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901.
902.
C. Reinhardt R. Kiyan S. Passinger A.L. Stepanov A. Ostendorf B.N. Chichkov 《Applied Physics A: Materials Science & Processing》2007,89(2):321-325
Renewed and growing interest in the field of surface plasmon polaritons (SPPs) comes from a rapid advance of nanostructuring
technologies. In this paper, we will report on the application of two-photon polymerization (2PP) technique for the fabrication
of dielectric SPP-structures, which can be used for localization, guiding, and manipulation of SPPs on a subwavelength scale.
This technology is based on nonlinear absorption of near-infrared femtosecond laser pulses. Resolutions down to 100 nm (and
even better) are already achievable. Characterization of these structures is performed by leakage radiation microscopy. 2PP
allows the fabrication of dielectric waveguides, splitters, and couplers directly on metal surfaces. The dielectric structures
on metal films are demonstrated to be very efficient for the excitation of SPPs. Using these structures, one can achieve excitation
and focusing of the resulting plasmon field.
PACS 42.70.Gi; 42.70.Jk; 42.82.Cr; 71.36.+c; 78.20.-e 相似文献
903.
D-amino acids were determined in brain, body fluids (urine, blood coagulate, serum, plasma) and faeces of animals belonging to nine out of 11 taxonomic orders of vertebrates (Artiodactyla, Aves, Carnivora, Lagomorpha, Marsupalia, Osteichthyes, Primates, Rodentia, Tubilidentata). Free amino acids were isolated by means of cation exchangers and converted into volatile N(O)-perfluoroacylamino acid propyl esters. Derivatives of amino acids were separated into D- and L-enantiomers using Chirasil-L-Val capillary columns and detected by selected ion monitoring mass spectrometry. Quantification of amino acids was achieved by comparison of analytes with amino acid standards using L-norleucine as internal standard. Large relative amounts of D-serine were determined in brains of mammals but not of birds. In body fluids the D-enantiomers of most proteinogenic L-amino acids were detected, largest absolute and relative amounts were found in urine. Therein quantities of D-Ala and D-Ser exceeded 50% relative to the L-enantiomers in many instances. Feeding animals with diet fortified with DL-Met resulted in excretion of almost racemic Met in urine. D-Amino acids were also abundant in faeces of rodents. The data confirm that d-amino acids are common in body fluids and certain tissues of vertebrates. 相似文献
904.
Baret JC Decré M Herminghaus S Seemann R 《Langmuir : the ACS journal of surfaces and colloids》2005,21(26):12218-12221
The complex morphologies of liquids on topographically structured substrates are exploited for liquid actuation in open microchannels. The liquid is either confined in prefabricated grooves, thus forming elongated filaments, or gathers in macroscopic drops without invading the grooves, depending on conditions. Using the electrowetting effect, we can reversibly switch between these two states. The length of the filaments is sensitive to the ionic content of the liquid and can be described quantitatively with an electrical model considering the voltage drop along the groove. 相似文献
905.
Hertle R 《Current protein & peptide science》2005,6(4):313-325
The Serratia marcescens hemolysin represents the prototype of a growing family of pore forming toxins. The available bacterial genome sequences reveal Serratia hemolysin homologues in additional species. However, only S. marcescens hemolysin has been studied in great molecular detail. This family of toxins has nothing in common with the pore forming toxins of E. coli type (RTX toxins), the Staphylococcus aureus alpha-toxin or the thiol activated toxin of group A beta-hemolytic streptococci (Streptolysin O). Studies on erythrocytes, eukaryotic cells and artificial black lipid membranes, have shown that the mechanism of pore formation of ShlA is different form other pore forming toxins. The S. marcescens hemolysin proteins ShlB and ShlA, exhibit protein sequence homologues in Proteus mirabilis, Haemophilus ducreyi, Yersinia pestis, Yersinia enterocolitica, Edwardsiella tarda, Photorhabdus luminescens and Xylella fastidiosa . The family of Serratia type pore forming toxins show a unique secretory mechanism which has been described as a two partner secretion system (TPSS) or type V-secretion system. Not only Serratia type pore forming toxins are secreted via TPSS but also adhesins from Bordetella pertussis, Erwinia chrysanthemi and Haemophilus influenzae. The uniqueness of the Serratia family is underlined by the fact that activation of ShlA by ShlB strictly requires phosphatidylethanolamine as a cofactor. And, quite unusual, ShlA undergoes a conformational change during activation. 相似文献
906.
Ulrich R Glaser RW Ulrich AS 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2003,164(1):115-127
In solid state NMR analysis of oriented biomembranes the samples typically have the shape of a rectangular block, formed by stacking a number of glass slides coated with the membranes under investigation. Reference material may be provided internally in the volume of the block or as an external layer on its surface, as described in the accompanying paper [J. Magn. Reson. 164 (2003) 104-114]. The demagnetizing field resulting in such non-spheroidal samples is inhomogeneous. It shifts and broadens the NMR lines of both the sample and of the reference, as compared to the ideal of a spherical sample. The magnitude of these effects is typically of the order of a few ppm. To determine the necessary corrections, a general analysis is presented here for the demagnetizing field of a layered sample of rectangular block geometry, with the normal of the layers parallel to the main field or tilted about an axis of the block. The correction to the line position of the block sample is found to be approximately equal to that of the spheroid which can be inscribed into the block, and for which the correction is well known. For an external reference layer, placed on top of the block, the correction can be found by the same approximation, invoking a simple mirror concept. The layered structure of the block can be accounted for by using an average magnetic susceptibility. Sample and support materials contribute to that average according to their volume filling factors. If the sample material is anisotropic at the molecular level, as e.g. lipid bilayers are, the resulting anisotropy of the block is reduced by the filling factor of the sample material. 相似文献
907.
Dettlaff-Weglikowska U Skákalová V Graupner R Jhang SH Kim BH Lee HJ Ley L Park YW Berber S Tománek D Roth S 《Journal of the American Chemical Society》2005,127(14):5125-5131
Chemical modification by SOCl2 of an entangled network of purified single-wall carbon nanotubes, also known as 'bucky paper', is reported to profoundly change the electrical and mechanical properties of this system. Four-probe measurements indicate a conductivity increase by up to a factor of 5 at room temperature and an even more pronounced increase at lower temperatures. This chemical modification also improves the mechanical properties of SWNT networks. Whereas the pristine sample shows an overall semiconducting character, the modified material behaves as a metal. The effect of SOCl2 is studied in terms of chemical doping of the nanotube network. We identified the microscopic origin of these changes using SEM, XPS, NEXAFS, EDX, and Raman spectroscopy measurements and ab initio calculations. We interpret the SOCl2-induced conductivity increase by p-type doping of the pristine material. This conclusion is reached by electronic structure calculations, which indicate a Fermi level shift into the valence band, and is consistent with the temperature dependence of the thermopower. 相似文献
908.
We generalize (A), which was introduced in [Sch], to larger cardinals. For a regular cardinal >0 we denote by (A) the statement that and for all regular >,is stationary in It was shown in [Sch] that can hold in a set-generic extension of L. We here prove that can hold in a set-generic extension of L as well. In both cases we in fact get equiconsistency theorems. This strengthens results of [Rä00] and [Rä01]. is equivalent with the existence of 0#.Mathematics Subject Classification (1991): Primary 03E55, 03E15, Secondary 03E35, 03E60 相似文献
909.
The translocation of structured RNA or DNA molecules through narrow pores necessitates the opening of all base pairs. Here, we study the interplay between the dynamics of translocation and base pairing theoretically, using kinetic Monte Carlo simulations and analytical methods. We find that the transient formation of base pairs that do not occur in the ground state can significantly speed up translocation. 相似文献
910.
It is demonstrated that the propagation of electromagnetic waves in an appropriately designed waveguide is (for large wavelengths) analogous to that within a curved space-time--such as around a black hole. As electromagnetic radiation (e.g., microwaves) can be controlled, amplified, and detected (with present-day technology) much easier than sound, for example, we propose a setup for the experimental verification of the Hawking effect. Apart from experimentally testing this striking prediction, this would facilitate the investigation of the trans-Planckian problem. 相似文献