全文获取类型
收费全文 | 313篇 |
免费 | 20篇 |
国内免费 | 9篇 |
专业分类
化学 | 239篇 |
晶体学 | 1篇 |
力学 | 12篇 |
数学 | 21篇 |
物理学 | 69篇 |
出版年
2023年 | 1篇 |
2022年 | 8篇 |
2021年 | 13篇 |
2020年 | 17篇 |
2019年 | 12篇 |
2018年 | 16篇 |
2017年 | 8篇 |
2016年 | 17篇 |
2015年 | 10篇 |
2014年 | 17篇 |
2013年 | 36篇 |
2012年 | 27篇 |
2011年 | 28篇 |
2010年 | 24篇 |
2009年 | 17篇 |
2008年 | 16篇 |
2007年 | 11篇 |
2006年 | 18篇 |
2005年 | 9篇 |
2004年 | 8篇 |
2003年 | 5篇 |
2002年 | 7篇 |
2000年 | 1篇 |
1999年 | 3篇 |
1997年 | 1篇 |
1995年 | 1篇 |
1994年 | 1篇 |
1988年 | 1篇 |
1986年 | 1篇 |
1984年 | 3篇 |
1983年 | 1篇 |
1982年 | 1篇 |
1980年 | 3篇 |
排序方式: 共有342条查询结果,搜索用时 15 毫秒
71.
72.
Sedigheh Alavinia Ramin Ghorbani-Vaghei Jamshid Rakhtshah Jaber Yousefi Seyf Iman Ali Arabian 《应用有机金属化学》2020,34(3):e5449
A porous cross-linked poly (ethyleneamine)-polysulfonamide (PEA-PSA) as a novel organic support system is synthesized in the presence of silica template by nanocasting technique. The paper demonstrates immobilization of CuI nanoparticles inside the pores (PEA-PSA@CuI) for the facile recovery and recycling of these nanoparticles. The presence of porous PEA-PSA and PEA-PSA@CuI nanocomposites was confirmed using FT-IR spectroscopy, FE-SEM, EDX, TGA, XRD, TEM, BET, XPS, WDX, 1H NMR, and ICP-OES techniques. The PEA-PSA@CuI along with Ag(I)/K2S2O8 was implemented as a reusable cooperative catalyst-oxidant system in the N-arylation of p-toluenesulfonamide with substituted carboxylic acids in mild condition. So, the novel decarboxylative cross-coupling catalyzed by copper and silver has been developed. Aromatic, secondary and tertiary aliphatic acids underwent high efficient decarboxylative processes with p-toluenesulfonamide to afford the corresponding products. This method provides a practical approach for the flexible synthesis of sulfonamides from the readily affordable substrates. The catalyst is highly reusable and efficient, especially in terms of time and yield of the desired product. 相似文献
73.
74.
Vânia G. Zuin Mateus L. Segatto Luize Z. Ramin 《Current Opinion in Green and Sustainable Chemistry》2018
Over the last century, the conventional and linear production system has significantly influenced the socio-environment globally. The transition to a more circular production system, aiming at maintaining the value of products and resources for as long as possible, is an opportunity to create innovative processes that are regenerative by intention. This means replacing the end-of-life concept with restoration, renewable energy use and by- or co-products as well as eliminating toxic chemicals by developing and using redesigned materials, procedures and business models. In this context, the main objective of this paper is to present a critical overview related to the most recent green and sustainable extraction or separation approaches to remove organic molecules from plant-derived resources, specifically agro-industrial and forestry waste using circular processing systems in operation in the last four years. 相似文献
75.
Khosrow Jadidi Ramin Ghahremanzadeh Morteza Mehrdad Mohammad Ghanbari Hamid Arvin-Nezhad 《Monatshefte für Chemie / Chemical Monthly》2008,139(3):277-280
Summary. Novel N-alkyl-4-imino-1,4-dihydro-2H-3,1-benzoxazin-2-ones were synthesized in a single step by Baeyer–Villiger oxidation of N-alkyl-3-imino-2-indolinone derivatives in high yields. The structures of the products were determined by spectral data and
by X-ray diffraction. Besides their novel structures, these compounds may have important biological activities and industrial
applications. 相似文献
76.
Najmeh Edraki Aida Iraji Omidreza Firuzi Yousef Fattahi Mohammad Mahdavi Alireza Foroumadi Mehdi Khoshneviszadeh Abbas Shafiee Ramin Miri 《Journal of the Iranian Chemical Society》2016,13(12):2163-2171
The inhibition of AKR1B10 has been recognized as a potential therapeutic approach to the treatment of various types of cancers. A novel series of compounds with imino-2H-chromen and phenylimino-2H-chromen scaffolds were synthesized by Knoevenagel condensation reaction. The in vitro cytotoxic activity of synthesized compounds was evaluated against MOLT-4 and SK-OV-3 cells. Among the tested compounds, N-(3,4-dimethoxyphenyl)-2-(phenylimino)-2H-chromene-3-carboxamide (8g) demonstrated potent inhibitory activity against both examined cell lines. The results of the molecular docking study suggested that this compound is involved in critical hydrogen-bonding interactions with the Val301 and Lue302 of AKR1B10 catalytic site. 相似文献
77.
On the Landau-Levich transition 总被引:1,自引:0,他引:1
Maleki M Reyssat E Quéré D Golestanian R 《Langmuir : the ACS journal of surfaces and colloids》2007,23(20):10116-10122
We discuss here the nature of the Landau-Levich transition, that is, the dynamical transition that occurs when drawing a solid out of a bath of a liquid that partially wets this solid. Above a threshold velocity, a film is entrained by the solid. We measure the macroscopic contact angle between the liquid and the solid by different methods, and conclude that this angle might be discontinuous at the transition. We also present a model to understand this fact and the shape of the meniscus as drawing the solid. 相似文献
78.
Shuyan Li Ramin Vatanparast Elina Vuorimaa Helge Lemmetyinen 《Journal of Polymer Science.Polymer Physics》2000,38(17):2213-2220
The curing process of hexamethylene diisocyanate‐based polyurethane has been monitored by applying FTIR and DSC methods. A general relationship between glass‐transition temperature (Tg) and conversion of curing process has been obtained. This suggests that the reaction path and the relative reaction rates are independent of the curing temperature. The reaction kinetics of the system is analyzed using the Tg data converted to the conversion of the curing process. A set of experimental data and one theoretical model of Tg versus chemical conversion are presented to prove the assumption where a direct one‐to‐one relationship between the Tg (as measured) and the chemical conversion is obtained. Apparent activation energies (Ea) obtained by applying three different methods suggest good agreement. © 2000 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys 38: 2213–2220, 2000 相似文献
79.
80.
Ranjbar Sara Edraki Najmeh Firuzi Omidreza Khoshneviszadeh Mehdi Miri Ramin 《Molecular diversity》2019,23(2):471-508
Molecular Diversity - 5-Oxo-hexahydroquinoline (5-oxo-HHQ) represents a biologically attractive fused heterocyclic core. Various synthetic analogs of 5-oxo-HHQ have been synthesized and assessed... 相似文献