全文获取类型
收费全文 | 501篇 |
免费 | 6篇 |
国内免费 | 7篇 |
专业分类
化学 | 208篇 |
晶体学 | 2篇 |
力学 | 20篇 |
数学 | 100篇 |
物理学 | 184篇 |
出版年
2019年 | 4篇 |
2015年 | 7篇 |
2014年 | 4篇 |
2013年 | 21篇 |
2012年 | 12篇 |
2011年 | 21篇 |
2010年 | 9篇 |
2009年 | 5篇 |
2008年 | 23篇 |
2007年 | 22篇 |
2006年 | 35篇 |
2005年 | 15篇 |
2004年 | 13篇 |
2003年 | 8篇 |
2002年 | 10篇 |
2001年 | 12篇 |
2000年 | 4篇 |
1999年 | 11篇 |
1998年 | 5篇 |
1997年 | 9篇 |
1996年 | 12篇 |
1995年 | 11篇 |
1994年 | 8篇 |
1993年 | 5篇 |
1992年 | 9篇 |
1991年 | 12篇 |
1990年 | 12篇 |
1989年 | 5篇 |
1988年 | 10篇 |
1987年 | 8篇 |
1986年 | 7篇 |
1985年 | 10篇 |
1981年 | 6篇 |
1980年 | 6篇 |
1978年 | 8篇 |
1977年 | 7篇 |
1976年 | 5篇 |
1975年 | 7篇 |
1974年 | 11篇 |
1973年 | 7篇 |
1972年 | 5篇 |
1970年 | 4篇 |
1967年 | 8篇 |
1934年 | 4篇 |
1932年 | 5篇 |
1927年 | 4篇 |
1926年 | 3篇 |
1915年 | 3篇 |
1914年 | 3篇 |
1905年 | 5篇 |
排序方式: 共有514条查询结果,搜索用时 15 毫秒
81.
Quality assurance and process understanding are assuming increasing importance in the production of Active Pharmaceutical Ingredients (APIs). NMR has the potential to report on physical processes, quantities, structures, and speciation as chemical reactions progress. Following the progression of chemical reactions by placing the sample in an NMR tube, one can perform a large number of useful studies that provide chemical and mechanistic insight. But this simple approach can have limitations, and we have therefore constructed an apparatus comprising a laboratory reactor coupled with an NMR flow cell. The reactor duplicates the exact reaction conditions that will apply with large-scale production. This reaction mixture is sampled and pumped to a high-resolution NMR flow cell where the spectrum is recorded through the course of the reaction. We demonstrate the utility of reaction monitoring using NMR both for simple cases where tubes can be used, and describe the design of the on-flow apparatus and highlight its utility with an example. 相似文献
82.
Thermodynamics of reactions of vanadium oxide clusters with SO2 are studied at the BPW91/LANL2DZ level of theory. BPW91/LANL2DZ is insufficient to properly describe relative V-O and S-O bond strengths of vanadium and sulfur oxides. Calibration of theoretical results with experimental data is necessary to compute reliable enthalpy changes for reactions between VxOy and SO2. Theoretical results indicate SO2 to SO conversion occurs for oxygen-deficient clusters and SO2 to SO3 conversion occurs for oxygen-rich clusters. Stable intermediate structures of VOy (y = 1 - 4) clusters with SO2 are also obtained at the BPW91/TZVP level of theory. Some possible mechanisms for SO3 formation and catalyst regeneration for condensed-phase systems are suggested. These results are in agreement with, and complement, gas-phase experimental studies of neutral vanadium oxide clusters. 相似文献
83.
The single crystal X-ray structure of the acetic acid solvate of trimesic acid shows the complete disruption of the hydrogen-bonded hexagonal networks of TMA by bonding to an acetic acid molecule. 相似文献
84.
Wang ZA Liu X Byrne RH Wanninkhof R Bernstein RE Kaltenbacher EA Patten J 《Analytica chimica acta》2007,596(1):23-36
An autonomous multi-parameter flow-through CO2 system has been developed to simultaneously measure surface seawater pH, carbon dioxide fugacity (fCO2), and total dissolved inorganic carbon (DIC). All three measurements are based on spectrophotometric determinations of solution pH at multiple wavelengths using sulfonephthalein indicators. The pH optical cell is machined from a PEEK polymer rod bearing a bore-hole with an optical pathlength of ∼15 cm. The fCO2 optical cell consists of Teflon AF 2400 (DuPont) capillary tubing sealed within the bore-hole of a PEEK rod. This Teflon AF tubing is filled with a standard indicator solution with a fixed total alkalinity, and forms a liquid core waveguide (LCW). The LCW functions as both a long pathlength (∼15 cm) optical cell and a membrane that equilibrates the internal standard solution with external seawater. fCO2 is then determined by measuring the pH of the internal solution. DIC is measured by determining the pH of standard internal solutions in equilibrium with seawater that has been acidified to convert all forms of DIC to CO2. The system runs repetitive measurement cycles with a sampling frequency of ∼7 samples (21 measurements) per hour. The system was used for underway measurements of sea surface pH, fCO2, and DIC during the CLIVAR/CO2 A16S cruise in the South Atlantic Ocean in 2005. The field precisions were evaluated to be 0.0008 units for pH, 0.9 μatm for fCO2, and 2.4 μmol kg−1 for DIC. These field precisions are close to those obtained in the laboratory. Direct comparison of our measurements and measurements obtained using established standard methods revealed that the system achieved field agreements of 0.0012 ± 0.0042 units for pH, 1.0 ± 2.5 μatm for fCO2, and 2.2 ± 6.0 μmol kg−1 for DIC. This system integrates spectrophotometric measurements of multiple CO2 parameters into a single package suitable for observations of both seawater and freshwater. 相似文献
85.
Daniel J. Bernstein Hendrik W. Lenstra Jr. Jonathan Pila. 《Mathematics of Computation》2007,76(257):385-388
This paper presents an algorithm that, given an integer , finds the largest integer such that is a th power. A previous algorithm by the first author took time where ; more precisely, time ; conjecturally, time . The new algorithm takes time . It relies on relatively complicated subroutines--specifically, on the first author's fast algorithm to factor integers into coprimes--but it allows a proof of the bound without much background; the previous proof of relied on transcendental number theory.
The computation of is the first step, and occasionally the bottleneck, in many number-theoretic algorithms: the Agrawal-Kayal-Saxena primality test, for example, and the number-field sieve for integer factorization.
86.
Daniel J. Bernstein. 《Mathematics of Computation》2007,76(257):389-403
This paper presents an algorithm that, given a prime , finds and verifies a proof of the primality of in random time . Several practical speedups are incorporated into the algorithm and discussed in detail.
87.
88.
A tabletop soft x-ray laser is applied for the first time as a high energy photon source for chemical dynamics experiments in the study of water, methanol, and ammonia clusters through time of flight mass spectroscopy. The 26.5 eV/photon laser (pulse time duration of approximately 1 ns) is employed as a single photon ionization source for the detection of these clusters. Only a small fraction of the photon energy is deposited in the cluster for metastable dissociation of cluster ions, and most of it is removed by the ejected electron. Protonated water, methanol, and ammonia clusters dominate the cluster mass spectra. Unprotonated ammonia clusters are observed in the protonated cluster ion size range 2< or =n< or =22. The unimolecular dissociation rate constants for reactions involving loss of one neutral molecule are calculated to be (0.6-2.7)x10(4), (3.6-6.0)x10(3), and (0.8-2.0)x10(4) s(-1) for the protonated water (9< or =n< or =24), methanol (5< or =n< or =10), and ammonia (5< or =n< or =18) clusters, respectively. The temperatures of the neutral clusters are estimated to be between 40 and 200 K for water clusters (10< or =n< or =21), and 50-100 K for methanol clusters (6< or =n< or =10). Products with losses of up to five H atoms are observed in the mass spectrum of the neutral ammonia dimer. Large ammonia clusters (NH(3))(n) (n>3) do not lose more than three H atoms in the photoionization/photodissociation process. For all three cluster systems studied, single photon ionization with a 26.5 eV photon yields near threshold ionization. The temperature of these three cluster systems increases with increasing cluster size over the above-indicated ranges. 相似文献
89.
Dong F Heinbuch S He SG Xie Y Rocca JJ Bernstein ER 《The Journal of chemical physics》2006,125(16):164318
Neutral vanadium, niobium, and tantalum oxide clusters are studied by single photon ionization employing a 26.5 eV/photon soft x-ray laser. During the ionization process the metal oxide clusters are almost free of fragmentation. The most stable neutral clusters of vanadium, niobium, and tantalum oxides are of the general form (MO2)0,1(M2O5)y. M2O5 is identified as a basic building unit for these three neutral metal oxide species. Each cluster family (Mm, m=1,...,9) displays at least one oxygen deficient and/or oxygen rich cluster stoichiometry in addition to the above most stable species. For tantalum and niobium families with even m, oxygen deficient clusters have the general formula (MO2)2(M2O5)y. For vanadium oxide clusters, oxygen deficient clusters are detected for all cluster families Vm (m=1,[ellipsis (horizontal)],9), with stable structures (VO2)x(V2O5)y. Oxygen rich metal oxide clusters with high ionization energies (IE>10.5 eV, 118 nm photon) are detected with general formulas expressed as (MO2)2 (M2O5)y O1,2,3. Oxygen rich clusters, in general, have up to three attached hydrogen atoms, such as VO3H1,2, V2O5H1,2, Nb2O5H1,2, etc. 相似文献
90.
Sarveswaran K Hu W Huber PW Bernstein GH Lieberman M 《Langmuir : the ACS journal of surfaces and colloids》2006,22(26):11279-11283
We demonstrate a guided self-assembly approach to the fabrication of DNA nanostructures on silicon substrates. DNA oligonucleotides self-assemble into "rafts" 8 x 37 x 2 nm in size. The rafts bind to cationic SAMs on silicon wafers. Electron-beam lithography of a thin poly(methyl methacrylate) (PMMA) resist layer was used to define trenches, and (3-aminopropyl)triethoxysilane (APTES), a cationic SAM precursor, was deposited from aqueous solution onto the exposed silicon dioxide at the trench bottoms. The remaining PMMA can be cleanly stripped off with dichloromethane, leaving APTES layers 0.7-1.2 nm in thickness and 110 nm in width. DNA rafts bind selectively to the resulting APTES stripes. The coverage of DNA rafts on adjacent areas of silicon dioxide is 20 times lower than on the APTES stripes. The topographic features of the rafts, measured by AFM, are identical to those of rafts deposited on wide-area SAMs. Binding to the APTES stripes appears to be very strong as indicated by "jamming" of the rafts at a saturation coverage of 42% and the stability to repeated AFM scanning in air. 相似文献