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991.
992.
Mohandas T. Kumar C. Udhaya Krishnan G. Anantha Pillai M. Velayutham Sakthivel P. 《Crystallography Reports》2019,64(7):1103-1107
Crystallography Reports - The allyl 6-amino-5-cyano-4-(4-fluorophenyl)-2-methyl-4H-pyran-3-carboxylate, C17H15FN2O3, compound adopts a triclinic crystal system with the sp. gr. $$P\bar {1}$$, Z =... 相似文献
993.
994.
Kinetics and Thermodynamics of Formation and Electron‐Transfer Reactions of Surfactant Cobalt(III) Complexes Containing Polypyridyl Ligands with Fe(CN)64− in Microheterogeneous Environment
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Karuppiah Nagaraj Krishnan Senthil Murugan Pilavadi Thangamuniyandi Subramanian Sakthinathan 《国际化学动力学杂志》2015,47(3):174-182
The electron‐transfer reaction of some surfactant cobalt(III) complexes, cis‐[Co(ip)2(C12H25NH2)2]3+ 1 , cis‐[Co(dpq)2(C12H25NH2)2]3+ 2 , and cis‐[Co(dpqc)2(C12H25NH2)2]3+ 3 (ip = imidazo[4,5‐f][1,10]phenanthroline, dpq = dipyrido[3,2‐d:2′‐3′‐f]quinoxaline, dpqc = dipyrido[3,2‐a:2′,4′‐c](6,7,8,9‐tetrahydro)phenazine, C12H25NH2 = dodecylamine) with the Fe(CN)64? ion has been investigated in microheterogeneous media (micelles, β‐cyclodextrin) at different temperatures by the spectrophotometric method under pseudo‐first‐order conditions using an excess of the reductant. Experimentally, the reaction was found to be second order and the electron transfer postulated as an outer sphere. The rate constant for the electron‐transfer reaction in micelles was found to increase with an increase in the initial concentration of the surfactant–cobalt(III) complex. This peculiar behavior of dependence of the second‐order rate constant on the initial concentration of one of the reactants has been attributed to the presence of various concentrations of micelles under different initial concentrations of the surfactant–cobalt(III) complex in the reaction medium. Inclusion of the long aliphatic chain of the surfactant complex ion into β‐cyclodextrin leads to decrease in the rate constant. Kinetic data and activation parameters are interpreted in terms of an outer‐sphere electron‐transfer mechanism. All these results have been interpreted in terms of the hydrophobic effect and the reactants with the opposite charge. 相似文献
995.
The semiorganic crystal of sodium acid phthalate (NaAP) single crystals was grown in the solvent of water by slow evaporation method at room temperature. The single crystal X-ray diffraction studies showed the crystal belongs to orthorhombic system. The optical absorption spectrum reveals that the crystal has good transparency in entire visible region. The hardness number of the material is measured by microhardness tester. The fluorescence green colour emission exhibits is semiorganic. The SHG efficiency of NaAP crystal confirms NLO behaviour of green colour emission to provide frequency doubling process for photo electronic applications. 相似文献
996.
Balasubramanian Sridhar Jagadeesh Babu Nanubolu Krishnan Ravikumar 《Acta Crystallographica. Section C, Structural Chemistry》2015,71(7):602-609
Cocrystals are molecular solids composed of at least two types of neutral chemical species held together by noncovalent forces. Crystallization of thymine [systematic name: 5‐methylpyrimidine‐2,4(1H,3H)‐dione] with four phenolic coformers resulted in cocrystal formation, viz. catechol (benzene‐1,2‐diol) giving thymine–catechol (1/1), C5H6N2O2·C6H6O2, (I), resorcinol (benzene‐1,3‐diol) giving thymine–resorcinol (2/1), 2C5H6N2O2·C6H6O2, (II), hydroquinone (benzene‐1,4‐diol) giving thymine–hydroquinone (2/1), 2C5H6N2O2·C6H6O2, (III), and pyrogallol (benzene‐1,2,3‐triol) giving thymine–pyrogallol (1/2), C5H6N2O2·2C6H6O3, (IV). The resorcinol molecule in (II) occupies a twofold axis, while the hydroquinone molecule in (III) is situated on a centre of inversion. Thymine–thymine base pairing is common across all four structures, albeit with different patterns. In (I)–(III), the base pair is propagated into an infinite one‐dimensional ribbon, whereas it exists as a discrete dimeric unit in (IV). In (I)–(III), the two donor N atoms and one carbonyl acceptor O atom of thymine are involved in thymine–thymine base pairing and the remaining carbonyl O atom is hydrogen bonded to the coformer. In contrast, in (IV), just one donor N atom and one acceptor O atom are involved in base pairing, and the remaining donor N atom and acceptor O atom of thymine form hydrogen bonds to the coformer molecules. Thus, the utilization of the donor and acceptor atoms of thymine in the hydrogen bonding is influenced by the coformers. 相似文献
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998.
999.
Ranganathan Raja Dinesh Murugan Archana Sivasubramaniyan Jaabil George Sakthivel Perumal 《合成通讯》2016,46(11):942-948
Two different heterocycles, thiazole-2-imines and imidazole-2-thiones, have been conveniently synthesized by just altering the sequential order (1 + 2 + 3 or 1 + 3 + 2) when combining the same components [aryl amine (1), aryl isothiocyanate (2), and phenacyl bromide (3)] in one-pot, three-component protocols. The third possible sequential order of combination (2 + 3 + 1) chemoselectively affords thiazole-2-imine. The finding is a stepping stone in the synthetic applicability of sequential one-pot, three-component protocols. 相似文献
1000.