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41.
42.
Ragab E. Abouzeid Ahmed Salama Esmail M. El-Fakharany Vincenzo Guarino 《Molecules (Basel, Switzerland)》2022,27(3)
Bio sustainable hydrogels including tunable morphological and/or chemical cues currently offer a valid strategy of designing innovative systems to enhance healing/regeneration processes of damaged tissue areas. In this work, TEMPO-oxidized cellulose nanofibrils (T-CNFs) were embedded in alginate (Alg) and polyvinyl alcohol (PVA) solution to form a stable mineralized hydrogel. A calcium chloride reaction was optimized to trigger a crosslinking reaction of polymer chains and mutually promote in situ mineralization of calcium phosphates. FTIR, XRD, SEM/EDAX, and TEM were assessed to investigate the morphological, chemical, and physical properties of different mineralized hybrid hydrogels, confirming differences in the deposited crystalline nanostructures, i.e., dicalcium phosphate dehydrate (DCPDH) and hydroxyapatite, respectively, as a function of applied pH conditions (i.e., pH 4 or 8). Moreover, in vitro tests, in the presence of HFB-4 and HSF skin cells, confirmed a low cytotoxicity of the mineralized hybrid hydrogels, and also highlighted a significant increase in cell viability via MTT tests, preferentially, for the low concentration, crosslinked Alg/PVA/calcium phosphate hybrid materials (<1 mg/mL) in the presence of hydroxyapatite. These preliminary results suggest a promising use of mineralized hybrid hydrogels based on Alg/PVA/T-CNFs for bone and wound healing applications. 相似文献
43.
本文报道于酸性水溶液中, 以单电流阶跃法, 单电位阶跃法, 计时电量法和循环伏安法测定了2,2,6,6-四甲基-4-羟基哌啶-1-氧自由基的扩散系数及其在碳糊和铂工作电极上的单电子氧化反应的传递系数. 以及该电极反应的标准速率常数. 相似文献
44.
化学反应中的双稳性的临界现象及Landau相变理论 总被引:4,自引:0,他引:4
本文通过两个典型事例,即Langmuir形式的交换过程和Schlogle用以模拟一级相变的自催化反应,阐明化学反应系统的双稳性临界现象同样可以纳入Landau相变理论的模式。从而进一步揭示了双稳系统一级相变线临界点的二级(连续)相变特征,同时也揭示了作为远离平衡的化学反应双稳性临界现象的共性,以至于在更大范围内临界现象的共性。将相变的Landau理论,由原来的处于热平衡的凝聚物质推广到范围更宽广,表现更为丰富多彩的远离平衡系统的临界现象。 相似文献
45.
46.
基于文献[5]中我们所获得的本征型光学双稳系统的熵产生表达式,本文证明该系统(光学被动腔)能够很好地满足最小熵产生定理。
关键词: 相似文献
47.
F. M. Ragab 《Acta Mathematica》1954,92(1):1-11
In this paper, some new linear relations for MacRobert'sE-Functions are established. They are formulae (1), (10), (15), (20), (22) and (28) below. For the definitions and properties
of these functions, the reader is referred to MacRobert, “Functions of a Complex Variable” (3rd ed., London 1946), p. 348.
This work will be denoted by the letters C.V. Also some expansions of Bessel Functions are deduced. 相似文献
48.
The general equation for the velocity potential of quasi-one-dimensional acoustic wave motion in a variable area, finite duct with one-dimensional flow is derived by using a perturbation technique. The non-linear second-order partial differential equation is linearized and then solved, by either a power series expansion method or the Runge-Kutta fourth-order method, for harmonic time dependence. The boundary condition taken at the duct mouth is that of matching the impedance of the duct sound field to that of the radiation field at the duct opening. Three axial Mach number variations along the duct axis are considered and the results obtained are compared with those for the case of constant Mach number, to determine the influence of the axial velocity gradient on sound propagation. The effect of flow on the radiation impedance is also considered. 相似文献
49.
50.
H.M. Ragab 《Physica B: Condensed Matter》2011,406(20):3759-3767
Films of PVA/PVP blend (50/50) filled with different concentrations of NiCl2 were prepared by casting method. The prepared films were investigated by different techniques. XRD scans demonstrated that the peak intensity at 2θ≈20° decreased and the band width increased with increase in the concentrations of NiCl2 content, which implied decrease in the degree of crystallization and hence causes increase in the amorphous region. UV-vis analysis revealed that the values of the optical band gap are affected with increase in NiCl2 content. This indicates the formation of charge transfer complexes between the polymer blend and the filler. The rise of conductivity is significant with increased concentration of NiCl2 filler; this reveals an increase in degree of amorphosity. AC conductivity (σac) behavior of all the prepared films was investigated over the frequency range 42 Hz-5 MHz and under different isothermal stabilization in the temperature range 313-393 K. It suggests that the hopping mechanism might be playing an important role in the conduction process in high frequency region. The dielectric behavior was analyzed using dielectric permittivity (ε´, ε″) dielectric loss tangent (tan δ) and electric modulus (M″). The decrease in dielectric permittivity was observed with increase in the concentration of NiCl2 filler. This suggests the role of NiCl2 as filler to improve the electrical conductivity of PVA/PVP blend. 相似文献