全文获取类型
收费全文 | 1689篇 |
免费 | 18篇 |
国内免费 | 22篇 |
专业分类
化学 | 1099篇 |
晶体学 | 15篇 |
力学 | 52篇 |
数学 | 313篇 |
物理学 | 250篇 |
出版年
2022年 | 17篇 |
2021年 | 23篇 |
2020年 | 16篇 |
2019年 | 19篇 |
2018年 | 19篇 |
2017年 | 21篇 |
2016年 | 38篇 |
2015年 | 21篇 |
2014年 | 44篇 |
2013年 | 81篇 |
2012年 | 80篇 |
2011年 | 76篇 |
2010年 | 59篇 |
2009年 | 68篇 |
2008年 | 87篇 |
2007年 | 111篇 |
2006年 | 102篇 |
2005年 | 86篇 |
2004年 | 78篇 |
2003年 | 59篇 |
2002年 | 49篇 |
2001年 | 35篇 |
2000年 | 25篇 |
1999年 | 20篇 |
1998年 | 20篇 |
1997年 | 22篇 |
1996年 | 33篇 |
1995年 | 24篇 |
1994年 | 22篇 |
1993年 | 23篇 |
1992年 | 19篇 |
1991年 | 16篇 |
1990年 | 21篇 |
1989年 | 15篇 |
1988年 | 17篇 |
1987年 | 14篇 |
1986年 | 15篇 |
1985年 | 25篇 |
1984年 | 20篇 |
1983年 | 16篇 |
1982年 | 24篇 |
1981年 | 14篇 |
1980年 | 18篇 |
1979年 | 11篇 |
1978年 | 14篇 |
1977年 | 19篇 |
1976年 | 14篇 |
1975年 | 6篇 |
1974年 | 9篇 |
1965年 | 8篇 |
排序方式: 共有1729条查询结果,搜索用时 13 毫秒
31.
Jerzy F. Plebański Maciej Przanowski 《International Journal of Theoretical Physics》1994,33(7):1535-1551
Electrodynamics admitting a duality transformation group is considered. For such an electrodynamics an extension of the classical Rainich-Misner-Wheeler theory is presented.On leave of absence from the University of Warsaw, Warsaw, Poland. 相似文献
32.
It is proved that a Lagrangian field theory based on a linear connection in space-time is equivalent to Einstein's general relativity interacting with additional matter fields. 相似文献
33.
It is shown how the energy-positivity criterion enables us to localize the energy in various field theories. For this purpose the role of surface integrals in a canonical formalism is investigated. The same techniques are applied to linearized gravity, where the mixed Cauchy-boundary value problem in a finite volume is analyzed. Unconstrained degrees of freedom and boundary data which have to be controlled are found. This paper is part of a program to analyze the possibility of localization of gravitational energy in complete General Relativity. 相似文献
34.
Grzegorz Stepniak Lukasz Maksymiuk Jerzy Siuzdak 《Optical and Quantum Electronics》2007,39(15):1281-1288
Frequency response of passive optical network (PON) based on multimode fibers is investigated. The network comprises fibers,
connectors and splitters/couplers. It is shown that due to mode filtering at splitters, the frequency response is different
for different network nodes in otherwise symmetrical network. 相似文献
35.
Noise map validation by continuous noise monitoring 总被引:1,自引:0,他引:1
Piotr Mioduszewski Jerzy A. Ejsmont Jan Grabowski Daniel Karpiński 《Applied Acoustics》2011,72(8):582-589
This paper presents a comparison of two noise assessments in the Gdansk agglomeration in Poland. One is based on the noise map produced by computational method for the city in 2007, the second one is based on real data from continuous measurements acquired by a noise monitoring network operating in the city since 2008. Differences are shown and analyzed. Additionally, seasonal and weekday influence on noise indicators (LDEN, LD, LE and LN) is analyzed and discussed in this paper. 相似文献
36.
Dutka M Gurbiel RJ Kozioł J Froncisz W 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2004,170(2):5786-227
Applicability of continuous wave multiquantum EPR methods to study relaxation times at X-band is examined. Multiquantum transitions excited in a two-level system by tetrachromatic irradiation are used for these studies. The Bloch equation model is applied to simulate lineshapes of the three quantum transitions as a function of frequency difference between exciting fields. The dependence of multiquantum transition signals on relaxation times and microwave amplitude is shown. On this basis a method of deducing relaxation times from these signals is formulated. The case of a homogeneously and inhomogeneously broadened resonance line is considered. Two experimental methods are used to verify the proposed hypothesis: the X-band continuous wave multiquantum EPR with four frequencies microwave field and saturation recovery EPR. The values of T1 obtained from CW MQ EPR and SR EPR are compared. 相似文献
37.
A localH-theorem is derived for a recently proposed extension of Enskog kinetic theory to a dense model fluid composed of particles with interactions extending beyond a hard core.On leave from: Katedra Fizyki, Uniwersytetu Szczecinskiego, 70-451 Szczecin, Poland. 相似文献
38.
39.
pH‐controlled reaction divergence of decarboxylation versus fragmentation in reactions of dihydroxyfumarate with glyoxylate and formaldehyde: parallels to biological pathways 下载免费PDF全文
Christopher J. Butch Jing Wang Jiande Gu Rebeca Vindas Jacob Crowe Pamela Pollet Leslie Gelbaum Jerzy Leszczynski Ramanarayanan Krishnamurthy Charles L. Liotta 《Journal of Physical Organic Chemistry》2016,29(7):352-360
The reactions of dihydroxyfumarate with glyoxylate and formaldehyde exhibit a unique pH‐controlled mechanistic divergence leading to different product suites by two distinct pathways. The divergent reactions proceed via a central intermediate (2,3‐dihydroxy‐oxalosuccinate, 3 , in the reaction with glyoxylate and 2‐hydroxy‐2‐hydroxymethyl‐3‐oxosuccinate, 14 , in the reaction with formaldehyde). At pH 7–8, products ( 7 , 8 , and 15 ) exclusively from a decarboxylation of the intermediate are observed, while at pH 13–14, products ( 9 , 10 , and 16 ) solely derived from a hydroxide‐promoted fragmentation of the intermediate are formed. The decarboxylative and fragmentation pathways are mutually exclusive and do not appear to coexist under the range of pH (7–14) conditions investigated. Herein, we employ a combination of quantitative 13C NMR measurements and density functional theory calculations to provide a rationale for this pH‐driven reaction divergence. These rationalizations also hold true for the reactions of dihydroxyfumarate produced in situ by the catalytic cyanide‐mediated dimerization of glyoxylate. In addition, the non‐enzymatic decarboxylation and fragmentation transformations of these central intermediates ( 3 and 14 ) appear to have intriguing parallels to the enzymatic reactions of oxalosuccinate and formation of glyceric acid derivatives in extant metabolism – the high and low pH mimicking the precise control exerted by the enzymes over reaction pathways. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献
40.
The paper presents the results of investigation studies involving the impact of atmospheric factors on sound-absorbing parameters of roadside acoustic screen panels. The research studies comprised the aging test consisting of 1000 cycles in simulated conditions, sound absorption measurements and surface morphology tests, using the SEM scanning method. The simulation of aging consisted of 100 or 150 cycles at a time. Then, the panels were investigated in the reverberation chamber to define their sound-absorbing properties. The process was repeated until 1000 cycles were completed. Basing on the carried out tests, a statistical linear model was worked out which was used to estimate the value of a single number sound absorption coefficient after successive aging cycles. The optimality of the model was demonstrated by means of a statistical test confirming normal distribution of random residuals. For the research studies, we employed an innovative structural design of panels for which aging characteristics were obtained. Basing on the obtained results and on the statistical analysis, the prospects to maintain acoustic properties of the panels during their service life was estimated. 相似文献