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61.
62.
We have undertaken the molecular imprinting of Leu5-enkephalin, and derivatives related to this endogenous neuropeptide, in highly cross-linked methacrylic acid/ethylene dimethacrylate copolymers. The underivatized enkephalin peptide yielded polymers with poor recognition abilities, since the imprinting of this compound had to be performed using dimethyl sulfoxide, which was found to interfere with the imprint inducement, as the solvent of polymerisation. In order to circumvent this problem, the amino- and carboxy-protected derivatives Boc-Leu5-enkephalin and Leu5-enkephalin anilide, which are soluble in apolar solvents, were investigated as alternative imprint molecules. Both compounds led to polymers which are highly specific for the imprint species. The anilide derivative was shown to be a good substitute for the free peptide since the resultant polymers showed efficient recognition of the parent enkephalin structure. 相似文献
63.
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65.
Emily K. Roesner Darya Asheghali Alina Kirillova Michael J. Strauss Austin M. Evans Matthew L. Becker William R. Dichtel 《Chemical science》2022,13(8):2475
Supramolecular nanotubes prepared through macrocycle assembly offer unique properties that stem from their long-range order, structural predictability, and tunable microenvironments. However, assemblies that rely on weak non-covalent interactions often have limited aspect ratios and poor mechanical integrity, which diminish their utility. Here pentagonal imine-linked macrocycles are prepared by condensing a pyridine-containing diamine and either terephthalaldehyde or 2,3,5,6-tetrafluoroterephthalaldehyde. Atomic force microscopy and synchrotron in solvo X-ray diffraction demonstrate that protonation of the pyridine groups drives assembly into high-aspect ratio nanotube assemblies. A 1 : 1 mixture of each macrocycle yielded nanotubes with enhanced crystallinity upon protonation. UV-Vis and fluorescence spectroscopy indicate that nanotubes containing both arene and perfluoroarene subunits display spectroscopic signatures of arene–perfluoroarene interactions. Touch-spun polymeric fibers containing assembled nanotubes prepared from the perhydro- or perfluorinated macrocycles exhibited Young''s moduli of 1.09 and 0.49 GPa, respectively. Fibers containing nanotube assemblies reinforced by arene–perfluoroarene interactions yielded a 93% increase in the Young''s modulus over the perhydro derivative, up to 2.1 GPa. These findings demonstrate that tuning the chemical composition of the monomeric macrocycles can have profound effects on the mechanical strength of the resulting assemblies. More broadly, these results will inspire future studies into tuning orthogonal non-covalent interactions between macrocycles to yield nanotubes with emergent functions and technological potential.Arene–perfluoroarene interactions resulted in enhanced crystallinity between analogous perhydro- and perfluoro macrocycles in a supramolecular nanotube assembly. 相似文献
66.
67.
We report the formation of homogeneous and stable V2O3 nanocrystals, directly from V2O5 thin films, at 600 °C, as observed by using in situ electron microscopy experiments. Thermally-induced reduction of V2O5 thin films in vacuum is remarkably different when compared to reduction of V2O5 single crystals and results in the formation of nanophase V2O3. Thermally grown V2O3 nanocrystals exhibit hexagon or square shape and are stable at higher temperature as well as room temperature. The formation of stable nanocrystals through the reduction process in a non-chemical environment (vacuum) could provide a basis for understanding the complex processes of vanadium oxide phase transitions and for controlling the chemical processes to produce oxide nanocrystals. 相似文献
68.
O. Kavatsyuk C. Mazzocchi Z. Janas A. Banu L. Batist F. Becker A. Blazhev W. Brüchle J. Döring T. Faestermann M. Górska H. Grawe A. Jungclaus M. Karny M. Kavatsyuk O. Klepper R. Kirchner M. La Commara K. Miernik I. Mukha C. Plettner A. Płochocki E. Roeckl M. Romoli K. Rykaczewski M. Schädel K. Schmidt R. Schwengner J. Żylicz 《The European Physical Journal A - Hadrons and Nuclei》2007,31(3):319-325
The β decay of the very neutron-deficient isotope 101Sn was studied at the GSI on-line mass separator using silicon detectors for recording charged particles and germanium detectors
for γ-ray spectroscopy. Based on the β-delayed proton data the production cross-section of 101Sn in the 50Cr + 58Ni fusion-evaporation reaction was determined to be about 60nb. The half-life of 101Sn was measured to be 1.9(3)s. For the first time β-delayed γ-rays of 101Sn were tentatively identified, yielding weak evidence for a cascade of 352 and 1065keV transitions in 101In. The results for the 101Sn decay as well as those from previous work on the 103Sn decay are discussed by comparing them to predictions obtained from shell model calculations employing a new interaction
in the 88Sr to 132Sn model space. 相似文献
69.
The variation of the oxygen content, xO, of synthetic fayalite (Fe2SiO4) single crystals was investigated thermogravimetrically at 1130 °C as a function of the oxygen activity, aO2 (= PO2/PO2° ≈ fO2/fO2° with PO2° ≈ fO2° = 1 bar ≈ 1 atm). It was found that xO varies less in fayalite single crystals than in polycrystalline Fe2SiO4 studied earlier. The majority defects are most likely cation vacancies, (VMe2+)″, ferric ions on M-sites, (Fe3+Me2+), and ferric ions on Si-sites, (Fe3+Si4+)′. Furthermore, the diffusion of iron in synthetic olivine single crystals ((FexMg1 − x)2SiO4) was studied at 1130 °C as a function of orientation, oxygen activity, and cationic composition. The observed oxygen activity dependencies suggest that cations move via different types of cation vacancies, most likely isolated vacancies, (VFe2+)″, and possibly neutral associates, {2(Fe3+Me2+) ⋅ (VMe2+)′ ? ′}x, the latter being minority defects. In addition, the electrical conductivity, σ, of fayalite single crystals was investigated as a function of orientation and oxygen activity within the stability field of fayalite at 1130 °C. The observed oxygen activity dependencies are compatible with (VMe2+)′ ? ′, (Fe3+Me2+), and (Fe3+Si4+)′ being the majority point defects at high aO2 and with h⋅ and e′ as the majority defects at low aO2. The electrical conduction in fayalite is governed by contributions of electrons and holes. This extended point defect model for fayalite is also compatible with data for the variation of the oxygen content and for the iron tracer diffusion. 相似文献
70.
The quantum group IGL
q
(N), the inhomogenization of GL
q
(N), is formulated with
-matrices. Theq-deformed universal enveloping algebra is constructed as the algebra of regular functionals in this formulation and contains the partial derivatives of the covariant differential calculus on the quantum space. 相似文献