Optical limiters and diffraction elements based on a COANP-fullerene system: Nonlinear optical properties and quantum-chemical simulation

The results of optical study and quantum-chemical simulation of a conjugated organic system, 2-cyclooctylamino-5-nitropyridine (COANP)-fullerene, performed to determine its potential for application as a limiter of visible and near-IR laser radiation and as a material for diffraction elements in systems for reversible recording of optical information, are presented. Complexation between a COANP molecule and fullerene is considered as one of the main mechanisms responsible for the corresponding properties of this system. For the first time, nonlinear optical characteristics of COANP-C₆₀ and COANP-C₇₀ systems are comparatively studied and the intermolecular interaction between a COANP molecule and fullerene is analyzed on the quantum-chemical level.     

Symmetry of internal dynamics of the tetrahydrofuran molecule

A noninvariant geometrical group characterizing the internal dynamics of the tetrahydrofuran molecule C₄H₈O with allowance for the clearly pronounced pseudorotation effect is constructed. On this basis, some qualitative features of the energy spectrum of the molecule following from the analysis of high-resolution spectroscopic data are explained.     

Measurement of the K α to L α and K β to L β intensity ratios of seven elements in the atomic number range 52≤ Z ≤62 using photoionization at 59.5 keV1

The Kα to Lα and Kβ to Lβ intensity ratios of seven elements have been measured following photoionization at 59.5 keV by using a Si (Li) detector (FWHM=155 eV at 5.96 keV). The intensity ratios were determined by measuring K and L x-rays emitted from a standard target of a given element. The theoretical values of the Kα to Lα and Kβ to Lβ intensity ratios were calculated using theoretically tabulated values of shell/subshell photoionization cross sections, fluorescence yields, Coster-Kronig transition probabilities, and radiative decay rates for ηKLi≠ and ηKLi=0. The measured values are in good agreement with theoretical results. From Optika i Spektroskopiya, Vol. 97, No. 2, 2004, pp. 186–189. Original English Text Copyright ? 2004 by A. Kü?ük?nder, S?ğüt, E. Kü?ük?nder, Büyükkasap. This article was submitted by the authors in English.     

Recording dynamic holograms in a semiconductor crystal CdF<Subscript>2</Subscript>:In

The kinetics of decay of a phase hologram in a semiconductor CdF₂ crystal with bistable In centers is studied. Kinetic constants of the hologram decay are found, and the potential relief of the bistable center is plotted. The resolving power of the crystal is evaluated and recording of a transparency is demonstrated.     

Absorption of electromagnetic radiation by an inhomogeneous spherical particle

The cross section of absorption of electromagnetic radiation by an inhomogeneous spherical particle is calculated. The general case of an arbitrary value of the ratio of the particle radius to the radius of the dielectric core is considered. The condition of diffuse reflection of electrons from the inner and outer surfaces of the metal layer of the particle is taken as the boundary condition of the problem. The limiting cases are considered and the results obtained are discussed.     

Computer processing of electronic absorption spectra of rare-earth elements in inorganic laser media

Algorithms and program modules are developed for calculation of the Judd-Ofelt parameters on modern computers. These programs can be used to perform numerical analysis of the energy absorption by rareearth ions in laser media.     

Hysteresis and Eddy-current Relaxation in SiFe Materials

The rate-dependent effects in metallic ferromagnetic materials with magnetization processes attributed to domain-walls motion were studied. The experimental method for eddy-current relaxation time determination was proposed. Some discrepancies between the data and theoretical predictions were observed and discussed. The origin of these discrepancies is accounted for by the decrease of viscous-type relaxation process as the rate of change of averaged magnetization is approaching zero.     

Optical amplification of photoinduced polarizability gratings in phosphate glasses

It is experimentally demonstrated that second-order polarizability gratings preliminarily recorded using bichromatic light in a phosphate glass can be amplified under the action of monochromatic radiation. The amplification effect takes place irrespective of the polarization and direction of propagation of the amplifying radiation and is achieved at various wavelengths. The phenomenon is related to the asymmetry of optical transitions between local centers in an isotropic medium in the presence of electric field. It is theoretically shown that this system may feature the formation of alternating electric field domains with dimensions depending on the grating amplitude.