一种新型时间测量探测器──多气隙电阻板室

介绍了具有6层气隙的电阻板室的结构和工作原理.用动量7GeV/c的粒子束测量了该探测器的性能,得到时间分辨为60—70ps,探测效率大于97%.在动量为3GeV/c的正电荷粒子束流测试中,用该探测器获得了p和π的时间谱,实现了很好的粒子分辨.     

Simultaneous determination of naphazoline and pyridoxine in eye drops using excitation–emission matrix fluorescence coupled with second-order calibration method based on alternating trilinear decomposition algorithm

A novel method is developed for the direct determination of naphazoline hydrochloride(NAP) and pyridoxine hydrochloride(VB6) in commercial eye drops. By using excitation–emission matrix(EEM)fluorescence coupled with second-order calibration method based on the alternating trilinear decomposition(ATLD) algorithm, the proposed approach can achieve quantitative analysis successfully even in the presence of unknown and uncalibrated interferences. The method shows good linearity for NAP and VB6 with correlation coefficients greater than 0.99. The results were in good agreement with the labeled contents. To further confirm the feasibility and reliability of the proposed method, the same batch samples were analyzed by multiple reaction monitoring(MRM) based on LC–MS/MS method.T-test demonstrated that there are no significant differences between the prediction results of the two methods. The satisfactory results obtained in this work indicate that the use of the second-order calibration method coupled with the EEM is a promising tool for industrial quality control and pharmaceutical analysis due to its advantages of high sensitivity, low-cost and simple implementation.     

2,2-二甲基-1-[5-二茂铁基-3-(三氟甲基)-1H-吡唑-1-基]丙-1-酮的合成及其电化学性质

以乙酰基二茂铁为原料,经3步反应合成了一个新型的二茂铁衍生物——2,2-二甲基-1-[5-二茂铁基-3-(三氟甲基)-1H-吡唑-1-基]丙-1-酮(4),其结构经1H NMR,ESI-MS,元素分析和X-射线单晶衍射表征。4属单斜晶系,P2(1)/c空间群,晶胞参数a=7.805 6(4),b=20.906 1(11),c=11.124 6(6),β=93.820(2)°,V=1 811.33(17)3,Z=4,Dc=1.482 g·cm-3,μ=0.872 mm-1,R1=0.034 8,wR2=0.089 2。采用循环伏安法研究了4的电化学性质。结果表明:4有一对可逆的氧化还原峰,Epa=0.640 V,Epc=0.482 V,ΔE=153 m V。     

气相色谱-串联质谱法同时测定卷烟滤嘴中15种多环芳烃

建立了气相色谱-串联质谱同时检测卷烟滤嘴中15种多环芳烃的方法。卷烟滤嘴用二氯甲烷振荡萃取后,经0.22μm有机相滤膜过滤,采用DB-5MS色谱柱(30 m×0.25 mm,0.25μm)进行分离,电子轰击源、正离子模式下以多反应监测模式进行检测,内标法进行定量。15种多环芳烃(苊烯、苊、芴、菲、蒽、荧蒽、芘、苯并[a]蒽、屈、苯并[b]荧蒽、苯并[k]荧蒽、苯并[a]芘、二苯并[a,h]蒽、苯并[g,h,i]苝和茚并[1,2,3-c,d]芘)的线性关系良好,相关系数(R~2)为0.991 4~0.999 9。15种多环芳烃在低、中、高3个添加水平下的平均回收率为81.6%~111.2%;除了芴在低添加水平时相对标准偏差为19.2%外,其他相对标准偏差均小于16%。15种多环芳烃的检出限为0.02~0.24 ng/滤嘴,定量限为0.04~0.80 ng/滤嘴。方法前处理简便,具有快速、准确、灵敏度高及重复性好的优点,适用于卷烟滤嘴中多环芳烃的分析。     

过模介质O-波导的传播特性

本文详细分析了过模介质O-波导的全部模式,提出一种简单准确的模式分类法,导出了各本征模分离的特征方程,避免了直接求解复杂的特征方程。讨论了按场分布划分的三类正规模:表面模、界面模和泄漏模以及它们的传播特性,给出了相应的近似解。几个极限结果与文献十分吻合。研究表明,适当选择过模介质O-波导的材料参数和波导尺寸,它的传播特性很容易控制。     

核ANC和激发态中子晕

利用转移反应¹¹B(d,p)¹²B和¹²C(d,p)¹³C抽取¹²B<—>¹¹B+n和¹³C<—>¹²C+n重叠函数的核渐近归一化常数,计算了¹²B和¹³C核中价中子密度分布的均方根半径及其在核外的几率.实验结果表明,¹²B的第二(J^π=2^－),第三(J^π=1^－)激发态和13C的第一(J^π=1/2⁺)激发态为中子晕态,而¹³C的第三(J^π=5/2⁺)激发态是中子皮态.考察了库仑势和角动量对晕形成的阻碍效应.提出了均方根半径对于有效核子分离能的统一的标度定律.     

量子阱中的束缚极化子的路径积分变分研究

利用Feynman路径积分变分方法，推导了整个电声子耦合区域的量子阱中束缚极化子的基态能。对其数值结果研究表明：当量子阱的约束势达到一定值，极化子的基态能修正－△E随电声子耦合常数α的增加激剧增大，约束势导致有效电声子耦合从无约束势时的弱耦合向居间耦合或强耦合渡越。更重要的是，我们发现存在一个量子阱的临界有效宽度lz0,当lZ小于临界值时，－△E随lz变小很快增大；当lz大于临界值时，随lz变大，－△E几乎不变。     

Nd2-xSrxCoO4 (x=1.25,1.33,1.60)体系的物理性质研究

用固相反应法制备了Nd2-xSrxCoO4 ( x = 1.25, 1.33, 1.60) 多晶.X射线衍射结果表明样品没有杂项,且都是四方层状K2NiF4结构[1].电阻率结果表明这组样品在测量温区都是半导体行为.对于x= 1.25和1.33的样品,热电势为正值;而对于x= 1.60的样品,热电势在60K发生了由正到负的转变.所有样品在80K左右零场冷却磁化率有个缓变的最大值,在180K左右场冷和零场冷磁化率发生劈裂,表明在低温下样品存在类自旋玻璃态.我们同时测量了x = 1.25样品在110 K到300 K温区的电子自旋共振谱,发现在居里温度左右存在顺磁相和铁磁相激烈竞争,强烈的轨道-自旋耦合导致了短自旋-晶格驰豫时间使谱线宽化.     

Mixed Symmetry Isomeric States in Nuclei

Mixed symmetry states are studied in the framework of the neutron-proton interacting boson model.It is found that some of the mixed symmetry states with moderate high spins change very fast with respect to the Majorana interaction.Under certain conditions,they become the yrast state or yrare state.These states are difficult to decay and become very stable.This study suggests that a possible new mode of isomers may exist due to the special nature in their proton and neutron degrees of freedom.