全文获取类型
收费全文 | 787篇 |
免费 | 19篇 |
国内免费 | 4篇 |
专业分类
化学 | 469篇 |
晶体学 | 16篇 |
力学 | 35篇 |
数学 | 108篇 |
物理学 | 182篇 |
出版年
2023年 | 5篇 |
2022年 | 15篇 |
2021年 | 22篇 |
2020年 | 23篇 |
2019年 | 19篇 |
2018年 | 22篇 |
2017年 | 17篇 |
2016年 | 42篇 |
2015年 | 24篇 |
2014年 | 33篇 |
2013年 | 54篇 |
2012年 | 54篇 |
2011年 | 65篇 |
2010年 | 42篇 |
2009年 | 21篇 |
2008年 | 38篇 |
2007年 | 40篇 |
2006年 | 25篇 |
2005年 | 24篇 |
2004年 | 24篇 |
2003年 | 15篇 |
2002年 | 19篇 |
2001年 | 11篇 |
2000年 | 9篇 |
1999年 | 5篇 |
1998年 | 10篇 |
1996年 | 11篇 |
1995年 | 10篇 |
1994年 | 12篇 |
1993年 | 8篇 |
1992年 | 5篇 |
1991年 | 10篇 |
1990年 | 5篇 |
1989年 | 6篇 |
1988年 | 4篇 |
1987年 | 9篇 |
1986年 | 8篇 |
1985年 | 4篇 |
1984年 | 4篇 |
1983年 | 2篇 |
1982年 | 3篇 |
1981年 | 4篇 |
1980年 | 3篇 |
1979年 | 2篇 |
1978年 | 5篇 |
1977年 | 3篇 |
1976年 | 2篇 |
1975年 | 2篇 |
1974年 | 2篇 |
1926年 | 2篇 |
排序方式: 共有810条查询结果,搜索用时 15 毫秒
11.
12.
Natural rubber is reinforced with a novel type of grass fiber (Cyperus Tegetum Rox b). The effects of fiber loading of different mesh sizes on curing characteristics and mechanical properties of grass fiber filled natural rubber composite are studied. Since 400 mesh grass fiber loaded natural rubber composite shows superior mechanical properties, therefore the effect of silane coupling agent was studied for this particular composite. Here composites were prepared by using water leached grass fiber. Optimum cure time increases with the increase in fiber loading but the change in scorch time is less. The same trend of increase in optimum cure time is observed in the presence of Si69. But the value is higher compared to that of rubber composite without Si69. With increase in the fiber loading, modulus and hardness of the composite increases but tensile strength decreases. The mechanical properties of the composite, namely moduli at 200 and 300% elongation and hardness increase in the presence of Si69 but tensile strength is less compared to that of the composite without Si69. Elongation at break is not much affected due to the presence of Si69. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献
13.
Snyder DA Chen Y Denissova NG Acton T Aramini JM Ciano M Karlin R Liu J Manor P Rajan PA Rossi P Swapna GV Xiao R Rost B Hunt J Montelione GT 《Journal of the American Chemical Society》2005,127(47):16505-16511
X-ray crystallography and NMR spectroscopy provide the only sources of experimental data from which protein structures can be analyzed at high or even atomic resolution. The degree to which these methods complement each other as sources of structural knowledge is a matter of debate; it is often proposed that small proteins yielding high quality, readily analyzed NMR spectra are a subset of those that readily yield strongly diffracting crystals. We have examined the correlation between NMR spectral quality and success in structure determination by X-ray crystallography for 159 prokaryotic and eukaryotic proteins, prescreened to avoid proteins providing polydisperse and/or aggregated samples. This study demonstrates that, across this protein sample set, the quality of a protein's [15N-1H]-heteronuclear correlation (HSQC) spectrum recorded under conditions generally suitable for 3D structure determination by NMR, a key predictor of the ability to determine a structure by NMR, is not correlated with successful crystallization and structure determination by X-ray crystallography. These results, together with similar results of an independent study presented in the accompanying paper (Yee, et al., J. Am. Chem. Soc., accompanying paper), demonstrate that X-ray crystallography and NMR often provide complementary sources of structural data and that both methods are required in order to optimize success for as many targets as possible in large-scale structural proteomics efforts. 相似文献
14.
In this article, we apply a novel time‐dependent discrete variable representation (TDDVR) method proposed by Barkakaty and Adhikari to investigate tunneling through an Eckart barrier. This semi‐classical method is theoretically rigorous and straightforward to implement. Among the TDDVR formulations, this report presents the first derivation of a rigorous form of quantum force (QF) for the present perspective. The validity of this semi‐classical approach is demanded based on the excellent agreement of the tunneling probability with the corresponding quantum results. © 2004 Wiley Periodicals, Inc. Int J Quantum Chem, 2004 相似文献
15.
16.
We examine a family ofGI/GI/1 queueing processes generated by a parametric family of service time distributions,F(x,), and we show that under suitable conditions the corresponding customer stationary expectation of the system time is twice continuously differentiable with respect to. Expressions for the derivatives are given which are suitable for single run derivative estimation. These results are extended to parameters of the interarrival time distribution and expressions for the corresponding second derivatives (as well as partial second derivatives involving both interarrivai and service time parameters) are also obtained. Finally, we present perturbation analysis algorithms based on these expressions along with simulation results demonstrating their performance. 相似文献
17.
Some procedures for the gravimetric determination of silica in lead-bearing samples involve the extraction of lead sulphate with ammonium acetate. Results for silica are then low because some silica is dissolved in ammonium acetate solution. Correct results can be obtained only by avoiding fuming with sulphuric acid. If samples contain a large proportion of insoluble silica, preliminary fusion with sodium hydroxide is recommended. 相似文献
18.
Summary An amperometric titration of calcium with selenite is described. Barium, strontium, and other cations forming insoluble selenites interfere, but magnesium does not. The method is rapid and suitable for routine analysis, the error being less than 10 parts per 1000 over the range 50 to 70 mg of calcium.
Zusammenfassung Ein amperometrisches Titrationsverfahren für Calcium mit Selenit wurde beschrieben. Barium, Strontium und andere Kationen, die unlösliche Selenite bilden, stören, nur Magnesium nicht. Das Verfahren ist rasch und für Routineanalysen geeignet. Im Bereich zwischen 50 und 70 mg Calcium ist der Fehler geringer als 1% relativ.
Résumé On décrit un titrage ampérométrique du calcium par l'ion sélénite. Le baryum, le strontium et les autres cations formant des sélénites insolubles interfèrent, excepté le magnésium. La méthode est rapide et convient à l'analyse en série, l'erreur étant inférieure à 10 parties pour 1000 dans le domaine de 50–70 mg de calcium.相似文献
19.
An amperometric method for the determination of thiocarbamyl sulphonamides has been developed, based on the cleavage of the S-N bond by hydriodic acid. The method can also be applied for the cleavage of the S-S bond in thiuram disulphides and dibenzothiazyl disulphide, and thus provides a useful means for the estimation of these compounds as well. 相似文献
20.
C. R. Rajan V. M. Nadkarni S. Ponrathnam 《Journal of polymer science. Part A, Polymer chemistry》1988,26(9):2581-2588
A new route to synthesize poly(p-phenylene sulfide) by nucleophilic substitution of 1,4-dibromobenzene with sodium sulfide in N-methylpyrrolidone is described. Kinetic evaluation shows the reaction to be of second order with two distinctive rate constant regimes. The first rate constant is higher and is operative until 50% conversion, whereas in the second regime (between 50 and 92% conversion) the rate is slower. The kinetics of this route is compared under identical conditions with the conventional synthesis based on 1,4-dichloro benzene and sodium sulfide. 相似文献