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21.
22.
Based on NMR imaging results of the spatial and temporal development of ion exchange processes in alginate gels, the question of appropriate modelling of these processes is discussed. For rare earth and actinoid ions, the behaviour is found to correspond qualitatively to the expectations of Stefan’s model (shrinking core model, SCM). However, quantitative correspondence of the experimental data with the model can only be achieved when an additional diffusive layer at the surface of the ion exchange material is assumed. An extension of the SCM with respect to this problem is derived. 相似文献
23.
Thomas Drewello Rainer Herzschuh Joachim Stach 《Zeitschrift für Physik D Atoms, Molecules and Clusters》1993,28(4):339-343
A triple stage hybrid mass spectrometer was scanned for the trapping of the reaction intermediates of the over-all loss of two CsI-moieties from size-selected caesium iodide cluster ions of the general formula Cs (CsI)+ n . In addition to appropriate MS/MS/MS-methods an electrically floated collision cell has been applied to trap intermediates of unimolecular and collision-induced evaporations. In comparison with other experimental findings the features of the evaporation mechanism are discussed. 相似文献
24.
Rainer Dick 《Letters in Mathematical Physics》1989,18(3):255-265
Bases of holomorphic -differentials on N-punctured Riemann surfaces of arbitrary genus are constructed. The resulting extension of the Virasoro algebra on N-punctured spheres is displayed explicitly. 相似文献
25.
Hubert HuppertzRolf-Dieter Hoffmann Rainer Pöttgen 《Journal of solid state chemistry》2002,169(2):155-159
EuPd0.72In1.28 and EuPt0.56In1.44 were prepared under multianvil high-pressure (10.5 GPa) high-temperature (1500 and 1400 K) conditions from the precursor compounds EuPdIn and EuPtIn. They were investigated by X-ray diffraction on both powders and single crystals: MgZn2-type, space group P63/mmc, a=578.7(1) pm, c=944.9(3) pm, wR2=0.0734, 263 F2 values for EuPd0.72In1.28 and a=591.1(2) pm, c=933.8(2) pm, wR2=0.0853, 151 F2 values for EuPt0.56In1.44 with 13 variable parameters per refinement. Both structures are built up from face- and corner-sharing tetrahedra of palladium (platinum) and indium atoms. The europium cations are located in cavities within the three-dimensional [Pd0.72In1.28] and [Pt0.56In1.44] networks. The 2a and 6 h positions of the tetrahedral networks show mixed Pd/In and Pt/In occupancy in EuPd0.72In1.28 and EuPt0.56In1.44, respectively. The crystal chemistry of these indides is briefly discussed. 相似文献
26.
Vasyl' I. Zaremba Dariusz Kaczorowski Galyna P. Nychyporuk Ute Ch. Rodewald Birgit Heying Rainer Pttgen 《无机化学与普通化学杂志》2006,632(6):975-980
New indides Ce3Ge0.66In4.34 and Ce11Ge4.74In5.26 were synthesized from the elements by arc‐melting and subsequent annealing at 870 K. Single crystals were grown through special annealing procedures in sealed tantalum tubes in a high‐frequency furnace. Both compounds were investigated on the basis of X‐ray powder and single crystal data: I4/mcm, La3GeIn4 type, a = 848.8(1), c = 1192.0(2) pm, Z = 4, wR2 = 0.0453, 499 F2 values, 17 variables for Ce3Ge0.66In4.34 and I4/mmm, Sm11Ge4In6 type (ordered version of the Ho11Ge10 type), a = 1199.3(2), c = 1662.0(3) pm, wR2 = 0.0507, 1217 F2 values, 41 variables for Ce11Ge4.74In5.26. The Ce3Ge0.66In4.34 structure shows a mixed Ge/In occupancy on the 4c Wyckoff position. This site is octahedrally coordinated by cerium atoms. These octahedra share all edges, leading to a three‐dimensional network. The latter is penetrated by a two‐dimensional indium substructure which consists of flattened tetrahedra at In–In distances of 291 and 300 pm. The Ce11Ge4.74In5.26 structure contains three crystallographically independent germanium sites. The latter are coordinated by eight or nine cerium neighbors. These CN8 and CN9 polyhedra are condensed to a complex network which is penetrated by a three‐dimensional indium network with In–In distances of 301–314 pm. The 16m site shows a mixed In/Ge occupancy. Chemical bonding in both compounds is dominated by the p elements. Both ternaries studied exhibit localized magnetism due to the presence of Ce3+ ions. The compound Ce3GeIn4 remains paramagnetic down to 1.72 K, whereas Ce11Ge4In6 orders ferromagnetically at TC = 7.5 K. 相似文献
27.
Experiments have been carried out to study the behaviour of organoarsenicals treated with zeolites by means of speciation
analysis. IC-ICP-MS was applied to identify and quantify arsenite, arsenate and the following organoarsenicals: monomethylarsonic
acid (MMA), dimethylarsinic acid (DMA), trimethylarsine oxide (TMAO), tetramethylarsonium bromide (TMA+), arsenobetaine (AsB) and arsenocholine (AsC). Zeolites loaded with ferrous ions did not significantly increase the retention
of inorganic arsenic species compared to the native zeolites, while there was a ten-fold removal of arsenate relating to arsenite.
The formation of As(V) and DMA in the leachates containing clinoptilolites and mordenites was confirmed in the presence of
natural and synthetic zeolites. Arsenobetaine and arsenocholine yielded higher levels of arsenate than the methylated species. 相似文献
28.
Kammerer B Kahlich R Ufer M Laufer S Gleiter CH 《Rapid communications in mass spectrometry : RCM》2004,18(4):458-464
Phenprocoumon is a commonly used oral anticoagulant of the coumarin type, and has found extensive clinical use in the treatment of thrombophlebitis, pulmonary embolism and atrial fibrillation. In the course of a clinical study to investigate the influence of genetic polymorphisms of the CYP2C9 enzyme on phenprocoumon metabolism, we developed a new enantioselective liquid chromatography/electrospray ionisation tandem mass spectrometry (LC/MS/MS) method to quantify (R)- and (S)-phenprocoumon in human plasma. HPLC separation of the enantiomers was achieved on a Chira-Grom-2 column under isocratic conditions using a water/acetonitrile/formic acid eluent. For detection and quantification a triple-quadrupole MS system was used in the selected reaction monitoring (SRM) mode. As an internal standard the structurally homologous compound warfarin was chosen. The detector response was linear with a correlation coefficient of 0.988-0.999 for (R)-phenprocoumon and 0.989-0.999 for (S)-phenprocoumon in the investigated concentration range between 62.5 and 1000 ng/mL (per enantiomer). The limit of detection (LOD) was 12.5 ng/mL. 相似文献
29.
The 3-trifluoromethylsulfonyloxy-1-hexeniminium triflate 1 reacts with two equivalents of an aliphatic nitrile or of benzonitrile to give the 4-(2-diethylaminovinyl)pyrimidinediium bis(triflates) 4 , which can be deprotonated to give the monoprotonated or neutral pyrimidines 5 and 6 , respectively. When the related 1-phenyl-substituted iminium salt 7 is heated in acetonitrile at 140°, 1,5-cyclization of the cation leading to indane derivative 8 competes with formation of the pyrimidinium salt 9 . X-ray crystal structure determination reveals significant differences in the bond lengths of mono-and diprotonated 4-(2-diethylaminovinyl)pyrimidines 5a and 4a . 相似文献
30.
Deprotonated Dithiocarbamic Acid Esters as Thiolate S-Donor Ligands. Structures of Ph(H)NC(S)SMe, Co(PhNC(S)SMe)3, and Cu6(PhNC(S)SMe)6 The reaction of N-phenyl-S-methyldithiocarbamate, PhN(H)C(?S)SMe, ( 1 ) with cobalt(II) and copper(II) salts yields the monomeric compound CoIII(PhNC(S)SMe)3 ( 2 ) and the hexameric compound Cu6I(PhNC(S)SMe)6 ( 3 ). These complexes contain the negatively charged imino-thiolate ligand PhN?C(? S)SMe, which has been formed by deprotonation of 1 . The crystal structures of 1 – 3 have been determined. 1 forms centrosymmetrical dimers through N? H …? S bridge bonds, the conformation in the solid state and in solution is Z,E′. CoIII shows in 2 a trigonal-antiprismatic coordination, with the ligands acting as N,S-chelates. 3 contains an octahedral Cu6-core with Cu …? Cu-distances ranging from 276.3(5) to 305.7(4) pm. Each copper center is trigonally coordinated to one nitrogen and two sulfur atoms of three different ligands. Crystal data: 1 , triclinic, space group P1 , a = 590.5(6), b = 869.0(1), c = 968.5(9) pm, α = 67.29(8), β = 78.44(8), γ = 81.64(9)°, Z = 2, 1 775 reflections, R(Rw) = 0.0317(0.032). 2 , orthorhombic, space group Pbca, a = 978.0(2), b = 1 842.9(4), c = 3 059.7(6) pm, Z = 8, 1 129 reflections, R(Rw) = 0.0997(0.0886). 3 , monoclinic, space group P21/c, a = 1 363.1(3), b = 1 342.8(3), c = 1 671.9(3) pm, β = 103.48°, Z = 2, 1 374 reflections, R(Rw) = 0.0708(0.0617). 相似文献