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171.
Rajani K. Behera Ajay K. Behera Rosy Pradhan Anita Pati Manabendra Patra 《Phosphorus, sulfur, and silicon and the related elements》2013,188(3):753-765
Barbituric acid 2 upon Michael addition with dibenzal acetones 1a–c afforded the corresponding diazaspiro derivatives 3a–c . The base-catalyzed condensation of 3a–c with various aromatic aldehydes produces diarylidine derivatives 4a–l . The diarylidene compounds 4a–l on condensation with hydrazine, phenyl hydrazine, hydroxylamine, urea, guanidine carbonate, and hydrazine hydrate with acetic acid afforded their respective in situ oxidized products 5, 6, 7, 8, 9 , and 10 . The structures of the compounds are ascertained from their analytical and spectral data. Some of the compounds are screened for their biological activities against E. coli, B. cirroflagellosus, A. niger, and C. albicans. 相似文献
172.
Pyrazole is a versatile lead compound to design potent bioactive molecules for drug discovery and development, particularly in cancer therapy. The aim of this review is to present the most recent deeds in the field of synthetic route made for functionalized pyrazole derivatives active against cell proliferation disease. The review article covers the synthesis of 1H-pyrazole, synthesis of N-substituted pyrazoles, synthesis of pyrazolopyrazoles, and synthesis of pyrazoles fused with a naturally occurring moiety. Some of these reported compounds have passed the preclinical or initial-phase clinical trials for their anticancer activity. 相似文献
173.
Kundu P Singhania N Madras G Ravishankar N 《Dalton transactions (Cambridge, England : 2003)》2012,41(29):8762-8766
We present a green method for the synthesis of ZnO-Au hybrids using an ultrafast microwave-based technique. This method provides good control over the nucleation of the metal nanoparticles on the oxide support, which governs the morphology and microstructure of the hybrids. The hybrids exhibit good catalytic activity for CO oxidation compared to similar hybrids reported in the literature. Detailed XPS investigation reveals the presence of Au-Zn and Au-O bonds at the interface. This surface doping leads to the formation of anionic and cationic Au sites that contribute to the enhanced activity. Our method is general and can be applied for designing other supported catalysts with controlled interfaces. 相似文献
174.
The esterification of propionic acid was investigated using three different alcohols, namely, isopropyl alcohol, isobutyl
alcohol, and isoamyl alcohol. The variation of conversion with time for the synthesis of isoamyl propionate was investigated
in the presence of five enzymes. Novozym 435 showed the highest activity, and this was used as the enzyme for investigating
the various parameters that influence the esterification reaction. The Ping-Pong Bi-Bi model with inhibition by both acid
and alcohol was used to model the experimental data and determine the kinetics of the esterification reaction. 相似文献
175.
Giridhar Nandipati Abdelkader Kara Syed Islamuddin Shah Talat S. Rahman 《Journal of computational physics》2012,231(9):3548-3560
We report the development of a pattern-recognition scheme for the off-lattice self-learning kinetic Monte Carlo (KMC) method, one that is simple and flexible enough that it can be applied to all types of surfaces. In this scheme, to uniquely identify the local environment and associated processes involving three-dimensional (3D) motion of an atom or atoms, space around a central atom is divided into 3D rectangular boxes. The dimensions and the number of 3D boxes are determined by the accuracy with which a process needs to be identified and a process is described as the central atom moving to a neighboring vacant box accompanied by the motion of any other atom or atoms in its surrounding boxes. As a test of this method to we apply it to examine the decay of 3D Cu islands on the Cu(100) and to the surface diffusion of a Cu monomer and a dimer on Cu(111) and compare the results and computational efficiency to those available in the literature. 相似文献