全文获取类型
收费全文 | 372篇 |
免费 | 12篇 |
国内免费 | 2篇 |
专业分类
化学 | 252篇 |
晶体学 | 5篇 |
力学 | 36篇 |
数学 | 61篇 |
物理学 | 32篇 |
出版年
2023年 | 3篇 |
2022年 | 15篇 |
2021年 | 8篇 |
2020年 | 8篇 |
2019年 | 12篇 |
2018年 | 9篇 |
2017年 | 9篇 |
2016年 | 20篇 |
2015年 | 6篇 |
2014年 | 18篇 |
2013年 | 34篇 |
2012年 | 28篇 |
2011年 | 23篇 |
2010年 | 13篇 |
2009年 | 18篇 |
2008年 | 20篇 |
2007年 | 20篇 |
2006年 | 15篇 |
2005年 | 8篇 |
2004年 | 17篇 |
2003年 | 15篇 |
2002年 | 15篇 |
2001年 | 6篇 |
2000年 | 2篇 |
1999年 | 5篇 |
1998年 | 10篇 |
1997年 | 3篇 |
1996年 | 5篇 |
1995年 | 2篇 |
1994年 | 3篇 |
1993年 | 2篇 |
1992年 | 3篇 |
1989年 | 3篇 |
1985年 | 1篇 |
1980年 | 1篇 |
1979年 | 1篇 |
1978年 | 3篇 |
1938年 | 1篇 |
1921年 | 1篇 |
排序方式: 共有386条查询结果,搜索用时 15 毫秒
51.
Nunes SP Karunakaran M Pradeep N Behzad AR Hooghan B Sougrat R He H Peinemann KV 《Langmuir : the ACS journal of surfaces and colloids》2011,27(16):10184-10190
The supramolecular assembly of PS-b-P4VP copolymer micelles induced by selective solvent mixtures was used to manufacture isoporous membranes. Micelle order in solution was confirmed by cryo-scanning electron microscopy in casting solutions, leading to ordered pore morphology. When dioxane, a solvent that interacts poorly with the micelle corona, was added to the solution, polymer-polymer segment contact was preferential, increasing the intermicelle contact. Immersion in water gave rise to asymmetric porous membranes with exceptional pore uniformity and high porosity. The introduction of a small number of carbon nanotubes to the casting solution improved the membrane stability and the reversibility of the gate response in the presence of different pH values. 相似文献
52.
A library of novel, lipid-modified derivatives of ascorbic acid was shown to exhibit highly attractive properties as surfactants, emulsifiers, oil soluble antioxidants, and highly effective gelators in organic solvents and especially water. In these systems, intermolecular hydrogen bonding and van der Waals forces act synergistically to induce gelation as confirmed by spectroscopic studies. The morphology of the formed gel has been characterized by scanning electron microscopy. 相似文献
53.
Mercey G Verdelet T Saint-André G Gillon E Wagner A Baati R Jean L Nachon F Renard PY 《Chemical communications (Cambridge, England)》2011,47(18):5295-5297
Nerve agents are highly toxic organophosphorus compounds with strong inhibition potency against acetylcholinesterase (AChE). Herein, we describe two first extremely promising uncharged reactivators for poisoned human AChE with a superior or similar in vitro ability to reactivate the enzyme as compared to that of HI-6, obidoxime, TMB-4 and HL?-7. 相似文献
54.
The stability and singularity problem of agile small satellite (ASS) with actuator failure is discussed in this paper. Firstly, the three-axis stabilized controller of an ASS is designed, where micro control moment gyros (MCMG's) in pyramid configuration (PC) is used as the actuator. By using the same controller and steering law, the control results before and after one gyro fails are compared by simulation. The variation of singular momentum envelope before and after one gyro fails is also compared. The simulation results show that the failure intensively decreases the capacity of output torque, which leads to the emergence of more singular points and the rapid saturation of MCMG's. Finally, the parameters of system controller are changed to compare the control effect. 相似文献
55.
Yassine Benmassaoud Khaled Murtada Rachid Salghi Mohammed Zougagh ngel Ríos 《Molecules (Basel, Switzerland)》2021,26(9)
In this study, we combine magnetic solid phase extraction (MSPE), with the screen-printed carbon electrode (SPCE) modified by a molecular imprinted polymer (MIP) for sensitive and selective extraction and electrochemical determination of Rhodamine B in food samples. A magnetic solid phase extraction (MSPE) was carried out using magnetic poly(styrene-co-divinylbenzene) (PS-DVB) and magnetic nanoparticles (MNPs) synthetized on the surface of multiwalled carbon nanotubes (MWCNTs). An MIP was prepared on the surface of MWCNTs in the presence of titanium oxide nanoparticles (TiO2NPs) modifying the SPCE for the rapid electrochemical detection of Rhodamine B. The MIPs synthesis was optimized by varying the activated titanium oxide (TiO2) and multiwalled carbon nanotubes (MWCNTs) amounts. The MSPE and electrochemical detection conditions were optimized as well. The present method exhibited good selectivity, high sensitivity, and good reproducibility towards the determination of Rhodamine B, making it a suitable method for the determination of Rhodamine B in food samples. 相似文献
56.
Wakif Abderrahim Chamkha Ali Thumma Thirupathi Animasaun I. L. Sehaqui Rachid 《Journal of Thermal Analysis and Calorimetry》2021,143(2):1201-1220
Journal of Thermal Analysis and Calorimetry - Sequel to the fact that hybrid nanofluidic systems (e.g. scalable micro-/nanofluidic device) exhibit greater thermal resistance with increasing... 相似文献
57.
Jean-Michel NavarreDominique Guianvarc'h Audrey Farese-Di GiorgioRoger Condom Rachid Benhida 《Tetrahedron letters》2003,44(10):2199-2202
A short route to novel α-(2-aminothiazolyl)-C-nucleosides has been developed. The key step was the high diastereoselective reduction of the hemiacetal intermediates using L-Selectride, which afforded the corresponding R-diols in quantitative yields. These diols were converted, after C4-C1 ring closure and protecting groups cleavage, to their corresponding free α-C-nucleosides. 相似文献
58.
A thermodynamic approach with internal variables using Lagrange formalism. Part I: General framework 总被引:1,自引:0,他引:1
Rachid Rahouadj Jean-Franois Ganghoffer Christian Cunat 《Mechanics Research Communications》2003,30(2):109-117
We present some reflections on the application of the Lagrangian formalism for continuous media locally uniform subjected to internal irreversible evolutions. The Lagrangian density, defined as the time derivative of a non-equilibrium thermodynamic potential, [Thermodynamics of Relaxation Processes using Internal variables within a Lagrange-formalism. P. Germain’s Anniversary Volume 2000. Contiuum Thermomechanics: the Art and Science of Modeling Matter’s Behaviour, 2000], contains all the symmetry properties of the system. The generalised Lagrange co-ordinates correspond to the state and internal variables of the time derivative of the generalised Gibbs potential. The latter being used within the framework of the De Donder’s method, must also account for the memory effect of the physical medium.This first part is devoted to the thermodynamic framework called the distribution of non-linear relaxations approach (DNLR) developed by C. Cunat on the basis of the generalised Gibbs’ relation. 相似文献
59.
Lahcen Hssaini Francisca Hernandez Manuel Viuda-Martos Jamal Charafi Rachid Razouk Karim Houmanat Rachida Ouaabou Said Ennahli Driss Elothmani Ilham Hmid Marie Laure Fauconnier Hafida Hanine 《Molecules (Basel, Switzerland)》2021,26(9)
In the present study, chromatic coordinates, phenolic acids, flavonoids and antioxidant capacity assessed by 1,1-diphenyl-2-picrylhydrazyl (DPPH), 2,2′-azino-bis (3-ethylbenzothiazoline-6-sulfonate (ABTS) and lipid peroxidation inhibition capacity (LPIC) essays and their relative IC50 were investigated in 25 fig cultivars growing in Morocco. The aims of this study were to determine (i) the variation in these compounds among light and dark-colored cultivars, (ii) their partitioning between fruit peel and pulp and (iii) to display network connections among these variables. Twelve phenolic compounds (PCs) were isolated in peel extract versus eight in pulp samples. Anthocyanins, mainly cyanidin-3,5-diglucoside and cyanidin-3-O-rutinoside, were the predominant compounds in peels, where the mean concentrations were 75.90 ± 18.76 and 77.97 ± 18.95 µg/g dw, respectively. On the other hand, (−)-epicatechin and cyanidin-3-O-rutinoside were the major compounds in the pulp extracts, where the mean values were 5.23 ± 4.03 and 9.01 ± 5.67 µg/g dw, respectively. A two-dimensional hierarchically clustered heatmap was applied to the dataset to explore correlations in the dataset and similarities between cultivars, without dimensionality reduction. Results showed that anthocyanins, particularly pelargonidin-3-O-rutinoside, cyanidin-3,5-diglucoside and cyanidin-3-O-rutinoside, were the main contributors to the peels’ free radical scavenging capacity. This capacity was particularly higher in the peel of dark-colored figs compared to the fruit pulp. The local cultivar “INRA 1301” showed the most promising phenolic profile due to its very high levels of almost all detected PCs, especially (−)-epicatechin, quercetin-3-O-rutinoside, quercetin-3-O-glucoside, cyanidine-3,5-diglucoside, cyanidine-3-O-rutinoside and pelargonidin-3-O-rutinoside (54.66, 141.08, 35.48, 494.08, 478.66, 12.56 µg/g dw, respectively). Having the darkest figs in the collection (L* = 25.72, c* = 22.09 and h° = 20.99), this cultivar has also combined promising IC50 values, which were of 19.85, 40.58 and 124.78 µg/mL for DPPH, ABTS and LPIC essays, respectively. 相似文献
60.
Invariant Manifold Approach for the Stabilization of Nonholonomic Chained Systems: Application to a Mobile Robot 总被引:1,自引:0,他引:1
In this paper it is shown that a class ofn-dimensional nonholonomic chained systems can bestabilized using the invariant manifold approach. First, we derive aninvariant manifold for this class of systems and we show that, once onit, all the closed-loop trajectories tend to the origin under a linearsmooth time-invariant state feedback. Thereafter, it is shown that thismanifold can be made attractive by means of a discontinuoustime-invariant state feedback. Finally, a mobile robot is taken as anexample demonstrating the effectiveness of our study. 相似文献