全文获取类型
收费全文 | 266篇 |
免费 | 5篇 |
国内免费 | 3篇 |
专业分类
化学 | 197篇 |
晶体学 | 2篇 |
力学 | 1篇 |
数学 | 34篇 |
物理学 | 40篇 |
出版年
2023年 | 2篇 |
2022年 | 6篇 |
2021年 | 10篇 |
2020年 | 9篇 |
2019年 | 6篇 |
2018年 | 5篇 |
2017年 | 3篇 |
2016年 | 8篇 |
2015年 | 8篇 |
2014年 | 9篇 |
2013年 | 21篇 |
2012年 | 16篇 |
2011年 | 11篇 |
2010年 | 16篇 |
2009年 | 14篇 |
2008年 | 13篇 |
2007年 | 17篇 |
2006年 | 14篇 |
2005年 | 9篇 |
2004年 | 11篇 |
2003年 | 9篇 |
2002年 | 6篇 |
2001年 | 1篇 |
2000年 | 2篇 |
1999年 | 1篇 |
1995年 | 1篇 |
1988年 | 1篇 |
1985年 | 1篇 |
1980年 | 1篇 |
1979年 | 2篇 |
1976年 | 2篇 |
1975年 | 1篇 |
1973年 | 1篇 |
1948年 | 2篇 |
1944年 | 4篇 |
1943年 | 6篇 |
1942年 | 1篇 |
1939年 | 5篇 |
1938年 | 2篇 |
1937年 | 1篇 |
1936年 | 3篇 |
1935年 | 3篇 |
1934年 | 3篇 |
1933年 | 4篇 |
1932年 | 2篇 |
1931年 | 1篇 |
排序方式: 共有274条查询结果,搜索用时 140 毫秒
61.
Raluca Ripan 《Fresenius' Journal of Analytical Chemistry》1943,125(1-2):38-40
Ohne Zusammenfassung 相似文献
62.
Raluca Nicoleta Darie Mihai Brebu Cornelia Vasile Marek Kozlowski 《Polymer Degradation and Stability》2003,80(3):551-566
Binary isotactic polypropylene (IPP)/polyamide 6 (PA6) and ternary IPP/PA6/ethylene–propylene diene terpolymer (EPDM) blends in various ratios were obtained in a Haake Rheocord mixer. Processing behaviour was changed in the presence of IPP functionalized with bismaleimide (BMI), maleic anhydride (MA) and acrylic acid (AA) as reactive compatibilizing agents. The thermal and thermo-oxidative behaviour of blends was studied by differential scanning calorimetry and thermogravimetry. The functionalized IPPs modify the crystallinity degree and the decomposition behaviour of both IPP and PA6 as a result of chemical reactions of functional groups with those of the PA6. The changes depend on the IPP/PA6 or IPP/PA6/EPDM ratio, the chemical nature and amount of the functionalized IPP. On the basis of the processing and thermal data one can conclude that the compatibilizing agent effect increases in the following order: IPP-AA 相似文献
63.
Spectrophotometric determination of magnesium in pharmaceutical preparations by cost-effective sequential injection analysis 总被引:1,自引:0,他引:1
A simple and rapid, inexpensive spectrophotometric method was proposed for magnesium assay in pharmaceutical preparations by sequential injection analysis (SIA). The method is based on the reaction between o-cresolphthalein complexone (CPC) and Mg(II) in alkaline media, yielding a pink colored complex with absorption maximum at 570 nm. Since the formation constant between Ca-CPC and Mg-CPC is similar, initially a sample/standard solution was aspirated into the holding coil followed by a mixture of masking-buffer solutions. This was done because masking of calcium should be accomplished before Mg-CPC complexation. Then the reagent was introduced into the reaction coil to produce a colored complex, which is measured spectrophotometrically at 570 nm. In this way the interference of calcium was reduced. Furthermore, all the parameters that affect the reaction were evaluated. The calibration curve is linear over a range of 0-20 mg l−1 of Mg(II) with a detection limit of 0.24 mg l−1. A sample throughput of 80 samples per hour and relative standard deviation <2.0% were achieved. The proposed method was successfully applied for the assay of magnesium in three different compositions of pharmaceutical preparations (tablets). The results were found to be in good agreement with the manual flame atomic absorption spectrophotometry (FAAS) and UV-Vis spectrophotometry methods and with the claimed values by the manufactures. The t-test shows no significant difference at 95% confidence level. 相似文献
64.
Catalina Cioates Negut Raluca‐Ioana Stefan‐van Staden Florian Harja Jacobus Frederick van Staden 《Electroanalysis》2020,32(1):7-10
New synthesized fatty acid amides (N‐(2‐(piperidin‐1‐yl)ethyl)oleamide, and N‐(2‐(pyrrolidin‐1‐yl)ethyl)oleamide) were used for the design of stochastic sensors based on nanographene paste. The stochastic sensors were used for pattern recognition of four amino acids: L‐histidine, L‐tyrosine, L‐ornithine, and L‐lysine in wines. The pattern recognition was performed based on the signatures recorded for each of the amino acids. The limits of determination allow the assay of amino acids in wine at very low concentrations faster, reliable, and more cost effective than other methods proposed to date. 相似文献
65.
Raluca Popescu Diana Costinel Damian Axente 《Isotopes in environmental and health studies》2014,50(4):461-474
One of the most important tributaries of the Danube River in Romania, the Olt River, was characterized in its middle catchment in terms of the isotopic composition using continuous flow–isotope ratio mass spectrometry (CF–IRMS). Throughout a period of 10 months, from November 2010 to August 2011, water samples from the Olt River and its more important tributaries were collected in order to investigate the seasonal and spatial isotope patterns of the basin waters. The results revealed a significant difference between the Olt River and its tributaries, by the fact that the Olt River waters show smaller seasonal variations in the stable isotopic composition and are more depleted in 18O and 2H. The waters present an overall enrichment in heavy isotopes during the warm seasons. 相似文献
66.
Marcela Stoia Mircea Stefanescu Thomas Dippong Oana Stefanescu Paul Barvinschi 《Journal of Sol-Gel Science and Technology》2010,54(1):49-56
The paper presents a study on the preparation of Co2SiO4/SiO2 nanocomposites by a new modified sol–gel method. We have prepared gels starting from tetraethylorthosilicate (Si(OC2H5)4), cobalt nitrate Co(NO3)2·6H2O and some diols: ethylene glycol (C2H6O2), 1,2propanediol (C3H8O2) and 1,3propanediol (C3H8O2), for a final composition: 30% CoO/70% SiO2. During the heating of the gels at 140 °C, a redox reaction takes place between NO3
− ions and diol with formation of some carboxylate anions. These carboxylate anions react with the Co(II) ions to form coordination
compounds embedded in silica matrix, as evidenced by FT-IR spectrometry and thermal analysis. These Co(II) coordinative compounds
thermally decompose in the range 250–300 °C to the corresponding oxides: CoO and/or Co3O4 inside the matrices pores. When CoO results, it reacts with SiO2 at low temperature leading to Co2SiO4, which crystallizes at 700 °C. XRD patterns of the samples annealed at temperatures lower than 700 °C were characteristic
to amorphous phases. The samples annealed at temperatures ≥700 °C, contain Co2SiO4 (olivine) as unique crystalline phase inside the amorphous silica matrix, according to XRD patterns. As evidenced by TEM
images, Co2SiO4 nanoparticles are homogenously dispersed inside the silica matrix. 相似文献
67.
Rosu T Pasculescu S Lazar V Chifiriuc C Cernat R 《Molecules (Basel, Switzerland)》2006,11(11):904-914
The synthesis of Cu(II) complexes derived from Schiff base ligands obtained by the condensation of 2-hydroxybenzaldehyde or terephtalic aldehyde with 4-amino-antipyrine (4-amino-2,3-dimethyl-1-phenyl-3-pyrazolin-5-one) is presented. The newly prepared compounds were characterized by( 1)H-NMR, UV-VIS, IR and ESR spectroscopy. The determination of the antimicrobial activity of the ligands and of the complexes was carried out on samples of Escherichia coli, Klebsiella pneumoniae, Acinetobacter boumanii, Pseudomonas aeruginosa, Staphylococcus aureus and Candida sp. The qualitative and quantitative antimicrobial activity test results proved that all the prepared complexes are very active, especially against samples of Ps. aeruginosa, A. Boumanii, E. coli and S. aureus. 相似文献
68.
Cho H Felmy AR Craciun R Keenum JP Shah N Dixon DA 《Journal of the American Chemical Society》2006,128(7):2324-2335
Evidence for nine new solution state silicate oligomers has been discovered by (29)Si NMR homonuclear correlation experiments of (29)Si-enriched samples. In addition to enhancing signal sensitivity, the isotopic enrichment increases the probability of the (29)Si-(29)Si two-bond scalar couplings that are necessary for the observation of internuclear correlations in 2-D experiments. The proposed assignments are validated by comparisons of experimental and simulated cross-peaks obtained with high digital resolution. The internuclear connectivity indicated by the NMR data suggests that several of these oligomers can have multiple stereoisomers, including conformers and/or diastereomers. The stabilities of these oligomers and their possible stereoisomers have been investigated by electronic structure calculations. 相似文献
69.
This paper presents results which advance and improve the usefulness, accuracy and efficiency of incremental centre hole drilling
as a method of measuring near surface residual stress fields. Particular emphasis is placed on providing optimal values for
the number of drilling step increments to be used and their corresponding size. Guidelines on the optimal values for the number
and size of steps to use during measurements are presented for various ratios of hole radius to strain gauge rosette radius
in the form of tabulated data. These guidelines are subsequently incorporated into a new data analysis program which permits
very near surface residual stress fields to be accurately determined in real components. The benefits of the new approach
are highlighted by reporting the results of measurements made on three industrial components, each of which has been subjected
to a well-known engineering process. These components are a shot-peened spring-steel, a friction stir welded aluminium alloy,
and a titanium alloy subjected to three different machining processes. The results reveal that the improvements to the incremental
centre hole drilling technique can provide measured residual stresses from depths ranging from about 10
m to 1 mm. 相似文献
70.
Porphyrins and metalloporphyrins fulfil a very important role in the metabolism of living organisms through biological pigments or biochromes and are therefore also employed in numerous applications in analytical chemistry. In flow-injection analysis the role of porphyrins and metalloporphyrins are centered as either that of analyte or that of a reagent or modifier in the determination of other species. This paper covers the attributes of porphyrin and metallophorphyrin complexes as enhancements in chemical analysis in flow-injection systems and points out the advantages and disadvantages in the implementation thereof. 相似文献