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71.
Radim Pilař Pavla Honcová Petr Koštál Galina Sádovská Ladislav Svoboda 《Journal of Thermal Analysis and Calorimetry》2014,118(1):485-491
The methods of heat capacity data determination from differential scanning calorimetry measurements are described. The negative effects increasing uncertainty of heat capacity determination are mentioned. Modified stepwise method was described and verified using molybdenum, copper, and gold standards. Modified stepwise method provides better accuracy of C p values compared to continuous and stepwise method. 相似文献
72.
V Novakova RZ Kobak R Kučera K Kopecky M Miletin V Krepsová J Ivincová P Zimcik 《Dalton transactions (Cambridge, England : 2003)》2012,41(35):10596-10604
A series of azaphthalocyanines (AzaPc) bearing one, two, four or eight isopropylidene-protected galactosyl units was prepared by azide-alkyne click reaction or by classical Pc template cyclotetramerization of the corresponding dicyanopyrazine and AzaPc properties important for photodynamic therapy were compared. All compounds absorbed at long wavelengths (above 650 nm) and belonged to strong singlet oxygen producers (Φ(Δ) = 0.58-0.64) retaining significant fluorescence emission (Φ(F) = 0.026-0.23). The only exception was the compound with four isopropyliden-protected galactosyl units where partial aggregation was observed. Removal of protecting groups increased the polar character of all AzaPc. However, only AzaPc bearing eight galactoses was found to be water-soluble (105 mg mL(-1)) but noticeably aggregated in water as well as in organic solvents (DMF, DMSO). Amphiphilic AzaPc bearing one deprotected galactose was incorporated into the lipidic bilayer of liposomes in a nonaggregated form. Liposomes may therefore be a suitable delivery system for this amphiphilic photosensitizer. 相似文献
73.
We report on the experimental verification of quantum non-Gaussian character of a heralded single-photon state with a positive Wigner function. We unambiguously demonstrate that the generated state cannot be expressed as a mixture of Gaussian states. Sufficient information to witness the quantum non-Gaussian character is obtained from a standard photon anticorrelation measurement. 相似文献
74.
Hrdina R Müller CE Wende RC Lippert KM Benassi M Spengler B Schreiner PR 《Journal of the American Chemical Society》2011,133(20):7624-7627
We present a new class of catalysts based on the combination of N,N'-diaryl(thio)ureas and weak silicon Lewis acids (e.g., SiCl(4)). Such silicon-(thio)urea catalysts effectively catalyze the stereospecific rearrangement of epoxides to quaternary carbaldehydes. 相似文献
75.
The structure of ionic complex [Cp2Ti(L -Met)2]2+[Cl−]2 (where Cp = η5-C5H5) possessing C2 symmetry is presented. Discrete cationic units with distorted tetrahedral geometry around the central titanium atom are connected through intermolecular H···Cl bonds between ammonium group protons of α-amino acid ligands and chloride anions. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献
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77.
We present the numbers of all non-isomorphic residuated lattices with up to 12 elements and a link to a database of these lattices. In addition, we explore various characteristics of these lattices such as the width, length, and various properties considered in the literature and provide the corresponding statistics. We also present algorithms for computing finite residuated lattices including a fast heuristic test of non-isomorphism. 相似文献
78.
As has been pointed out in a study by Cao, there is an erroneous omission in the study by Axelsson, Corollary 3.2 and Proposition 3.2, and the authors thank Zhi‐hao Cao for pointing this out. We mention, however, that these are side results and do not influence the major result of the paper ‘Preconditioning of matrices partitioned in 2 by 2 block form: Eigenvalue estimates and Schwarz DD for mixed FEM’. In this reply, we give a short background to the relations between inverses of saddle point matrices, thereby providing justified references to previous publications of the topic and present a corrected and extended version of Proposition 3.2. This gives an alternative presentation of the statements in the study by Cao, which might be useful for readers. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
79.
Radim Horák Lubomír Kvapil Kamil Motyka Ludmila Slaninová Martin Grepl Kamil Kořistek Miroslav Urbášek Pavel Hradil Miroslav Soural 《Tetrahedron》2018,74(2):366-374
2-Alkenyl-3-hydroxyquinolin-4(1H)-ones were prepared by the rearrangement of anthranilic acid esters synthesized by two alternative methods. The prepared derivatives were screened for their antimicrobial activities against representative Gram-positive and Gram-negative bacteria, displaying notable minimum inhibitory concentration values against specific strains. The emission spectra of the target quinolines exhibited two well-separated emission bands, and the maximum excitation wavelengths of the selected compounds were detected at relatively high values. 相似文献
80.
Lukáš Šimurka Radim Čtvrtlík Jan Tomaštík Gence Bektaş Jan Svoboda Klaus Bange 《Chemical Papers》2018,72(9):2143-2151
The optical and mechanical properties of amorphous SiO2 films deposited on soda-lime silicate float glass by reactive RF magnetron sputtering at room temperature were investigated in dependence of the process pressure. The densities of the films are strongly influenced by the process pressure and vary between 2.38 and 1.91 g cm?3 as the pressure changes from 0.27 to 1.33 Pa. The refractive indices of the films shift between 1.52 and 1.37, while the residual compressive stresses in the deposited films vary in the range from 440 to 1 MPa. Hardness and reduced elastic modulus values follow the same trend and decline with the increase of process pressure from 8.5 to 2.2 GPa and from 73.7 to 30.9 GPa, respectively. The abrasive wear resistance decreases with the density of the films. 相似文献