全文获取类型
收费全文 | 1348篇 |
免费 | 47篇 |
国内免费 | 9篇 |
专业分类
化学 | 980篇 |
晶体学 | 33篇 |
力学 | 30篇 |
数学 | 79篇 |
物理学 | 282篇 |
出版年
2024年 | 8篇 |
2023年 | 15篇 |
2022年 | 25篇 |
2021年 | 21篇 |
2020年 | 39篇 |
2019年 | 45篇 |
2018年 | 31篇 |
2017年 | 40篇 |
2016年 | 58篇 |
2015年 | 39篇 |
2014年 | 95篇 |
2013年 | 116篇 |
2012年 | 96篇 |
2011年 | 130篇 |
2010年 | 65篇 |
2009年 | 76篇 |
2008年 | 90篇 |
2007年 | 86篇 |
2006年 | 62篇 |
2005年 | 44篇 |
2004年 | 47篇 |
2003年 | 46篇 |
2002年 | 36篇 |
2001年 | 12篇 |
2000年 | 9篇 |
1999年 | 5篇 |
1998年 | 8篇 |
1997年 | 7篇 |
1996年 | 10篇 |
1995年 | 6篇 |
1994年 | 3篇 |
1993年 | 5篇 |
1992年 | 4篇 |
1991年 | 3篇 |
1990年 | 3篇 |
1989年 | 1篇 |
1988年 | 2篇 |
1987年 | 3篇 |
1986年 | 3篇 |
1985年 | 1篇 |
1984年 | 2篇 |
1982年 | 1篇 |
1981年 | 2篇 |
1978年 | 1篇 |
1969年 | 1篇 |
1967年 | 1篇 |
1965年 | 1篇 |
排序方式: 共有1404条查询结果,搜索用时 125 毫秒
11.
Patil KJ Pawar RB 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2003,59(6):1289-1297
Near infrared spectra of solution of 6.4 M HDO in D(2)O have been obtained at 15, 25, 30, and 35 degrees C. It was observed that the bands of HDO in D(2)O occur at 1416, 1525, 1556, and 1666 nm, which are in good agreement with the similar data reported earlier by Worley and Klotz. The calculations of enthalpy change for hydrogen bond formation (DeltaH degrees ) yielded the value of -2.5+/-0.4 kcal mol(-1), which is in excellent agreement with the value reported by Walrafen. Similar spectra were recorded for 1 and 2 m 18-crown-6 (18C6) dissolved in the solution of HDO in D(2)O at different temperatures. The band positions remain unchanged, however, the variation of intensity as a function of concentration of 18C6 and temperature clearly indicate that 18C6 acts as a structure making solute. The structural temperature and DeltaH degrees values have been obtained for the 18C6 solutions. These results are explained on the basis of the stabilization of 18C6 in the D(3d) conformation through hydrogen bonding of HDO molecules [doubly hydrogen bonded, i.e. bridging, and singly hydrogen bonded] to the oxygen atoms of 18C6 molecules. Slightly different DeltaH degrees values obtained can be attributed to clathrate like structure at 1 m 18C6 concentration while at 2 m 18C6 concentration it is postulated that the hydrophobic interactions are contributing additionally. 相似文献
12.
P. B. Ruikar M. S. Nagar M. S. Subramanian K. K. Gupta N. Varadarajan R. K. Singh 《Journal of Radioanalytical and Nuclear Chemistry》1995,201(2):125-134
The extraction of plutonium(IV), uranium(VI), zirconium(IV), europium(III) and ruthenium(III) with -pre-irradiated n-dodecane solutions of methylbutyl substituted hexanamide (MBHA), octanamide (MBOA) and decanamide (MBDA) from 3.5M HNO3 has been studied as a function of absorbed dose up to 184×104 Gray. The distribution ratios (Kd) of uranium(VI) decreased gradually up to a dose of 50×104 Gray and became almost constant thereafter, while ruthenium(III) and europium(III) were not extracted in the entire dose range studied. The Kd values of Pu(IV) decreased gradually up to 10×104 Gray, for MBOA, and 30×104 Gray for MBHA and MBDA and then increased up to a dose of 72×104 Gray, indicating the synergistic effect of radiolytic products at higher doses. The extraction of zirconium(IV) was found to increase gradually up to 72×104 Gray. However, the steep fall in Kd values of plutonium(IV), zirconium(IV) beyond a dose of 72×104 Gray was atrributed to third phase formation. The radiolytic degradation of amides was monitored by quantitative IR spectroscopy and was found to follow the order MBOA>MBDA>MBHA at 184×104 Gray having the amines and carboxylic acids as the main radiolytic products. 相似文献
13.
Kramer RM Li C Carter DC Stone MO Naik RR 《Journal of the American Chemical Society》2004,126(41):13282-13286
Self-assembled particles of genetically engineered human L subunit ferritin expressing a silver-binding peptide were used as nanocontainers for the synthesis of silver nanoparticles. The inner cavity of the self-assembled protein cage displays a dodecapeptide that is capable of reducing silver ions to metallic silver. This chimeric protein cage when incubated in the presence of silver nitrate exhibits the growth of a silver nanocrystal within its cavity. Our studies indicate that it is possible to design chimeric cages, using specific peptide templates, for the growth of other inorganic nanoparticles. 相似文献
14.
Gonnade RG Bhadbhade MM Shashidhar MS 《Chemical communications (Cambridge, England)》2004,(22):2530-2531
myo-Inositol hexabenzoate having meso configuration produces chiral polymorph (form I) when crystallized rapidly but yields achiral polymorph (form II) when allowed to crystallize slowly; in the mother liquor form I slowly but completely disappears to give form II. 相似文献
15.
Dip-pen nanolithography in tapping mode 总被引:1,自引:0,他引:1
Dip-pen nanolithography (DPN) is becoming a popular nano-patterning technique for depositing materials onto a substrate using the probe of an atomic force microscope (AFM). Here, we demonstrate the deposition of a short synthetic peptide by DPN using the Tapping Mode of AFM rather than the commonly used contact mode. DPN in Tapping Mode requires drive amplitude modifications for deposition, yet allows for gentle imaging of the deposited material and enables deposition on soft surfaces. 相似文献
16.
The total and differential cross sections for the electron and positron impact excitation of hydrogen from its initially excited metastable 22S state to 32S and 32P states are reported. A distorted-wave approximation theory is used for the calculation. The angular correlation parameters, Ly and alignment angle are also reported for 22S-32P excitation. For comparison, similar first Born results are also obtained. Interesting features are noted on comparing our distorted wave results with the first Born results as well as with the other available results forn
2S andn
2P (n=2,3) excitations from the ground 12S state of hydrogen. 相似文献
17.
Amit Sircar Rajesh K. Dwivedi R. K. Thareja 《Applied physics. B, Lasers and optics》1996,63(6):623-627
An experimental investigation of laser-induced breakdown using Nd:YAG laser harmonics for argon, nitrogen and oxygen gases is reported. Pressure dependence as well as wavelength dependence of the breakdown threshold irradianceI
th is investigated. The experimental observations for 1.064 and 0.532 m laser wavelengths are in agreement with theoretical calculations which include the effects of multiphoton ionization and cascade ionization. 相似文献
18.
A. M. George N. C. Mishra M. S. Nagar N. C. Jayadevan 《Journal of Thermal Analysis and Calorimetry》1996,47(6):1701-1708
Thermal decomposition of the amorphous coprecipitate of yttrium and aluminium hydroxides forming yttrium aluminium garnet has been investigated employing thermal analyses, X-ray diffraction and IR spectroscopy. On heating, the coprecipitate progressively loses water forming a stable but highly disordered hydroxy garnet which crystallizes at 1180 K and decomposes to YAG at 1290 K. Nucleation of the crystalline phase appears to begin at 800 K.The authors thank Dr. P. V. Ravindran of the Analytical Chemistry and Shri N. K. Kulkarni of the Fuel Chemistry Divisions of BARC for their assistance in the thermoanalytical experiments. 相似文献
19.
Billups WE Saini RK Litosh VA Alemany LB Wilson WK Wiberg KB 《The Journal of organic chemistry》2002,67(13):4436-4440
Thermolysis of spiro[2.4]hepta-1,4,6-triene (1a) at 50 degrees C yielded bicyclo[3.2.0]hepta-1,3,6-triene (5), which dimerized in two different fashions to form cyclobutanes. The 1,2-dimethyl and 1-propyl derivatives of 1a also rearranged at 50 degrees C, but at a faster rate, each yielding a pair of cyclobutane dimers. The structures of these symmetrical dimers were investigated by 1D and 2D NMR and NOE difference spectroscopy. Ab initio calculations indicated that the two strained olefins 1a and 5 had comparable energies about 50 kcal/mol lower than norborna-1(7),2,5-triene, which was thus excluded as a reaction intermediate. 相似文献
20.
M. S. Nagar P. B. Ruikar M. S. Subramanian 《Journal of Radioanalytical and Nuclear Chemistry》1986,99(1):109-119
The precipitation behaviour of basic plutonium(IV) compounds from dilute nitric acid medium with aliphatic dicarboxylic acids has been investigated. Unlike plutonium(IV) oxalate, which is precipitated in acid medium (1–4M), the higher dicarboxylates precipitate in 0.9–2.5 pH range and their elemental analysis indicate Pu/dicarboxylate ratio of 11. The mode of formation, composition, solubility and thermal degradation behaviour for plutonium(IV) hydroxosuccinate has been studied. The hydroxy group determination by kinetic titration using fluoride complexing revealed that the compound has a Pu:OH ratio of 11 and determination of bridging oxygen group gave a Pu:O ratio of 10.5 suggest its formation as hydroxysuccinate having an oxobridged formula. 相似文献