全文获取类型
收费全文 | 418篇 |
免费 | 9篇 |
国内免费 | 1篇 |
专业分类
化学 | 229篇 |
晶体学 | 13篇 |
力学 | 23篇 |
数学 | 78篇 |
物理学 | 85篇 |
出版年
2023年 | 2篇 |
2022年 | 9篇 |
2021年 | 14篇 |
2020年 | 15篇 |
2019年 | 7篇 |
2018年 | 7篇 |
2017年 | 9篇 |
2016年 | 18篇 |
2015年 | 15篇 |
2014年 | 19篇 |
2013年 | 21篇 |
2012年 | 20篇 |
2011年 | 27篇 |
2010年 | 17篇 |
2009年 | 10篇 |
2008年 | 15篇 |
2007年 | 15篇 |
2006年 | 12篇 |
2005年 | 14篇 |
2004年 | 8篇 |
2003年 | 10篇 |
2002年 | 10篇 |
2001年 | 7篇 |
2000年 | 7篇 |
1999年 | 4篇 |
1998年 | 6篇 |
1997年 | 6篇 |
1996年 | 8篇 |
1995年 | 8篇 |
1994年 | 10篇 |
1993年 | 7篇 |
1992年 | 3篇 |
1991年 | 7篇 |
1990年 | 5篇 |
1989年 | 5篇 |
1988年 | 3篇 |
1987年 | 8篇 |
1986年 | 7篇 |
1985年 | 4篇 |
1984年 | 4篇 |
1983年 | 2篇 |
1982年 | 3篇 |
1981年 | 3篇 |
1979年 | 2篇 |
1978年 | 5篇 |
1977年 | 2篇 |
1976年 | 2篇 |
1973年 | 1篇 |
1965年 | 1篇 |
1961年 | 1篇 |
排序方式: 共有428条查询结果,搜索用时 15 毫秒
101.
A high throughput approach for generating combinatorial libraries with varying processing conditions for bulk ceramics has
been developed. This approach utilized the linear temperature gradient in a tube furnace to screen a whole temperature range
for optimized preparation. With this approach, the processing of 0.98[0.6BiFeO3–0.4PbTiO3]–0.02Pb(Mg1/3Nb2/3)O3 ceramic powders and pellets for high-temperature piezoelectric applications was demonstrated to identify the best synthesis
conditions for phase purity. The dielectric property measurement on the as-processed solid solution ceramics confirmed the
high Curie temperature and the improved loss tangent with the Pb(Mg1/3Nb2/3)O3 doping. 相似文献
102.
The benefits of simultaneous consideration of siting and sizing of distribution centers have been well acknowledged in supply
chain design. Most formulations assume that the potential DC sites are known and the decision on location is to select sites
from the finite potential DC sites. However, the quality of this discrete version problem depends on the selection of potential
DC sites. In this paper we present a planar version of the problem, which assumes that there is no a priori knowledge of DC
sites and DCs can be located anywhere in the plane. The goal of the problem is to simultaneously find locations and sizing
of DC sites. The solution of the planar problem provides a lower bound for the discrete problem. The objective of the problem
is to minimize the total of inbound and outbound transportation costs and distribution center construction costs—which include
its fixed charge cost and concave sizing cost. The problem is initially formulated as a nonlinear programming model. We then
reformulate it as a set covering problem after establishing certain key properties. A greedy drop heuristic and a column generation
heuristic are developed to solve the problem. Computational experiments are provided. 相似文献
103.
Jose R Zhanpeisov NU Fukumura H Baba Y Ishikawa M 《Journal of the American Chemical Society》2006,128(2):629-636
Structures and properties of CdSe quantum dots (clusters) up to a diameter of approximately 2 nm were investigated by combining experimental absorption, photoluminescence (PL), and X-ray diffraction (XRD) spectroscopies as well as ab initio DFT calculations. These CdSe clusters were nucleated and grown from solutions containing respective cadmium and selenium precursors following the hot-injection technique that allows one to obtain size-controlled CdSe clusters having PL efficiency up to 0.5. The DFT calculations were performed at the B3LYP/Lanl2dz level and followed by time-dependent TDDFT calculations to estimate n energy singlet transitions. On the basis of the results of these experimental and theoretical studies, an approach to determine whether the proposed cluster with a mean diameter of approximately 2 nm is more physically reasonable is discussed. It was shown that the minimum nucleus of a CdSe cluster consists of (CdSe)(3) with a six-membered ring and planar structure. No PL is observed for this structure. The formation of the next stable cluster depends on whether hexadecylamine (HDA) was used for the growth of the CdSe clusters. In the absence of HDA, the second cluster was found to be (CdSe)(6) characterized by a broad PL spectrum, while in the presence of HDA, it was found to be (CdSe)(n) (where n > or = 14) with a sharp PL spectrum. 相似文献
104.
Liao Y Bhattacharjee S Firestone KA Eichinger BE Paranji R Anderson CA Robinson BH Reid PJ Dalton LR 《Journal of the American Chemical Society》2006,128(21):6847-6853
Efficient noncentrosymmetric arrangement of nonlinear optical (NLO) chromophores with high first-order hyperpolarizability (beta) for increased electro-optical (EO) efficiency has proven challenging as strong dipolar interactions between the chromophores encourage antiparallel alignment, attenuating the macroscopic EO effect. This work explores a novel approach to simultaneously achieve large beta values while providing an adjustable dipole moment by linking a strong neutral-ground-state (NGS) NLO chromophore with positive beta to a zwitterionic (ZWI) chromophore with negative beta in an antiparallel fashion. It is proposed that the overall beta of such a structure will be the sum of the absolute values of the two types of chromophores while the dipole moment will be the difference. Molecules 1-3 were synthesized to test the feasibility of this approach. Molecular dynamics calculations and NMR data supported that the NGS chromophore component and the ZWI chromophore component self-assemble to an antiparallel conformation in chloroform. Calculations showed that the dipole moment of 1 is close to the difference of the two component chromophores. Hyper-Rayleigh scattering (HRS) studies confirmed that the first hyperpolarizability of 1 is close to the sum of the two component chromophores. These results support the idea that an antiparallel-aligned neutral-ground-state chromophore and a zwitterionic chromophore can simultaneously achieve an increase in beta and a decrease of the dipole moment. 相似文献
105.
Astha Chauhan Kajal Sharma Rajan Arora 《Mathematical Methods in the Applied Sciences》2020,43(15):8823-8840
In this work, Lie group theoretic method is used to carry out the similarity reduction and solitary wave solutions of (2 + 1)-dimensional Date–Jimbo–Kashiwara–Miwa (DJKM) equation. The equation describes the propagation of nonlinear dispersive waves in inhomogeneous media. Under the invariance property of Lie groups, the infinitesimal generators for the governing equation have been obtained. Thereafter, commutator table, adjoint table, invariant functions, and one-dimensional optimal system of subalgebras are derived by using Lie point symmetries. The symmetry reductions and some group invariant solutions of the DJKM equation are obtained based on some subalgebras. The obtained solutions are new and more general than the rest while known results reported in the literature. In order to show the physical affirmation of the results, the obtained solutions are supplemented through numerical simulation. Thus, the solitary wave, doubly soliton, multi soliton, and dark soliton profiles of the solutions are traced to make this research physically meaningful. 相似文献
106.
A VB-algebroid is essentially defined as a Lie algebroid object in the category of vector bundles. There is a one-to-one correspondence between VB-algebroids and certain flat Lie algebroid superconnections, up to a natural notion of equivalence. In this setting, we are able to construct characteristic classes, which in special cases reproduce characteristic classes constructed by Crainic and Fernandes. We give a complete classification of regular VB-algebroids, and in the process we obtain another characteristic class of Lie algebroids that does not appear in the ordinary representation theory of Lie algebroids. 相似文献
107.
Elif Tokar Erdemir Rajan Batta Peter A. Rogerson Alan Blatt Marie Flanigan 《European Journal of Operational Research》2010
Aeromedical and ground ambulance services often team up in responding to trauma crashes, especially when the emergency helicopter is unable to land at the crash scene. We propose location-coverage models and a greedy heuristic for their solution to simultaneously locate ground and air ambulances, and landing zones (transfer points). We provide a coverage definition based on both response time and total service time, and consider three coverage options; only ground emergency medical services (EMS) coverage, only air EMS coverage, or joint coverage of ground and air EMS in which the patient is transferred from an ambulance into an emergency helicopter at a transfer point. To analyze this complex coverage situation we develop two sets of models, which are variations of the Location Set Covering Problem (LSCP) and the Maximal Covering Location Problem (MCLP). These models address uncertainty in spatial distribution of motor vehicle crash locations by providing coverage to a given set of both crash nodes and paths. The models also consider unavailability of ground ambulances by drawing upon concepts from backup coverage models. We illustrate our results on a case study that uses crash data from the state of New Mexico. The case study shows that crash node and path coverage percentage values decrease when ground ambulances are utilized only within their own jurisdiction. 相似文献
108.
109.
The crystal structure of 1,5-dihydroxy xanthone obtained from Callophyllum trapezifolium has been determined (C13H8O4), Mr = 228.21, a = 5.547(5), b = 5.186(5), c = 16.487(5) Å, = 91.40(1), Z = 2 and V = 474.1(6) Å3. The xanthone molecule is planar and exhibits rotational disorder in the crystal. The packing of the molecules in the crystal lattice is due to inter- and intramolecular O–H O hydrogen bonds forming infinite chains. 相似文献
110.
This paper studies a facility location problem with stochastic customer demand and immobile servers. Motivated by applications to locating bank automated teller machines (ATMs) or Internet mirror sites, these models are developed for situations in which immobile service facilities are congested by stochastic demand originating from nearby customer locations. Customers are assumed to visit the closest open facility. The objective of this problem is to minimize customers' total traveling cost and waiting cost. In addition, there is a restriction on the number of facilities that may be opened and an upper bound on the allowable expected waiting time at a facility. Three heuristic algorithms are developed, including a greedy-dropping procedure, a tabu search approach and an -optimal branch-and-bound method. These methods are compared computationally on a bank location data set from Amherst, New York. 相似文献