排序方式: 共有53条查询结果,搜索用时 406 毫秒
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Laxman Singh Ravikant Sharma Narayan Singh Atendra Kumar Dev K Mahato Youngil Lee Mikhael Bechelany KD Mandal 《Progress in Crystal Growth and Characterization of Materials》2021,67(4):100542
This review paper covers the low temperature wet growth of nano-engineered particles of ZnO-based mixed metal oxides, their growth mechanism, and characterization using X-ray diffraction, SEM, TEM and IR, UV–visible, and XPS spectral techniques. Main focus of this article is centered on low temperature semi-wet methods of synthesis that are suitable for large scale production of zinc oxide-based systems mixed with iron oxide, copper oxide, nickel oxide and cobalt oxide. These mixed metal oxides have broad industrial applications as catalyst, semiconductors, adsorbents, superconductors, electro-ceramics, and antifungal agents in addition to extensive applications in medicines. This paper discusses the low-cost and environment friendly synthesis of these mixed metal oxides, measurement of properties and applicability of these materials systems. 相似文献
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Dominik Jacob Kathrin Thüring Aurellia Galliot Virginie Marchand Adeline Galvanin Akif Ciftci Karin Scharmann Michael Stock Jean‐Yves Roignant Sebastian A. Leidel Yuri Motorin Raffael Schaffrath Roland Klassen Mark Helm 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(28):9666-9670
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Dr. Gerrit Jürjens Dr. Sören M. M. Schuler Dr. Michael Kurz Dr. Sylvain Petit Dr. Cédric Couturier Dr. Frédéric Jeannot Fabian Nguyen Dr. Raffael C. Wende Prof. Dr. Peter E. Hammann Prof. Dr. Daniel N. Wilson Dr. Eric Bacqué Dr. Christoph Pöverlein Dr. Armin Bauer 《Angewandte Chemie (International ed. in English)》2018,57(37):12157-12161
The total synthesis of the naturally occurring antibiotic GE81112A, a densely functionalized tetrapeptide, is reported. Comparison of spectral data with those of the natural product and the lack of biological activity of the synthesized compound led us to revise the published configuration of the 3‐hydroxypipecolic acid moiety. This hypothesis was fully validated by the synthesis of the corresponding epimer. 相似文献
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Blanchet V Raffael K Turri G Chatel B Girard B Garcia IA Wilkinson I Whitaker BJ 《The Journal of chemical physics》2008,128(16):164318
Pump-probe photoionization has been used to map the relaxation processes taking place from highly vibrationally excited levels of the S(2) state of azulene, populated directly or via internal conversion from the S(4) state. Photoelectron spectra obtained by 1+2(') two-color time-resolved photoelectron imaging are invariant (apart from in intensity) to the pump-probe time delay and to the pump wavelength. This reveals a photoionization process which is driven by an unstable electronic state (e.g., doubly excited state) lying below the ionization potential. This state is postulated to be populated by a probe transition from S(2) and to rapidly relax via an Auger-like process onto highly vibrationally excited Rydberg states. This accounts for the time invariance of the photoelectron spectrum. The intensity of the photoelectron spectrum is proportional to the population in S(2). An exponential energy gap law is used to describe the internal conversion rate from S(2) to S(0). The vibronic coupling strength is found to be larger than 60+/-5 microeV. 相似文献
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Sorgues S Poisson L Raffael K Krim L Soep B Shafizadeh N 《The Journal of chemical physics》2006,124(11):114302
A systematic study of the ultrafast decay of metalloporphyrins containing various transition metals with partially filled 3d shells and zinc (3d filled) is reported here after excitation in the second excited state of the system (Soret band). Both time-of-flight mass spectrometry and velocity map imaging have been used for detection. A general biexponential decay with a short time constant tau1 approximately 100 fs is observed for the transition metal porphyrins, followed by a tau2 approximately 1 ps time decay. This evolution is interpreted as a porphyrin-to-metal charge transfer, tau1, followed by a back transfer, tau2, which leads to an excited state (d,d*) localized on the metal. These conclusions stem from the different behaviors of zinc and the transition metal porphyrins. A porphyrin-to-metal charge transfer model is chosen to describe the relaxation mechanism, based upon the fact that transition metalloporphyrins can accept electrons on the metal site, in contrast to zinc porphyrins. 相似文献
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We consider a collapsing spherically symmetric inhomogeneous dust cloud in higher dimensional space-time. We show that the
central singularity of collapse can be a strong curvature or a weak curvature naked singularity depending on the initial density
distribution. 相似文献
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Nadine S Simons-Weidenmaier Maruschka Weber Claudia F Plappert Peter KD Pilz Susanne Schmid 《BMC neuroscience》2006,7(1):38