Mild,Efficient, and Rapid Dehydration of Aldoximes to Nitriles Mediated by Phthalic Anhydride Under Microwave Irradiation

Summary.  Aldoximes can be efficiently and rapidly dehydrated to nitriles by treatment with phthalic anhydride under microwave irradiation. Received April 18, 2001. Accepted (revised) June 7, 2001     

Joint determination of production quantity,inspection schedule,and quality control for an imperfect process with deteriorating products

In this paper, we study the simultaneous effects of both deteriorating product items and deteriorating production processes on economic production quantity, inspection schedules, and the economic design of control charts. Deterioration times for both product and process are assumed to follow arbitrary probability distributions. The product quality characteristic, however, is assumed to be normally distributed. Applications of the proposed model are demonstrated through illustrative examples.     

Magneto-optical photonic crystal 1 × 3 switchable power divider

Optical power splitter is an important building element in the photonic systems. Here, a 1 × 3 power divider using magneto-optical photonic crystal is proposed. The mechanism of operation is based on spatial field distribution, the mode matching of the fields and the effect of gyrotropy. It has a wide branching angle and the input power can either be switched completely to one of the output ports or divided equally between the three output ports by using an external magneto-static bias signal. A very good power transmission between the input and the output ports is observed.     

Investigation on thermal conductivity and physical properties of polythiophene/p-phenylenediamine-graphene oxide and polythiophene-co-poly(methyl methacrylate)/p-phenylenediamine graphene oxide composites

An efficient approach was employed to simultaneously functionalize and reduce the graphene oxide (GO) with p-phenylene diamine (PPD) using simple refluxing. There was a possibility of nucleophilic substitution of amino moieties of PPD with the epoxy groups of GO. The polythiophene (PTh) and polythiophene-co-poly(methylmethacrylate) (PTh-co-PMMA) nanocomposites with chemically modified GO were prepared using in situ polymerization technique. Two series of nanocomposites that is PTh/PPD-GO and PTh-co-PMMA/PPD-GO were designed. The nanocomposites were characterized by Fourier transform infrared spectroscopy (FTIR), X-ray diffraction, scanning electron microscopy (SEM), thermal conductivity, and electrical conductivity measurement. The FTIR spectra depicted the characteristic absorption peaks for the formation of copolymer and their composites with PPD-GO. The SEM micrographs showed that the PPD-GO nanosheets were homogeneously dispersed in copolymer matrix forming nano-granular morphology. The nanofluids were prepared by suspending modified GO particles inside the basefluid of polythiophene and PTh-co-PMMA. The thermal conductivity of nanocomposites was significantly improved even with low PPD-GO loading. The thermal conductivity of PTh-co-PMMA/PPD-GO with 1.5 wt.% filler was increased to 1.42 W/mK at a higher temperature. The XRD patterns confirmed the presence of chemical interactions between the copolymer and filler particles. The electrical conductivity of PTh-co-PMMA/PPD-GO was also found to increase in the range of 6.1 × 10^?3–2.5 × 10^?2 S/cm. Novel PTh-co-PMMA/PPD-GO-based nanocomposite is potentially significant in high-performance thermal systems.     

F,Cl, Br Doped Ge44 and Al22P22 Nanocages As Anode Electrode Materials of Li,Na, and K ion Batteries

Russian Journal of Physical Chemistry A - In this study, the potential of Ge44 and Al22P22 as anode electrodes of Li-ion, Na-ion, and K-ion batteries were investigated via density functional...     

Investigating Bulk Waves in Orthotropic Rectangular Nanoplates Based on Three Dimensional Elasticity Theory and Nonlocal Elasticity Theory

The propagation of bulk waves in rectangular nanoplates is studied on the basis of nonlocal three-dimensional elasticity theory. The nonlocal theory applies to both thin and thick rectangular orthotropic nanoplates. The dispersion relation for the waves is derived analytically. Our results are checked against data for macroplates. The influence of nonlocality and other parameters on the wave frequency and phase velocity is discussed.     

The comparison of different mathematical methods to determine the BOD parameters,a new developed method and impacts of these parameters variations on the design of WWTPs

One of the most common tests for the determination of strength and organic content of wastewater is the biochemical oxygen demand (BOD). This test is widely applied to define organic water pollution and to control the performance of wastewater treatment plants. Generally, BOD is standardized by the measurement of oxygen consumption in 5 days (BOD₅). But, determination of the ultimate biochemical oxygen demand (BOD_u), which is taken 28 days and the reaction rate constant (k) are necessary to understand the organic strength of the wastewater. In this study, the different mathematical methods in order to determine the BOD parameters (BOD_u, k) and two different BOD test method (respirometer and dilution method) are investigated comparatively. Also, a new method based on cubic spline method to estimate ultimate BOD values is developed. Moreover, the impacts of BOD parameters on the design of an activated sludge and aerated lagoon systems are analyzed by using a written user-friend program, which is developed for designing WWTPs by the mean of C++ programming language.