Inhibition of copper corrosion in acidic sulphate media by eco-friendly amino acid compound

This investigation aimed to study a “green” non-toxic biodegradable copper corrosion inhibitor in an acidic sodium sulphate solution. The methods used in the investigation of cysteine as a copper corrosion inhibitor in an acidic sodium sulphate solution were: potentiodynamic measurements, open circuit potential measurements, and chronoamperometric measurements. Optical microscopy was used in addition to electrochemical methods. Potentiodynamic measurements show that cysteine has good inhibitory properties in an acidic medium. Polarisation curves indicate that the presence of cysteine in a sulphate solution decreases the current density and that using various cysteine concentrations results in the formation of a protective film on the surface of the electrode due to the formation of the Cu(I)-cys complex. These results are confirmed by chronoamperometric measurements. Furthermore, it is clear from microphotographs that a protective film does form on copper electrode in the presence of cysteine. The Langmuir adsorption isotherm indicates that cysteine is chemisorbed on the surface of the electrode.     

Determining elemental strontium distribution in rat bones treated with strontium ranelate and strontium citrate using 2D micro-XRF and 3D dual energy K-edge subtraction synchrotron imaging

Strontium-based medications, such as strontium ranelate, have been suggested to have therapeutic effects in patients with osteoporosis. Strontium salts available off-shelf in stores across North America are assumed to provide similar effects as strontium ranelate and thus should lead to similar distributions of elemental strontium incorporated in bone. The objective of this study was to compare the spatial distribution of strontium in animal bones following the administration of strontium ranelate and strontium citrate. Seventeen-week-old Sprague–Dawley rats were split into three groups over 10 weeks and given 625 mg/kg/day of strontium ranelate and 676 mg/kg/day of strontium citrate; the control group received no additional supplementary strontium. The humeri were collected from all animals, and strontium distribution was mapped using 2D micro-XRF and 3D dual energy K-edge subtraction (KES) imaging. 2D and 3D elemental mapping methods demonstrated that strontium delivered during treatment by both salts had the same spatial distribution. 3D elemental strontium maps of treated animal bones showed that strontium was largely observed in the trabecular regions under the epiphyseal (growth) plate. The thickness of the strontium layers in both the strontium ranelate and strontium citrate sample was not significantly different (p = .9201). 2D micro-XRF and 3D dual-energy KES images effectively elucidated the spatial distribution of elemental strontium in calcified tissue. These methods provide a novel approach to evaluating the potential efficacy of strontium supplements in the treatment of osteoporosis.     

Application of very weak formulation on homogenization of boundary value problems in porous media

Czechoslovak Mathematical Journal - The goal of this paper is to present a different approach to the homogenization of the Dirichlet boundary value problem in porous medium. Unlike the standard...     

Low latency localization of multiple sound sources in reverberant environments

Sound source localization algorithms determine the physical position of a sound source in respect to a listener. For practical applications, a localization algorithm design has to take into account real world conditions like multiple active sources, reverberation, and noise. The application can impose additional constraints on the algorithm, e.g., a requirement for low latency. This work defines the most important constraints for practical applications, introduces an algorithm, which tries to fulfill all requirements as good as possible, and compares it to state-of-the-art sound source localization approaches.     

Production of heavy fragments in interactions of high-energy protons with silver

A silver target was exposed to 14, 18 and 23 GeV protons. The values of the cross-sections for production of events with two and three fragments have been determined by the use of a polycarbonate detector. The results obtained show that these events are due to fission as well as to fragmentation and spallation.     

Interplay between phase defects and spin polarization in the specific heat of the spin-density-wave compound (TMTTF)2Br in a magnetic field

Equilibrium heat relaxation experiments provide evidence that the ground state of the commensurate spin-density-wave compound (TMTTF)2Br after the application of a sufficient magnetic field is different from the conventional ground state. The experiments are interpreted on the basis of the local model of strong pinning as the deconfinement of soliton-antisoliton pairs triggered by the Zeeman coupling to spin degrees of freedom, resulting in a magnetic-field-induced density-wave glass for the spin carrying the phase configuration.     

The formaldehyde cation: Rovibrational energy level structure and Coriolis interaction near the adiabatic ionization threshold

Rotationally resolved pulsed-field-ionization zero-kinetic-energy photoelectron spectra of the 0⁰, 6¹ and 4¹ vibrational levels of the ground electronic state of the formaldehyde cation were recorded using a resonant three-color three-photon excitation scheme. The first adiabatic ionization energy of CH₂O (87793.33(1.30) cm⁻¹) and the rigid-rotor rotational constants (A⁺ = 8.874(8) cm⁻¹, B⁺ = 1.342(15) cm⁻¹, C⁺ = 1.148(18) cm⁻¹) of the vibronic ground state of CH₂O⁺ were derived. A strong a-type Coriolis interaction between the 6¹ and 4¹ vibrational levels was observed. The Coriolis coupling parameter and the deperturbed fundamental vibrational frequencies of the in-plane-rocking mode ν₆ and the out-of-plane bending mode ν₄ were determined to be 8.70(10) cm⁻¹, 823.67(30) cm⁻¹ and 1036.50(30) cm⁻¹, respectively. The intensity distribution of the photoelectron spectra was analyzed in the realm of a simple photoionization model.     

Percolation magnetoresistance in ferromagnetic superconductors

It is shown that the magnetoresistance (as a function of magnetic field H) in polycrystalline magnetic superconductors has the percolation character which is the consequence of the anisotropy of magnetic susceptibility. The magnetoresistance R_m(H), and the upper critical field H_c2(T) of ErRh₄B₄ are evaluated and compared with the experimental data.