études sur les composés organométalliques,VIII. Synthése du tétrabenzyltitane

Tetrabenzyltitane is prepared by reaction of TiCl₄ on dibenzylmagnesium in pentane or hexane at – 20° in the presence of a small amount of ether.     

A novel group of highly hydroxylated steroids from the starfish Protoreaster nodosus

Thre novel polyhydroxylated sterols, 5-cholestane-3β,6,8,15,16β,26-hexol, 5-cholestane-3β,6,7,8,15,16β,26-heptol and 5-cholestane-3β,4β,6,7,8,15,16β,26-octol, have been isolated from the Pacific Starfish Protoreaster nodosus and their structures have been established through extensive ¹H NMR and ¹³C NMR studies, chemical transformations and related spectroscopic data.     

Poly(4-methylpentene-1)/hydrogenated oligo (cyclopentadiene) blends: Miscibility,tensile stress–strain,and dynamic mechanical behaviors

This article discusses the influence of the oligomeric resin, hydrogenated oligo(cyclopentadiene) (HOCP), on the morphology, and thermal and tensile mechanical properties of its blends with isotactic poly(4-methylpentene-1) (P4MP1). The P4MP1 and HOCP are found not miscible in the melt state. P4MP1/HOCP blends after solidification contain three phases: the crystalline phase of P4MP1, an amorphous phase of P4MP1, and an amorphous phase of HOCP. From optical micrographs obtained at 150°C, it is found that the solidified blends show a morphology constituted by P4MP1 microspherulites and small HOCP domains homogeneously distributed in intraspherulitic regions. DSC and DMTA results show that the blends present two glass transition temperatures (T_g) equal to the T_gs of the pure components. The tensile mechanical properties have been investigated at 20, 60, and 120°C. At 20°C both the HOCP oligomer and the amorphous P4MP1 are glassy, and it is found that all the blends are brittle and the stress–strain curves have equal trends. At 60°C the HOCP oligomer is glassy, whereas the amorphous P4MP1 is rubbery. The tensile mechanical properties at 60°C are found to depend on blend composition. It is found that the Young's modulus, the stresses at yielding and break points slightly decrease with HOCP content in the blends and these results are related to the decrease of blend crystallinity. The decrease of the elongation at break is accounted for by the presence of glassy HOCP domains that act as defects in the P4MP1 matrix, hampering the drawing. At 120°C both the amorphous phases are rubbery. It is found decreases of Young's modulus, stresses at yielding and break points. These results have been related to the decrease of blend crystallinity and to the increase of the total rubbery amorphous phase. Moreover, it is found that the blends present elongations at break equal to that of pure P4MP1. This constancy is attributed to: (a) at 120°C the HOCP domains are rubbery and their presence seems not to disturb the drawing of the samples; (b) a sufficient number of the tie-molecules and entanglements of P4MP1 present in the blends. In fact, although the numbers of tie-molecules and entanglements decrease in the blends, increasing the HOCP oligomer, they seem to be enough to keep the material interlaced and avoid earlier rupture. © 1997 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys 35 : 1269–1277, 1997     

On different geometric formulations of Lagrangian formalism

We consider two geometric formulations of Lagrangian formalism on fibred manifolds: Krupka's theory of finite order variational sequences, and Vinogradov's infinite order variational sequence associated with the -spectral sequence. On one hand, we show that the direct limit of Krupka's variational bicomplex is a new infinite order variational bicomplex which yields a new infinite order variational sequence. On the other hand, by means of Vinogradov's -spectral sequence, we provide a new finite order variational sequence whose direct limit turns out to be the Vinogradov's infinite order variational sequence. Finally, we provide an equivalence of the two finite order and infinite order variational sequences modulo the space of Euler-Lagrange morphisms.     

Evaluation of solubility parameters during polymerisation of amine‐cured epoxy resins

A new procedure for the calculation of solubility parameter evolution during polymerisation has been developed for amine‐cured epoxy systems, which allows quantitative thermodynamic modelling of chemically induced phase separation (CIPS). Solubility parameters calculation, chemical analysis based on near infrared spectroscopy and curing kinetics results obtained by differential scanning calorimetry will allow to model the evolution of the Flory–Huggins interaction parameter in amine‐cured epoxy blends. The resin system investigated was based on a diglycidyl ether bisphenol A (DGEBA) epoxy resin cured with isophorone diamine (IPD) blended with various reactive epoxydised dendritic hyperbranched polymer modifiers (HBP), yielding a CIPS‐controlled morphology. The analysis showed the evolution of the different contributions to the solubility parameters to follow the polymerisation kinetics. The dispersive contribution had the highest value at all stages of polymerisation, but the hydrogen and polar contributions showed the largest variation. By evaluating the dynamic evolution of the solubility parameter components, the Flory–Huggins interaction parameter in the epoxy resin‐hyperbranched polymer blends has been modelled as a function of time. This procedure, combined with thermodynamic modelling, will enable to predict phase diagrams in CIPS thermosetting blends quantitatively. © 2000 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys 38: 1883–1892, 2000     

VIP-2 —High-Sensitivity Tests on the Pauli Exclusion Principle for Electrons

The VIP collaboration is performing high sensitivity tests of the Pauli Exclusion Principle for electrons in the extremely low cosmic background environment of the underground Gran Sasso National Laboratory INFN (Italy). In particular, the VIP-2 Open Systems experiment was conceived to put strong constraints on those Pauli Exclusion Principle violation models which respect the so-called Messiah–Greenberg superselection rule. The experimental technique consists of introducing a direct current in a copper conductor, and searching for the X-rays emission coming from a forbidden atomic transition from the L shell to the K shell of copper when the K shell is already occupied by two electrons. The analysis of the first three months of collected data (in 2018) is presented. The obtained result represents the best bound on the Pauli Exclusion Principle violation probability which fulfills the Messiah–Greenberg rule.     

Miscibility and phase behavior in atactic polystyrene and poly(o-chlorostyrene-co-p-chlorostyrene) blends: Effect of polystyrene molecular weight and copolymer composition

Miscibility in blends of random copolymers of o-chlorostyrene and p-chlorostyrene [P(oClSy-co-pClS_1-y)] with 8 atactic polystyrene (aPS) fractions has been studied at temperatures ranging from 150°C to 300°C. Miscibility windows whose size depends on the molecular weight of the PS and on the copolymer composition, y, were observed for each blend. From these data, the temperature dependence of the three segmental interaction parameters required to describe this system were obtained.     

Breakup and breakdown of bent kerosene jets in gas turbine conditions

Jet A-1 kerosene injection in air crossflow conditions has been studied for temperature up to 600 K and pressure up to 2 MPa. Thousand frames of jet shadowgraphs have been sampled for each of the 82 experimental conditions to determine statistical parameters characterizing the jet behavior. Among them the breakdown point, corresponding to the spatial position along the jet where the momentum jet looses its coherence, is the most relevant one. The axial coordinate of this point is strongly correlated with the liquid–gas momentum ratio while the breakdown position in gas stream direction mainly depends on the aerodynamic Weber number. This shows that the deformation of the liquid before and after its primary atomization is the most significant correction in respect to the ballistic, inviscid evolution of a bent cylindrical jet. The generalized profile equation, normalized to the breakdown coordinates, is invariant in respect of whatever external parameter and it predicts with high level of accuracy the measured profile upstream of the breakdown position.