Microwave-assisted extraction of phenolic compounds from grape seed

A microwave-assisted extraction technique was developed to optimize the extraction of phenolic compounds from grape seeds. The microwave power (300-150W) and time of extraction (20-200s) were varied during the optimization process. The polyphenol content of the resulting extracts were measured as mg of tannic acid equivalent per gram of crude extract (mg TAE/g of crude extract), using a Folin-Ciocalteau reagent. In general, neither the time nor the power had a significant effect on the overall % yield (average of 13.5%) and on the polyphenol content (392 mg TAE/g of crude extract) of the extracts. However, when the solvent polarity was changed by the addition of 10% water, the yield increased to 15.2% and the polyphenol content increased to 429 mg TAE/g of crude extract.     

Temperature dependence of the quadrupole interaction of69GeTl and113SnSn

The quadrupole interaction constants of⁶⁹GeT1 and¹¹³SnSn were measured by means of the perturbed angular distribution technique as a function of temperature in the range of 80KT508 K and 80KT480 K, respectively. Isomeric states in⁶⁹Ge and¹¹³Sn were populated by the heavy ion reactions⁵⁶Fe(¹⁶O, 2p n) and¹⁰⁰Mo(¹⁶O, 3n) and recoil implanted into polycrystalline Tl- and single crystalline Sn-backings. In the case of¹¹³SnSn, where the quadrupole coupling is weak, a special single crystal geometry was employed to enhance the sensitivity of the measurement. Within the limits of the errors the temperature dependence for both systems follows the empirical T^1.5-dependence. While a strong temperature dependence comparable to InIn is observed for⁶⁹GeT1, that for¹¹³SnSn is weaker than expected. The strength of the temperature dependence for¹¹³SnSn does not agree with the predictions of a lattice vibration model proposed recently for the temperature dependence of the quadrupole interaction.Supported in part by NSFAssociate of the Graduate Faculty of Rutgers University     

Inclusive production ofK *(892) andΣ(1385) in\bar p p interactions at 3.6 GeV/c and a test of factorization hypothesis

We present a study of the inclusive production ofK ^*(892) and ∑^t+-(1385)+cc at 3.6 GeV/c from \(\bar p\) p interactions. The sensitivity of the exposure is 35.4 events/μb. Longitudinal and transverse momentum distributions are presented. The indirect production ofK _s ⁰ from parentK ^* and that of Λ's from parent Σ(1385) are studied. The shape of thex distribution of Λ's for \(p\xrightarrow{{\bar p}}\Lambda \) are calculated from \(p\xrightarrow{p}\Lambda \) and \(p\xrightarrow{{\pi ^ - }}\Lambda \) and compared with the experimental distributions. The difference of antiparticle production cross-section ofK _s ⁰ in the central region is compared with the expectation from Mueller-Regge formalism.     

The synthesis and conformational analysis of amino acid-tetrahydroanthranilic acid hybrids

The optimization of a palladium-catalyzed amidation reaction providing a new class of amino acid-tetrahydroanthranilic acid derivatives has been achieved. The scope of the reaction and preliminary conformational analysis of the resulting series of molecules is discussed.     

Polymerization of 1‐olefins by zirconium/titanium precatalysts with O,N,O‐ligating atoms—can aggregation of catalyst be inferred from the reaction profile?

The 2‐[benzyl‐(2‐hydroxy‐2‐phenylethyl)‐amino]‐1‐phenylethanol ligand (1‐H₂) prepared as a diastereomeric mixture or in racemic and meso forms, from known procedure, has been disodiated and complexed with ZrCl₄. The precatalysts (mix‐1‐ZrCl₂, rac‐1‐ZrCl₂, and meso‐1‐ZrCl₂) were used in combination with methylaluminoxane and found to be active for the polymerization of 1‐hexene and 1‐octene. The high molecular weight polyhexenes (PHs) and polyoctenes (POs) thus obtained were isotactic in nature and showed a negligible amount of end groups arising from the chain termination reactions. In PHs and POs, there was linear correlation in the modified Arrhenius plot (the natural logarithm of the number‐average molecular weight vs. the reciprocal of the temperature), indicating the presence of a single active species. The enantiomerically pure titanium precatalyst ((R,R)‐1‐TiCl₂), when employed for the polymerization of 1‐hexene, was found to be active and the modified Arrhenius plot showed linear dependence demonstrating presence of a single active species. The analogous titanium precatalysts (mix‐1‐TiCl₂, rac‐1‐TiCl₂, and meso‐1‐TiCl₂) obtained from known procedures were also found to be active for the polymerization of 1‐octene. The rac‐1‐TiCl₂ precatalyst demonstrated a sigmoidal behavior in the modified Arrhenius plot for the POs and the mix‐1‐TiCl₂ precatalyst showed an exponential type of behavior. The obtained POs seemed to have small amounts of chain termination via β‐hydride elimination alone. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 3599–3610, 2007     

Hyperbranched poly(ether–urea)s using AB2‐type blocked isocyanate monomer and azide monomer: Synthesis,characterization, reactive end functionalization,and copolymerization with AB monomer

3,5‐bis(4‐aminophenoxy)phenyl phenylcarbamate—a novel AB₂‐type blocked isocyanate monomer and 3,5‐bis{ethyleneoxy(4‐aminophenoxy)}phenyl carbonyl azide—a novel AB₂‐type azide monomer were synthesized in high yield. Step‐growth polymerization of these monomers were found to give a first example of hyperbranched poly (aryl‐ether‐urea) and poly(aryl‐alkyl‐ether‐urea). Molecular weights (M_w) of the polymer were found to vary from 1,858 to 52,432 depending upon the monomer and experimental conditions used. The polydispersity indexes were relatively narrow due to the controlled regeneration of isocyanate functional groups for the polymerization reaction. The degree of branching (DB) was determined using ¹H‐NMR spectroscopy and the values ranged from 87 to 54%. All the polymers underwent two‐stage decomposition and were stable up to 300 °C. Functionalized end‐capping of poly(aryl‐ether‐urea) using phenylchloroformate and di‐t‐butyl dicarbonate (Boc)₂O changed the thermal properties and solubility of the polymers. Copolymerization of AB₂‐type blocked isocyante monomer with functionally similar AB monomer were also carried out. The molecular weights of copolymers were found to be in the order of 6 × 10⁵ with narrow dispersity. It was found that the T_g's of poly(aryl‐alkyl‐ether‐urea)s were significantly less (46–49 °C) compared to poly(aryl‐ether‐urea)s. Moreover the former showed melting transition at 154 °C, which was not observed in the latter case. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 2959–2977, 2007     

Assignment games with stable core

We prove that the core of an assignment game (a two-sided matching game with transferable utility as introduced by Shapley and Shubik, 1972) is stable (i.e., it is the unique von Neumann-Morgenstern solution) if and only if there is a matching between the two types of players such that the corresponding entries in the underlying matrix are all row and column maximums. We identify other easily verifiable matrix properties and show their equivalence to various known sufficient conditions for core-stability. By these matrix characterizations we found that on the class of assignment games, largeness of the core, extendability and exactness of the game are all equivalent conditions, and strictly imply the stability of the core. In turn, convexity and subconvexity are equivalent, and strictly imply all aformentioned conditions. Final version: April 1, 2001     

Large grained and high charge carrier lifetime CH3NH3PbI3 thin-films: implications for perovskite solar cells

Spin coated perovskite thin films are known to have an issue of pinholes & poor morphology control which lead to poor device-to-device repeatability, that is an impediment to scale-up. In this work, Methylamine vapor annealing process is demonstrated which consistently leads to high-quality perovskite thin-films with an average grain-size of 10–15 μm. The improvement in film morphology enables improvement in effective carrier recombination lifetime, from 21 μs in as-deposited films to 54 μs in vapor-annealed films. The annealed films with large-grains are also more stable in ambient conditions. Devices made on annealed perovskite films are very consistent, with a standard deviation of only 0.7%. Methylamine vapor annealing process is a promising method of depositing large-grain CH₃NH₃PbI₃ films with high recombination lifetime and the devices with improved performance.