首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   2158篇
  免费   52篇
  国内免费   10篇
化学   1310篇
晶体学   19篇
力学   45篇
数学   466篇
物理学   380篇
  2021年   16篇
  2020年   23篇
  2019年   26篇
  2018年   15篇
  2017年   19篇
  2016年   36篇
  2015年   36篇
  2014年   33篇
  2013年   101篇
  2012年   89篇
  2011年   101篇
  2010年   61篇
  2009年   52篇
  2008年   99篇
  2007年   95篇
  2006年   103篇
  2005年   108篇
  2004年   76篇
  2003年   87篇
  2002年   95篇
  2001年   27篇
  2000年   39篇
  1999年   32篇
  1998年   32篇
  1997年   31篇
  1996年   32篇
  1995年   16篇
  1994年   37篇
  1993年   31篇
  1992年   26篇
  1991年   26篇
  1990年   26篇
  1989年   19篇
  1988年   16篇
  1987年   19篇
  1986年   18篇
  1985年   21篇
  1984年   34篇
  1983年   25篇
  1982年   37篇
  1981年   39篇
  1980年   31篇
  1979年   23篇
  1978年   32篇
  1977年   25篇
  1976年   23篇
  1975年   19篇
  1974年   22篇
  1973年   22篇
  1971年   17篇
排序方式: 共有2220条查询结果,搜索用时 15 毫秒
51.
Quantum computing using two coherent states as a qubit basis is a proposed alternative architecture with lower overheads but has been questioned as a practical way of performing quantum computing due to the fragility of diagonal states with large coherent amplitudes. We show that using error correction only small amplitudes (alpha>1.2) are required for fault-tolerant quantum computing. We study fault tolerance under the effects of small amplitudes and loss using a Monte Carlo simulation. The first encoding level resources are orders of magnitude lower than the best single photon scheme.  相似文献   
52.
The structural characteristics of olivine-type lithium orthophosphate Li(Mg0.5Ni0.5)PO4 synthesized via solid-state reaction have been studied using X-ray diffraction, ion beam technique, scanning electron microscopy, infrared spectroscopy, transmission electron microscopy and energy dispersive X-ray analysis. The parent LiNiPO4 compound can be synthesized in olivine structure without any evidence of secondary phases as impurities. The structural quality of the parent LiNiPO4 in the absence of secondary component phases resulted in the formation of hexagonal closed packed structure. The olivine analogue compound containing mixed M (M?=?Mg, Ni) cations, Li(Mg0.5Ni0.5)PO4 contained Li3PO4 as a second phase upon synthesis, however a carbothermal reduction method produced a single-phase compound. The redox behaviour of carbon-coated Li(Mg0.5Ni0.5)PO4 cathode in aqueous lithium hydroxide as the electrolyte showed reversible lithium intercalation.  相似文献   
53.
54.
Rapid initiation of reactions in Al/Ni multilayers with nanoscale layering   总被引:3,自引:0,他引:3  
Research into nanoenergetic materials is enabling new capabilities for controlling exothermic reaction rates and energy output, as well as new methods for integrating these materials with conventional electronics fabrication techniques. Many reactions produce primarily heat, and in some cases it is desirable to increase the rate of heat release beyond what is typically observed. Here we investigate the Al-Ni intermetallic reaction, which normally propagates across films or foils at rates lower than 10 m/s. However, models and experiments indicate that local heating rates can be very high (107 K/s), and uniform heating of such a multilayer film can lead to a rapid, thermally explosive type of reaction. With the hopes of using a device to transduce electrical energy to kinetic energy of a flyer plate in the timescale of 100's of nanoseconds, we have incorporated a Ni/Al nanolayer film that locally heats upon application of a large electrical current. We observed flyer plate velocities in the 2-6 km/s range, corresponding to 4-36 kJ/g in terms of specific kinetic energy. Several samples containing Ni/Al films with different bilayer thicknesses were tested, and many produced additional kinetic energy in the 1.1-2.3 kJ/g range, as would be expected from the Ni-Al intermetallic reaction. These results provide evidence that nanoscale Ni/Al layers reacted in the timescale necessary to contribute to device output.  相似文献   
55.
A method has been developed for determining the polarization state of the retro-reflected beam from a corner cube irradiated with an input beam of arbitrary polarization state and of arbitrary tilt angle to the cube. Experimentally, the output beam consists of six distinct beamlets of different polarization states that are focused into six non-overlapping regions in the active area of the detector. The overall polarization state of the beam as measured by the photodetector can thus be represented by the incoherent superposition of the polarization states of the six beamlets. Experiments have been performed that verify the theory for a linearly polarized input beam irradiating the corner cube.  相似文献   
56.
Variations in large-scale seafloor slope and average seabed sound speed account for a significant portion of the variations in scattering intensity observed in low-grazing-angle monostatic reverberation. Numerical modeling using a finite-difference solution to the elastic wave equation is used to quantify the effect of these large-scale parameters in interpretations of reverberation data. For hard rough seafloor (e.g., basalt), the results of the modeling suggest that the monostatic backscattering strength increases with increasing large-scale seafloor slope up to a slope of about 15 degrees dipping toward the incident direction. Once the grazing angle of the incident wavefield exceeds the critical grazing angle for the flat reference seafloor the backscattering intensity increases only slowly with increasing grazing angle. Similarly, average subseafloor sound speed has a significant effect. Seafloor with low sound speeds characteristic of soft bottoms (e.g., sediment) generate significantly weaker backscatter signals than seafloor with sound speeds characteristic of hard bottoms (e.g., basalt). The difference is that the shear waves can always be passed into soft bottoms because even for a flat seafloor there is no shear wave critical grazing angle.  相似文献   
57.
Using the atomic beam magnetic resonance method the Zeeman interactions of12C in the3 P 1 and3 P 2 states at magnetic fields of about 3.4 kOe have been measured. The measured quantities areg J (3 P 1)?gJ(3 P 2)=15.4(1.0)·10?6 g J (3 P 2)=1.5010616 (50), from which the following value for gJ(3P1) can be calculated:g J (3 P 1)=1.5010770 (50). The experimental results are in moderate agreement with theoretical calculations.  相似文献   
58.
A relatively weak ESR spectrum is observed in single crystals of NaN3 after X-ray irradiation at 77 K. This spectrum, which has an anisotropic g value and exhibits a resolved 5-line hyperfine structure with components in the ratio 1:2:3:2:1, corresponds to a single unpaired electron interacting symmetrically with two spin-one nuclei, in three inequivalent sites. The spin-Hamiltonian parameters are: gx = 2.0054 ± 0.0005, gy = 2.0045 ± 0.0005, gz = 1.9688 ± 0.0005, |Ax| = 4.0 ± 0.2 G, |Ay| = 20.0 ± 0.2 G, and |Az| = 4.9 ± 0.2 G, c-axis, and y is perpendicular to the c-axis. This spectrum, which is clearly different from that of substitutional N2?reported by Gelerinter and Silsbee, is attributed to interstitial N2?.  相似文献   
59.
An elementary theory for a radiation field with any spinJ is presented. This is a natural extension of Maxwell's equations for the electromagnetic field. The idea is to use the generators for theU(2) group in a multidimensional representation. These generators are a linear combination of the ones for infinitesimal Lorentz transformations. The constants of the motion in this formalism are discussed. As an example, angular distributions of the Poynting vector are given.Supported in part by grants from the Research Corporation and the Mitsubishi Fund.Parts of this work were done in partial fulfilment of the requirements for the M.A. Degree at Western Michigan University.  相似文献   
60.
Abstract

Ten homologous series (n-butyl through n-decyl) of aldose S,S-acetals (D-glucose, D-galactose, D-mannose, L-rhamnose, 2-deoxy-D-glucose, D-xylose, D-lyxose, D- or L-arabinose, D-ribose and 2-deoxy-D-ribose) have been prepared. Most of these compounds form thermotropic liquid crystals, the exceptions being the entire L-rhamnose series and some of the derivatives with the shortest alkyl chains. All of the compounds have been investigated with differential scanning calorimetry and polarization microscopy. Some temperature dependent powder X-ray data are also presented. A model is proposed which correlates the carbohydrate configuration with the melting behaviour. On the basis of now available behaviourial characteristics, visual inspection, mixing experiments and precedent, the mesophase is identified as smectic Ad, the partially overlapping carbohydrate moieties being in the centre and the aliphatic chains pointing outward at an angle of about 62°. Despite the intrinsic chirality of all the carbohydrate mesogens, no evidence for chiral mesophases was found, not even after introduction of a homochiral branched alkyl chain.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号