全文获取类型
收费全文 | 2996篇 |
免费 | 105篇 |
国内免费 | 5篇 |
专业分类
化学 | 2203篇 |
晶体学 | 7篇 |
力学 | 62篇 |
数学 | 463篇 |
物理学 | 371篇 |
出版年
2022年 | 26篇 |
2021年 | 19篇 |
2020年 | 43篇 |
2019年 | 45篇 |
2018年 | 29篇 |
2017年 | 26篇 |
2016年 | 71篇 |
2015年 | 64篇 |
2014年 | 91篇 |
2013年 | 123篇 |
2012年 | 138篇 |
2011年 | 183篇 |
2010年 | 93篇 |
2009年 | 79篇 |
2008年 | 139篇 |
2007年 | 156篇 |
2006年 | 140篇 |
2005年 | 146篇 |
2004年 | 139篇 |
2003年 | 93篇 |
2002年 | 95篇 |
2001年 | 59篇 |
2000年 | 49篇 |
1999年 | 56篇 |
1998年 | 44篇 |
1997年 | 62篇 |
1996年 | 54篇 |
1995年 | 35篇 |
1994年 | 48篇 |
1993年 | 43篇 |
1992年 | 27篇 |
1991年 | 31篇 |
1990年 | 29篇 |
1989年 | 31篇 |
1988年 | 30篇 |
1987年 | 31篇 |
1986年 | 42篇 |
1985年 | 47篇 |
1984年 | 50篇 |
1983年 | 40篇 |
1982年 | 46篇 |
1981年 | 26篇 |
1980年 | 37篇 |
1979年 | 37篇 |
1978年 | 29篇 |
1977年 | 34篇 |
1976年 | 24篇 |
1973年 | 16篇 |
1972年 | 19篇 |
1971年 | 16篇 |
排序方式: 共有3106条查询结果,搜索用时 0 毫秒
91.
William P. Clark Andreas Khn Rainer Niewa 《Angewandte Chemie (International ed. in English)》2020,59(1):339-342
The first quasi‐binary acetonitriletriide Sr3[C2N]2 has been synthesised and characterised. The nearly colourless crystals were obtained from the reaction of Sr metal, graphite, and elemental N2, generated by decomposition of Sr(N3)2, in a sealed Ni ampoule with the aid of an alkali metal flux. The structure of this compound was analysed via single‐crystal X‐ray diffraction and the identity of the [C2N]3? anion was confirmed by Raman spectroscopy and further investigated by quantum‐chemical methods. Computed interatomic distances within the [C2N]3? anion strikingly match the obtained experimental data. 相似文献
92.
Bridged 2,3-naphthalocyaninatoruthenium oligomers {[MacRu(L)] n } were synthesized and characterized using solid-state methods. For comparison, soluble t-butyl substituted phthalocyaninatoruthenium oligomers were prepared and their chain length examined by 1H NMR spectroscopy. The powder conductivities of all bridged compounds ([MacRu(L)] n ) were measured and the dependence of the conductivities on the bridging ligands is discussed. 相似文献
93.
94.
95.
Rainer Haag 《Nachrichten aus der Chemie》1995,43(12):1300-1301
96.
97.
98.
Emission of volatile sesquiterpenes and monoterpenes in grapevine genotypes following Plasmopara viticola inoculation in vitro 下载免费PDF全文
Alberto Algarra Alarcon Valentina Lazazzara Luca Cappellin Pier Luigi Bianchedi Rainer Schuhmacher Georg Wohlfahrt Ilaria Pertot Franco Biasioli Michele Perazzolli 《Journal of mass spectrometry : JMS》2015,50(8):1013-1022
The grapevine (Vitis vinifera) is one of the most widely cultivated fruit crops globally, and one of its most important diseases in terms of economic losses is downy mildew, caused by Plasmopara viticola. Several wild Vitis species have been found to be resistant to this pathogen and have been used in breeding programs to introduce resistance traits to susceptible cultivars. Plant defense is based on different mechanisms, and volatile organic compounds (VOCs) play a major role in the response to insects and pathogens. Although grapevine resistance mechanisms and the production of secondary metabolites have been widely characterized in resistant genotypes, the emission of VOCs has not yet been investigated following P. viticola inoculation. A Proton Transfer Reaction‐Time of Flight‐Mass Spectrometer (PTR‐ToF‐MS) was used to analyze the VOCs emitted by in vitro‐grown plants of grapevine genotypes with different levels of resistance. Downy mildew inoculation significantly increased the emission of monoterpenes and sesquiterpenes by the resistant SO4 and Kober 5BB genotypes, but not by the susceptible V. vinifera Pinot noir. Volatile terpenes were implicated in plant defense responses against pathogens, suggesting that they could play a major role in the resistance against downy mildew by direct toxicity or by inducing grapevine resistance. The grapevine genotypes differed in terms of the VOC emission pattern of both inoculated and uninoculated plants, indicating that PTR‐ToF‐MS could be used to screen hybrids with different levels of downy mildew resistance. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
99.
100.