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51.
S. Boileau R. Ben Khalifa A. Jallouli L. Lestel D. Teyssi 《Macromolecular Symposia》1995,98(1):687-687
Polycarbosilane networks were prepared from well-defined α, ω-difunctional oligomers: X-[Si(CH3)2-CH2-CH2]n-X with X = H ( 1 ) and X = CH=CH2 ( 2 ). Crosslinking reactions were performed by hydrosilylation of tetramethyltetravinylcyclotetrasiloxane (V4) or of tetravinylsilane with SiH end groups of 1 . Hydrosilylation of Si-CH=CH2 end groups of 2 with tetramethyltetrahydrocyclotetrasiloxane (D4H) was also successfully tried. Some physicochemical properties of these new networks will be presented.1) Interpenetrating networks based on polysiloxanes and polycarbonates were synthesized by the in situ method: a polysiloxane bearing various proportions of room temperature crosslinkable -Si(OEt)3 side groups was mixed with bis(allyl ethylene glycol) biscarbonate and a free-radical initiator. After the formation of the first network at room temperature, the cross-linking of the polycarbonate network was performed by raising the temperature up to 80°C. Various chemical modifications of the polysiloxane component in the IPN were performed in order to improve the degree of interpenetration as estimated from turbidity, density, refractive index and DSC measurements.2) 相似文献
52.
Imen Ben Atitallah Georgia Antonopoulou Ioanna Ntaikou Amaia Soto Beobide Vassilios Dracopoulos Tahar Mechichi Gerasimos Lyberatos 《Molecules (Basel, Switzerland)》2022,27(4)
The effect of different pretreatment approaches based on alkali (NaOH)/hydrogen peroxide (H2O2) on willow sawdust (WS) biomass, in terms of delignification efficiency, structural changes of lignocellulose and subsequent fermentation toward ethanol, was investigated. Bioethanol production was carried out using the conventional yeast Saccharomyces cerevisiae, as well as three non-conventional yeasts strains, i.e., Pichia stipitis, Pachysolen tannophilus, Wickerhamomyces anomalus X19, separately and in co-cultures. The experimental results showed that a two-stage pretreatment approach (NaOH (0.5% w/v) for 24 h and H2O2 (0.5% v/v) for 24 h) led to higher delignification (38.3 ± 0.1%) and saccharification efficiency (31.7 ± 0.3%) and higher ethanol concentration and yield. Monocultures of S. cerevisiae or W. anomalus X19 and co-cultures with P. stipitis exhibited ethanol yields in the range of 11.67 ± 0.21 to 13.81 ± 0.20 g/100 g total solids (TS). When WS was subjected to H2O2 (0.5% v/v) alone for 24 h, the lowest ethanol yields were observed for all yeast strains, due to the minor impact of this treatment on the main chemical and structural WS characteristics. In order to decide which is the best pretreatment approach, a detailed techno-economical assessment is needed, which will take into account the ethanol yields and the minimum processing cost. 相似文献
53.
Towards a unified recurrent neural network theory: The uniformly pseudo-projection-anti-monotone net
In the past decades, various neural network models have been developed for modeling the behavior of human brain or performing
problem-solving through simulating the behavior of human brain. The recurrent neural networks are the type of neural networks
to model or simulate associative memory behavior of human being. A recurrent neural network (RNN) can be generally formalized
as a dynamic system associated with two fundamental operators: one is the nonlinear activation operator deduced from the input-output
properties of the involved neurons, and the other is the synaptic connections (a matrix) among the neurons. Through carefully
examining properties of various activation functions used, we introduce a novel type of monotone operators, the uniformly
pseudo-projectionanti-monotone (UPPAM) operators, to unify the various RNN models appeared in the literature. We develop a
unified encoding and stability theory for the UPPAM network model when the time is discrete. The established model and theory
not only unify but also jointly generalize the most known results of RNNs. The approach has lunched a visible step towards
establishment of a unified mathematical theory of recurrent neural networks. 相似文献
54.
55.
In this paper the effective mass approximation and the k·p multi-band models, describing quantum evolution of electrons in
a crystal lattice, are discussed. Electrons are assumed to move in both a periodic potential and a macroscopic one. The typical
period e{\epsilon} of the periodic potential is assumed to be very small, while the macroscopic potential acts on a much bigger length scale.
Such homogenization asymptotic is investigated by using the envelope-function decomposition of the electron wave function.
If the external potential is smooth enough, the k·p and effective mass models, well known in solid-state physics, are proved
to be close (in the strong sense) to the exact dynamics. Moreover, the position density of the electrons is proved to converge
weakly to its effective mass approximation. 相似文献
56.
57.
We describe a protocol for distilling maximally entangled bipartite states between random pairs of parties from those sharing a tripartite W state |W=(1/sqrt[3])(|100+|010+|001)(ABC), and show that the total distillation rate E(t)(infinity) [the total number of Einstein-Podolsky-Rosen (EPR) pairs distilled per W, irrespective of who shares them] may be done at a higher rate than EPR distillation between specified pairs of parties. Specifically, the optimal rate for distillation to specified parties has been previously shown to be 0.92 EPR pairs per W, while our protocol can asymptotically distill 1 EPR pair per W between random pairs of parties, which we conjecture to be optimal. We thus demonstrate a tradeoff between overall distillation rate and final distribution of EPR pairs. We further show that there exist states with fixed lower-bounded E(t)(infinity), but arbitrarily small distillable entanglement for specified parties. 相似文献
58.
P. C. Morais A. C. Oliveira V. K. Garg M. L. Silva E. F. C. Alcântara F. Q. Soares D. Rabelo 《Hyperfine Interactions》2007,177(1-3):51-56
We have used time-differential perturbed angular correlation (PAC) spectroscopy with 181Ta-probes to study the electric field gradient at Zr-sites in synthetic zircon and hafnon between room temperature and 1,200°C. PAC spectra are similar to those obtained from naturally occurring zircons. In particular, a change in slope of the quadrupole coupling vs. temperature is observed in the synthetic zircon at the same temperature as seen in natural zircons from the Mud Tank carbonatite (Australia). The synthetic hafnon data also shows this feature but at somewhat higher temperature. Low-temperature PAC spectra of both synthetic zircon and hafnon have a clearly reduced anisotropy. We believe that the cause for this is a electronic defect, possibly created during the β-decay of the probe parent nucleus. 相似文献
59.
The Maxwell-Wagner-Sillars (MWS) relaxation is studied for semi-crystalline polymers poly (ether ether ketone) (PEEK), in the range 20 Hz-1 MHz and temperature varying from 80 to 330 °C. The parameter is the crystallization condition in the case of PEEK, which is a semi-crystalline polymer considered as a particulate composite. The relaxation found in the semi-crystalline polymers above the α relaxation of the PEEK is ascribed to the trapping of conductive carriers at the interface between crystalline lamellae and the amorphous matrix. The study of PEEK microstructure is based on differential calorimetry and X-rays diffraction. Two lamellae populations have been detected, that depends on the crystallization temperature and its duration. The crystallinity rate is increasing with crystallization temperature and duration. In dielectric studies, the use of the electric modulus instead of permittivity allows us to minimize the ionic conduction and then leads to the appearance of the interfacial relaxation. According to our measurements, the crystallinity rate is not the main factor of the interfacial relaxation intensity, which also depends on the nature and degree of perfection of the lamellae. 相似文献
60.
Analysis Mathematica - We introduce and study the k-Hankel Gabor transform. We investigate the localization operators for this transform. In particular, we study their trace class properties and we... 相似文献