全文获取类型
收费全文 | 1127篇 |
免费 | 19篇 |
国内免费 | 2篇 |
专业分类
化学 | 617篇 |
晶体学 | 12篇 |
力学 | 81篇 |
数学 | 121篇 |
物理学 | 317篇 |
出版年
2022年 | 18篇 |
2020年 | 15篇 |
2019年 | 18篇 |
2018年 | 14篇 |
2017年 | 18篇 |
2016年 | 29篇 |
2015年 | 10篇 |
2014年 | 35篇 |
2013年 | 85篇 |
2012年 | 69篇 |
2011年 | 75篇 |
2010年 | 45篇 |
2009年 | 30篇 |
2008年 | 40篇 |
2007年 | 34篇 |
2006年 | 32篇 |
2005年 | 32篇 |
2004年 | 26篇 |
2003年 | 37篇 |
2002年 | 30篇 |
2001年 | 14篇 |
2000年 | 12篇 |
1999年 | 10篇 |
1998年 | 9篇 |
1997年 | 23篇 |
1996年 | 16篇 |
1995年 | 21篇 |
1994年 | 11篇 |
1993年 | 10篇 |
1992年 | 10篇 |
1991年 | 12篇 |
1990年 | 12篇 |
1989年 | 13篇 |
1988年 | 9篇 |
1987年 | 8篇 |
1986年 | 11篇 |
1985年 | 14篇 |
1984年 | 9篇 |
1983年 | 12篇 |
1982年 | 13篇 |
1981年 | 14篇 |
1980年 | 14篇 |
1979年 | 16篇 |
1978年 | 14篇 |
1977年 | 14篇 |
1976年 | 11篇 |
1974年 | 10篇 |
1973年 | 13篇 |
1941年 | 11篇 |
1936年 | 9篇 |
排序方式: 共有1148条查询结果,搜索用时 15 毫秒
21.
Y. Rama Krishna Sarma 《Annals of the Institute of Statistical Mathematics》1987,39(1):497-512
Summary In this note some asymptotically optimum tests for testing hypotheses concerning parameters when the observations are dependent
are obtained. Test statistics based on the score functions, similar to the one proposed by Rao in the case when the observations
are i.i.d. are proposed. Asymptotically UMP tests for one sided hypotheses against one sided alternatives and asymptotically
UMP unbiased test for a simple hypothesis against two sided alternatives are derived. In the multiparameter case tests for
simple hypotheses that have asymptotically best constant power on some family of surfaces in the parameter space are derived. 相似文献
22.
Amit Sircar Rajesh K. Dwivedi R. K. Thareja 《Applied physics. B, Lasers and optics》1996,63(6):623-627
An experimental investigation of laser-induced breakdown using Nd:YAG laser harmonics for argon, nitrogen and oxygen gases is reported. Pressure dependence as well as wavelength dependence of the breakdown threshold irradianceI
th is investigated. The experimental observations for 1.064 and 0.532 m laser wavelengths are in agreement with theoretical calculations which include the effects of multiphoton ionization and cascade ionization. 相似文献
23.
A systematic investigation of 62 r MeV proton irradiated Poly(ethylene terephthalate) (PET) has been carried out using Fourier Transformed Infrared Spectroscopy, thermogravimetric analysis, differential scanning calorimetry and X-ray diffraction spectroscopy. The experiments revealed a restoration of the crystalline matrix and simultaneous decrease in thermal stability in the irradiated polymer as a function of dose, indicating that PET underwent both degradation and cross-linking by proton irradiation. 相似文献
24.
Bhogi Jai Rama Satyanarayana Swamy Rangu Vijay Pamidi Ramesh Babu Bhaskar Sanyal Yerramreddy Gandhi Nalluri Veeraiah 《Ionics》2016,22(9):1625-1634
γ-Ray-induced dielectric dispersion in CaF2–B2O3–P2O5 glasses doped with different concentrations of CuO was investigated. The glass samples were exposed to γ-rays with dose varying within the range 0–10 kGy. The dielectric dispersion and spectroscopic properties were measured before and after γ-ray treatment. Additionally, thermoluminescence studies were performed on post-irradiated glass samples. The results of dielectric properties and dielectric breakdown strength indicated a substantial increase in the insulating strength of CuO containing glasses due to γ-ray irradiation. The analysis of these results together with UV-vis optical absorption, IR spectra, and thermoluminescence studies have indicated a gradual increase in the concentration of mono-valent copper ions due to γ-ray treatment of the glass network. The additional studies have confirmed that these Cu+ ions occupy network-forming positions, increase the polymerization of the borophosphate glass network, and facilitates for the increase of insulating strength of the titled glass. 相似文献
25.
26.
Density functional theory (DFT) of freezing is used to study the isotropic–nematic, isotropic–smectic A and nematic–smectic A phase transitions in a system of large, semi-flexible conjugated oligomers parameterised within Gay–Berne (GB) potential. The pair correlation functions of the isotropic fluid, used as structural inputs in the DFT, are calculated by solving the Percus–Yevick integral equation theory. Large number of spherical harmonic coefficients of each orientation-dependent functions has been considered to ensure the numerical accuracy at different densities and temperatures for the system of these model GB ellipsoids having large aspect ratio (length-to-breadth ratio). We found that the system of GB ellipsoids parameterised for conjugated oligomers shows stable isotropic, nematic and smectic A phases. At low temperatures, on increasing the density, isotropic fluid makes a direct transition to smectic A phase. Nematic phase get stabilised in between the isotropic and smectic A phases on increasing the temperature. Using the transition parameter obtained through the DFT, we have plotted the temperature–density and pressure–temperature phase diagrams which are found to be qualitatively similar to the one obtained in simulations for the systems with low aspect ratio GB particles. 相似文献
27.
Summary Xylenol orange reacts very sensitively with gallium(III), indium (III) and thallium(III) to form reddish violet colored chelates having max 560 nm in case of Ga and In and max 590 nm in case of Ti at PH 4.0. The molar ratio for all the chelates is 1 1 (metal reagent). Optimum conditions including the range for adherence to Beer's law, effect of PH on the color intensity, effect of excess reagent, and sensitivity are reported for the photometric determination of these metal ions using Xylenol orange.
Zusammenfassung Xylenolorange reagiert sehr empfindlich mit Gallium(III), Indium(III) und Thallium(III) unter Bildung rötlich-violetter Chelate mit einem Absorptionsmaximum bei 560 nm im Falle von Ga und In bzw. 590 nm für Tl bei pH 4,0. Das Molverhältnis ist in jedem Fall 11. Die besten Arbeitsbedingungen, der Gültigkeitsbereich des Beerschen Gesetzes, der Einfluß des PH auf die Farbintensität und des Reagensüberschusses sowie die Empfindlichkeit werden für die photometrische Bestimmung der genannten Ionen angegeben.相似文献
28.
The use of dimedone in green chemistry has been described for the synthesis of selective heterocyclic motifs which are both pharmacologically and industrially important. The objective of this review is to summarize some of the selected recent advances of dimedone in the synthesis of organic compounds utilizing green chemistry procedures. 相似文献
29.
30.
Sancheeta Kolay Kallol K. Ghosh Amy MacDonald Jonathan Moulins Rama M. Palepu 《Journal of solution chemistry》2008,37(1):59-72
The thermodynamics of micellization and other micellar properties of alkyl- (C10-, C12-, C14- and C16-) triphenylphosphonium bromides in water + ethylene glycol (EG) (0 to 30% v/v) mixtures over a temperature range of 298 to
318 K and cetyltriphenylphosphonium bromide in water + diethylene glycol (DEG) mixtures (0 to 30% v/v) at 298 K have been
studied conductometrically. In all cases, an increase in the percentage of co-solvent results in an increase in the cmc values.
On the basis of these results, the thermodynamic parameters, the Gibbs energy (ΔG
mo), enthalpy (ΔH
mo) and entropy (ΔS
mo) of micellization have been evaluated. In addition to the conductivity measurements, kinetic experiments have also been done
to determine the dependence of observed rate constant for the nucleophilic substitution reaction of p-nitrophenyl acetate and benzohydroxamate ions in the presence of the surfactant cetyltriphenylphosphonium bromide with a
varying concentration of EG and DEG ranging from 0 to 50% v/v at pH=7.9 and 300 K. All of the reactions followed pseudo-first-order
kinetics. An increase in the surfactant concentration results in an increase in the reaction rate and for a given surfactant
concentration, the rate constant decreases as the concentration of co-solvent in the mixture increases. The kinetic micellar
effects have been explained by using the pseudophase model. The thermodynamic and structural changes originating from the
presence of solvents control the micellar kinetic effects. 相似文献