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121.
Anna Evans Anja Bieberle-Hütter Henning Galinski Jennifer L. M. Rupp Thomas Ryll Barbara Scherrer René Tölke Ludwig J. Gauckler 《Monatshefte für Chemie / Chemical Monthly》2009,140(9):975-983
Abstract Micro-solid oxide fuel cells (micro-SOFC) are predicted to be of high energy density and are potential power sources for portable
electronic devices. A micro-SOFC system consists of a fuel cell comprising a positive electrode-electrolyte-negative electrode
(i.e. PEN) element, a gas-processing unit, and a thermal system where processing is based on micro-electro-mechanical-systems
fabrication techniques. A possible system approach is presented. The critical properties of the thin film materials used in
the PEN membrane are discussed, and the unsolved subtasks related to micro-SOFC membrane development are pointed out. Such
a micro-SOFC system approach seems feasible and offers a promising alternative to state-of-the-art batteries in portable electronics.
Graphical abstract Graphical Abstract text
相似文献
122.
The Finite Cell Method (FCM) combines the fictitious domain approach with high-order finite elements and adaptive integration. For linear elastic problems with smooth solution, FCM has been shown to achieve exponential rates of convergence in energy norm, while its structured cell grid guarantees simple mesh generation irrespective of the geometric complexity involved. In this contribution, the FCM idea is combined with standard finite element technology for the solution of geometrically nonlinear problems. In particular, a modified FCM formulation is introduced, which resets the deformed configuration of the fictitious domain to the deformation-free reference configuration after each Newton iteration. Numerical experiments show that this intervention allows for stable nonlinear FCM analysis with very small values of the penalty parameter, while the accuracy of the geometrically nonlinear solution within the physical domain remains unaffected. (© 2011 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
123.
Vananroye A Van Puyvelde P Moldenaers P 《Langmuir : the ACS journal of surfaces and colloids》2006,22(9):3972-3974
The breakup of Newtonian droplets in a Newtonian matrix during shear flow is investigated in a counterrotating parallel plate device. For bulk conditions, the critical capillary number for breakup is known to be only determined by the viscosity ratio. Here, we show that the critical capillary number is also affected by the degree of confinement: for low viscosity ratios, confinement suppresses breakup, whereas for high viscosity ratios, confinement promotes breakup. This way, above a critical value for the degree of confinement, even droplets with a viscosity ratio larger than 4, which are unbreakable by shear in a bulk situation, can be broken in a simple shear flow field. 相似文献
124.
The mechanical behaviour of cellular materials is dominated by the influence of the microtopology. If the characteristic microstructural length scale becomes comparable to the macroscopical length scale, classical homogenisation strategies fail and have to be replaced by extended approaches. In the present contribution, we present a micropolar continuum model for large deformations introducing the microrotation as an additional degree of freedom. (© 2008 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
125.
We consider stress–induced transformations of polycrystalline shape–memory alloys which are so–called scalar materials. In this case the Sachs bound on the phase transformation yield stress turns out to be sharp. (© 2008 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
126.
Stefan Wyhlidal Dieter Rank Katharina Schott Gerhard Heiss Jason Goetz 《Isotopes in environmental and health studies》2014,50(4):448-460
Results of stable isotope measurements (δ2H, δ18O) of daily grab samples, taken from the Danube River at Tulln (river km 1963) during 2012, show seasonal and short-term variations depending on the climatic/hydrological conditions and changes in the catchment area (temperature changes, heavy rains and snow melt processes). Isotope ratios in river water clearly reflect the isotopic composition of precipitation water in the catchment area since evaporation influences play a minor role. Average δ2H and δ18O values in 2012 are?78‰ and?11.0‰, respectively, deuterium excess averages 10‰. The entire variation amounts to 1.8‰ in δ18O and 15‰ in δ2H. Quick changes of the isotopic composition within a few days emphasise the necessity of daily sampling for the investigation of hydrological events, while monthly grab sampling seems sufficient for the investigation of long-term hydro-climatic trends. 3H results show peaks (half-width 1–2 days, up to about 150 TU) exceeding the regional environmental level of about 9 TU, probably due to releases from nuclear power plants. 相似文献
127.
128.
Haschemi Nassab M Mitschke A Suchy MT Gutzki FM Zoerner AA Rhein M Hillemacher T Frieling H Jordan J Tsikas D 《The Analyst》2012,137(10):2480-2485
Common ethanol detection methods are not applicable to cell culture media and microdialysates due to interference with medium constituents including amino acids and pH indicators. We present a novel GC-MS method for the accurate and precise analysis of ethanol in cell cultures and microdialysates. The method is based on the carbonate-catalyzed extractive pentafluorobenzoylation of ethanol and deuterium-labelled ethanol serving as the internal standard and on their GC-MS analysis in the electron-capture negative-ion chemical ionization mode. The method was used to optimize experimental conditions in a custom-made ethanol vapour system utilized for studies examining ethanol influences on neuronal cell lines and in microdialysis. 相似文献
129.
Taft F Harmrolfs K Nickeleit I Heutling A Kiene M Malek N Sasse F Kirschning A 《Chemistry (Weinheim an der Bergstrasse, Germany)》2012,18(3):880-886
Access of four new tumor specific folic acid/ansamitocin conjugates is reported that relies on a synthetic strategy based on the combination of mutasynthesis and semisynthesis. Two bromo‐ansamitocin derivatives were prepared by mutasynthesis or by a modified fermentation protocol, respectively, that served as starting point for the semisynthetic introduction of an allyl amine linker under Stille conditions. A sequence of standard coupling steps introduced the pteroic acid/glutamic acid/cysteine unit to the modified ansamitocins. All new derivatives, including those that are expected to be generated after internalization of the folic acid/ansamitocin conjugates into the cancer cell and reductive cleavage of the disulfide linkage showed good to strong antiproliferative activity (IC50 <10 nM ) for different cancer cell lines. Finally, the four conjugates were exposed to two cancer cell lines [cervix carcinoma, KB‐3‐1 (FR+) and lung carcinoma, A‐459 (FR?)], the latter devoid of the membrane‐bound folic acid receptor (FR?). All four conjugates showed strong antiproliferative activity for the FR+ cancer cell line but were inactive against the FR? cell line. The synthetic strategy pursued is based on the combination of mutasynthesis and semisynthesis and proved to be powerful for accessing new ansamitocin derivatives that are difficult to prepare by total synthesis. 相似文献
130.
Redshaw C Elsegood MR Wright JA Baillie-Johnson H Yamato T De Giovanni S Mueller A 《Chemical communications (Cambridge, England)》2012,48(8):1129-1131
Vanadyl bearing calix[4]arene ligands have undergone evaluation against several cell lines, and show varying degrees of toxicity. For vanadyl complexed to a sulfonylcalix[4]arene, monitoring of the strong blue fluorescence revealed slow uptake kinetics. The complex is exclusively found in the cytoplasm of the cells and uptake is not due to active endocytotic mechanisms. 相似文献