3-三氮唑结构的1,5-苯并硫氮杂[艹卓]的合成及其抑真菌活性

设计合成了三类含1,2,3-三氮唑结构的1,5-苯并硫氮杂[艹卓]化合物3-(1H-1,2,3-三氮唑)-4-芳基-2,5-二氢-1,5-苯并硫氮杂[艹卓](5a^5f)、3-(2H-1,2,3-三氮唑)-4-芳基-2,3-二氢-1,5-苯并硫氮杂[艹卓](6a^6f)和3-(1H-1,2,3-三氮唑)-4-芳基-2,3,4,5-四氢-1,5-苯并硫氮杂[艹卓](7a^7f).研究了中间体及目标产物的合成条件,分离出其中两个副产物并进行了结构确定.目标产物的抑真菌活性测试表明,化合物5a^5f对真菌具有良好的抑制作用,对新生隐球菌的抑制效果尤为突出.初步抑真菌构效关系研究表明, 1H-1,2,3-三氮唑环和C=C双键是化合物5a^5f抑真菌活性的关键官能团.     

飞秒多脉冲激光烧蚀金属过程中的能量剩余现象

提出了描述整个飞秒多脉冲激光烧蚀过程的物理模型,模型考虑了多脉冲烧蚀的新的特点,考虑靶材吸收率随温度的变化和蒸发效应,建立了激光烧蚀不同阶段的热传导方程,给出了相应的定解条件。以金靶材为例,利用有限差分法,求解了热传导动力学方程,分别给出单脉冲和多脉冲作用下相应的靶材电子和离子亚系统的温度演化图像,及多脉冲激光作用下能量剩余系数和脉冲个数的变化规律,发现理论曲线与相应的实验数据吻合较好。研究结果充分证明多脉冲激光烧蚀过程中剩余能量的存在。     

Photothermal performance of MFe2O4 nanoparticles

In this paper, we synthesized three kinds of ferrites and investigated their photothermal property. The result indicated that the photothermal effect of Fe₃O₄ and MnFe₂O₄ nanoparticles declined while that of ZnFe₂O₄ nanoparticles maintained relatively stable after preservation for 70 days, and then ZnFe₂O₄ nanoparticles could effectively kill cancer cells under NIR laser.     

欠驱动空间柔性机器人动力学建模与实时仿真

研究了在轨服务欠驱动空间柔性机器人的广义递推高效动力学算法. 根据系统中铰的驱动情况分别对铰链定义为主动铰和被动铰,通过判断铰链的类型分别按照两次从系统的顶端到基座的顺序、一次从基座到顶端的顺序进行了系统铰接体惯量的递推、系统冗余力的递推和广义加速度和广义主动力的递推. 通过上述3 种方式的递推过程建立了空间机器人广义递推动力学模型,实现了高效率O(n) 次的计算效率. 然后采用线性多步积分算法,对所建立的微分-代数方程进行了快速的数值求解. 最后通过软件编制仿真验证了本研究内容的正确性和高效性.     

涉及整函数差分算子的唯一性定理

作者研究了关于有穷级整函数两个差分算子的分担值问题,证明了:令f(z)是满足λ(f-a(z))＜p(f)的有穷级超越整函数,其中a(z)(∈ S(f))是整函数且满足p(a(z))＜1,并令η(∈C)是常数且满足Δ2ηf(z)≠0.如果Δ2ηf(z)和Δηf(z)CM分担Δηa(z),其中Δηa(z)∈S(Δ2ηf(z...     

Direct growth of flexible LiMn2O4/CNT lithium-ion cathodes

Flexible, binder-free LiMn(2)O(4)/CNT nanocomposites with good reversible capability and cycling stability were fabricated by in-situ hydrothermal growth for flexible lithium battery applications.