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51.
T. Balakrishnan V. Rajendran 《Journal of polymer science. Part A, Polymer chemistry》1997,35(4):727-733
Crosslinked poly(4-vinylpyridine-co-styrene) was prepared and functionalized with titanium tetrachloride to afford the corresponding poly(4-vinylpyridine-co-styrene)-titanium tetrachloride complex. This insoluble functionalized polymer-supported catalyst shows good catalytic activity for esterification reactions. In this article, the kinetics of esterification of acrylic acid with n-butanol is reported. The rate of formation of product depends on many experimental parameters, viz., stirring speed, concentration of acrylic acid, catalyst amount, temperature, percent active site, percent crosslinking, and mesh size of the polymer catalyst. The reaction rates were found to increase with increase in the stirring speed, concentration of acrylic acid, catalyst amount, and temperature, and decreases with increasing percentage crosslinking and mesh size of the polymer beads. © 1997 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 35: 727–733, 1997 相似文献
52.
S. Sankarrajan S. Aravindan R. Yuvakkumar K. Sakthipandi V. Rajendran 《Journal of magnetism and magnetic materials》2009,321(21):3611-3620
Nd1−xSrxMnO3 perovskite manganite material with different compositions (x=0.31, 0.35, 0.37, 0.39 and 0.41) have been prepared employing solid-state reaction technique. The ultrasonic velocities and attenuation of the above samples have been measured employing through transmission method operated at a fundamental frequency of 5 MHz over wide range of temperatures. The temperature dependence of ultrasonic velocities, attenuation, relative percentage variation in velocities and elastic constants show an interesting anomaly in all compositions. The observed anomalies in ultrasonic parameters at Tc in all compositions have been revealed in terms of existence of ferromagnetic (FM) state. Similarly, the anomalies at Tco show the transition from FM to charge-ordered antiferromagnetic (AFM) state. The observed results have been used to explore the competitions between FM and AFM. 相似文献
53.
The separation of the enantiomers of flurbiprofen on an amylose-derived chiral stationary phase, Chiralpak AD-H, by supercritical fluid chromatography (SFC) under both linear and non-linear conditions is studied. Pulse injections were implemented using supercritical CO2modified with methanol as a mobile phase at a temperature of 30 °C. At linear conditions, the isotherm is determined directly from the chromatogram. Under overload conditions, the elution profiles were described by competitive Langmuir and bi-Langmuir isotherm. Isotherm parameters were estimated using the inverse method and the effects of operation variables such as pressure and modifier composition were studied. The value of selectivity is from 1.9 to 2.1 while the value of resolution is from 5.3 to 11.8. The number of theoretical plates is always greater than 5000 indicating high efficiency of SFC. 相似文献
54.
Methyl‐3‐(2‐chloroquinolin‐3‐yl)acrylates 5a‐i on reaction with methyl amine in acetonitrile yielded methyl‐3‐[2‐(methylamino)quinolin‐3‐yl]acrylates 6a‐i . When, these were followed by the reaction with the Vilsmeier reagent, they afforded methyl benzo[b][1,8]naphthyridin‐3‐carboxylate 7a‐i in good yields. 相似文献
55.
Somasundaram Gayathri Rajaraman Vasanthi Mahalingam Vanjinathan Rajendran Kumaran 《Journal of fluorescence》2018,28(6):1379-1391
Photophysical and electrochemical studies of DDP dye with Formamide and alkyl substituted amides were carried out in water. Addition of Formamide (F), Acetamide (ACM), N,N-Dimethylformamide (DMF), Dimethylacetamide (DMAC) to DDP dye result in an isosbestic point. A fluorescence enhancement of DDP dye is observed on the addition of amides. Apart from the fluorescence enhancement, the addition of formamide result in no significant shift in the position of emission maxima of DDP dye whereas addition of ACM and DMF result in a shift towards the blue and red region respectively. DDP dye exhibits three lifetime components which are unique in lifetime and amplitude. The fluorescence lifetime and relative amplitude of DDP dye varies significantly by addition of amides in aqueous solution which are influenced by amidewater hydrogen-bonding network and hydrophobic influences of the alkyl substituted amides. The nature of interaction between dye and amide be predominantly through hydrogen-bonding wherein the carbonyl oxygen (C=O) of amides are bonded to N-H hydrogen of DDP dye through water molecule. The existence of more than one microenvironment of DDP dye in aqueous phase is elucidated by Electrochemical Impedence Spectroscopy (EIS) through Nyquist plots wherein it signifies that there exist at least three different micro environments which support the existence of different fluorescence lifetimes. Fluorescence spectral technique is used as an efficient tool to elucidate the nature of interaction of water soluble probe with hydrogen-bonding solutes is established in our studies. 相似文献
56.
Plasticized polymer electrolytes comprising of ethylene carbonate as the plasticizing agent in poly (vinyl chloride) [PVC]–poly (butyl methacrylate) [PBMA] blended polymer electrolytes were prepared by solution casting technique. Complex formation, structural elucidation, conductivity, dielectric parameters (?′, ?″, M′, and M″), thermal stability, and surface morphology are brought out from FTIR, XRD, ac impedance analysis, dielectric studies, thermogravimetry/differential thermal analysis, and scanning electron microscopic studies, respectively. Polymer electrolytes are found to exhibit higher ionic conductivity at higher concentration of plasticizer at the cost of their mechanical stability. Conductivity of 1.879 × 10?4 S cm?1 is exhibited by the polymer electrolyte consisting of 69% of plasticizer with appreciable thermal stability up to 523 K. Temperature and frequency dependence of conductivity is found to follow Vogel Tammann Fulcher relation and Jonscher power law, respectively. Real and imaginary parts of dielectric constants are found to decrease with increase in frequency which could be due to the electrode polarization effect. 相似文献
57.
Rajendran Suresh Babu Pandurangan Prabhu Sangilimuthu Sriman Narayanan 《Journal of Solid State Electrochemistry》2016,20(6):1575-1583
In this paper, a facile immobilization of copper hexacyanoferrate nanoparticles (CuHCFNP) on a paraffin wax-impregnated graphite electrode (PIGE) was carried out using the room-temperature ionic liquid (RTIL) 1-ethyl-3-methylimidazolium tetrafluoroborate (EMIMBF4) as an ionic binder. The characteristics of the CuHCFNP/EMIMBF4 gel-modified electrode were investigated by cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) techniques, and the modified electrode morphology was also characterized using field emission scanning electron microscopy (FESEM). The electrocatalytic behavior of butylated hydroxyl anisole (BHA) at the modified electrode has been investigated in 0.1 M KNO3 in static and dynamic conditions. Under the optimum conditions, the oxidation peak current was proportional to the BHA concentration in the range from 1.5 to 1000 μM with a detection limit of 0.5 μM (S/N = 3). The proposed method was applied to determine BHA content in real samples with satisfactory results. 相似文献
58.
Immobilized activated carbon doped TiO2 thin films were prepared by sol–gel dip coating method by using Titanium IV isopropoxide as a precursor. Aim of our work is to synthesize and investigate the structural, surface morphology and optical properties of the synthesized thin film. X-ray diffraction pattern reveals that the crystallinity of the film increases with increase in temperature. Also, the structural parameters such as particle size, microstrain and dislocation density have been calculated. The formation of nanosphere of diameter ranging from 300 nm to 500 nm has been confirmed by Scanning electron microscope. Photocatalytic active large optical band gap at 3.75 eV was found by using UV–visible sspectrum. 相似文献
59.
Wu F Zhu H Sun L Rajendran C Wang M Ren X Panjikar S Cherkasov A Zou H Stöckigt J 《Journal of the American Chemical Society》2012,134(3):1498-1500
The Pictet-Spenglerase strictosidine synthase (STR1) has been recognized as a key enzyme in the biosynthesis of some 2000 indole alkaloids in plants, some with high therapeutic value. In this study, a novel function of STR1 has been detected which allows for the first time a simple enzymatic synthesis of the strictosidine analogue 3 harboring the piperazino[1,2-a]indole (PI) scaffold and to switch from the common tryptoline (hydrogenated carboline) to the rare PI skeleton. Insight into the reaction is provided by X-ray crystal analysis and modeling of STR1 ligand complexes. STR1 presently provides exclusively access to 3 and can act as a source to generate by chemoenzymatic approaches libraries of this novel class of alkaloids which may have new biological activities. Synthetic or natural monoterpenoid alkaloids with the PI core have not been reported before. 相似文献
60.