Semi-classical transport for predicting joule heating in carbon nanotubes

A method for predicting the joule heating using Monte Carlo simulation for the electron dynamics is proposed. The joule heating in (10,10) carbon nanotubes is computed. The full energy band is utilized; however the results show that for low temperatures only the lower subband is sufficient, while for temperatures above 900 K, it is important to include all the subbands. Results are compared with a quantum mechanical integral form which uses an approximation for the electron occupation probability. There is a quantitative agreement of the results; however saturation of the heat generated observed in the integral form is not observed.     

Topological超共形代数的Leibniz中心扩张

通过计算得到了Topological N=2超共形代数丁的Leibniz二上同调群,从而确定了此代数的Leibniz中心扩张.     

Electrical conductivity improvement of strontium titanate doped lead vanadate glasses by nanocrystallization

The structural and electrical conductivity (σ) of annealed SrTiO₃–PbO₂–V₂O₅ glasses were studied. The annealing of initially glass samples leads to formation of nanocrystalline grains embedded in the glassy matrix. XRD patterns of the glass–ceramic samples show that nanocrystals were embedded in the glassy matrix with an average grain size of 32 nm. The glass–ceramic nanocrystals obtained by annealing at temperatures close to the crystallization temperature T_c exhibit enhancement of electrical conductivity up to four orders of magnitude than initially glasses. The enhancement of the electrical conductivity due to annealing was attributed to two interdependent factors: (i) an increase of concentration of V⁴⁺–V⁵⁺ pairs; and (ii) formation of defective, well-conducting regions along the glass–crystallites interfaces. From the conductivity temperature relation, it was found that small polaron hopping model was applicable at temperature above θ_D/2 (θ_D, the Debye temperature). The electrical conduction at T >θ_D/2 was due to non-adiabatic small polaron hopping (SPH) of electrons between vanadium ions. The parameters obtained from the fits of the experimental data to this model appear reasonable and are consistent with glass composition.     

一类超W-代数权空间维数有限的不可约模

本文研究了一类超W-代数上某一权空间维数有限的不可约权模,证明了该权模必是Harish-Chandra模.     

Darcy–Brinkman Flow through a Three-Dimensional Bumpy Channel with Stationary Random Model in the Slip Regime

Colloid Journal - A perturbation analysis is presented to study the flow of a Newtonian fluid in a three-dimensional channel with impermeable walls of random tortuosity filled with a porous medium....     

Atomic absorption spectroscopic, conductometric and colorimetric methods for determination of fluoroquinolone antibiotics using ammonium reineckate ion-pair complex formation

Three accurate, rapid and simple atomic absorption spectrometric, conductometric and colorimetric methods were developed for the determination of norfloxacin (NRF), ciprofloxacin (CIP), ofloxacin (OFL) and enrofloxacin (ENF). The proposed methods depend upon the reaction of ammonium reineckate with the studied drugs to form stable precipitate of ion-pair complexes, which was dissolved in acetone. The pink coloured complexes were determined either by AAS or colorimetrically at lambdmax 525 nm directly using the dissolved complex. Using conductometric titration, the studied drugs could be evaluated in 50% (v/v) acetone in the range 5.0-65, 4.0-48, 5.0-56 and 6.0-72 microg ml-1 of NRF, CPF, OFL and ENF, respectively. The optimizations of various experimental conditions were described. The results obtained showed good recoveries of 99.15 +/- 1.15, 99.30 +/- 1.40, 99.60 +/- 1.50, and 99.00 +/- 1.25% with relative standard deviations of 0.81, 1.06, 0.97, and 0.69% for NRF, CPF, OFL, and ENF, respectively. Applications of the proposed methods to representative pharmaceutical formulations are successfully presented.     

Spectrophotometric determination of certain cephalosporins in pure form and in pharmaceutical formulations

A simple and reproducible spectrophotometeric method for the assay of cefotaxime sodium, cefuroxime sodium, and ceftriaxone disodium with metol-chromium(VI) reagent has been developed. The procedure is based on direct oxidation of metol by potassium dichromate in presence of drug in acidic medium and subsequent formation of ternary complex. Beer's law is obeyed in the range 0.2-28 microg ml(-1) at lambdamax 520 nm. For more accurate analysis, Ringbom optimum concentration range is found to be 0.8-26.5 microg ml(-1). The molar absorptivity and Sandell sensitivity were calculated. Six replicate analysis of solutions containing seven different concentrations of the examined drugs were carried out and gave a mean correlation coefficient < or =0.9996; the factors of the regression line equation for the three cephalosporins were calculated. The proposed method was applied to the determination of the examined drugs in pharmaceutical formulations and the results demonstrated that the method is equally accurate, precise, and reproducible as the official methods.     

Synthesis of some novel pyrazolo[1,5-a]quinazolines and their fused derivatives

New pyrazolo[1,5-a]quinazoline-3-carbonitriles 4a,b were obtained via cyclocondensation of 5-amino-3-cyanomethyl-1H-pyrazole-4-carbonitrile (1) with enaminones of 1,3-cyclohexanedione derivatives 2a,b in refluxing glacial acetic acid. Condensation of compounds 4a,b with various aromatic aldehydes furnished the corresponding arylidene derivatives 6a–j. On the other hand, condensation of 4a,b with o-hydroxybenzaldehydes yielded the polyheterocyclic compounds 10a–h. Coupling of compounds 4a,b with aryldiazonium chlorides led to formation of 2-arylhydrazono derivatives 12a–h. Also, reaction of compounds 4a,b with phenyl isothiocyanate, followed by addition of ethyl chloroacetate and chloroacetonitrile, afforded the polyheterocyclic compounds based on pyrazolo[1,5-a]quinazoline core. The reaction of compounds 4a,b with phenyl isothiocyanate and elemental sulfur gave the thiazole-2-thione derivatives 25a,b. The reaction of enamines of compounds 4a,b with each of hydrazine hydrate and guanidine hydrochloride afforded pyrazolo[4″,3″:5′,6′]pyrido[4′,3′:3,4]pyrazolo[1,5-a]quinazolin-8-ones 30a,b and pyrimido[5″,4″:5′,6′]pyrido[4′,3′:3,4]pyrazolo[1,5-a]quinazolin-9(10H)-ones 33a,b, respectively. The structures of all the newly synthesized compounds were elucidated by elemental analyses and spectral data. The plausible mechanisms have been postulated to account for their formation.     

用三轴转台测量激光导引发射、接收视场角数据处理问题的探讨

研究了最一般情形下用三轴转台测量激光导引发射、接收视场角数据的处理问题,由此得出一般情形下计算视场角的公式,并给出了较为详细的推导过程。现场调试结果表明:通过该公式进行数据处理后,所得测试结果更符合实际情形,测试精度得到较大提高。