Ce3+-冠醚配合物的紫外有机电致发光

采用5d-4f跃迁的稀土Ce³⁺-冠醚配合物(Ce-二环己基并-18-冠-6,Ce-DC18C6)作为发光掺杂剂,4,4'-二(9-咔唑基)联苯(CBP)为基质,设计制备了紫外发光器件:ITO/CuPc/Ce-DC18C6:CBP/Bu-PBD/LiF/Al,首次观测到峰位于376nm的Ce³⁺离子的紫外电致发光。通过对比器件的EL谱与Ce³⁺-冠醚配合物薄膜的PL谱发现,EL光谱中有部分来自Ce³⁺配合物中的Ce³⁺离子的。这种5d-4f电子跃迁的掺杂质量分数为3%时,该UV-发光器件的最大辐射功率为13μW/cm²。     

部分相干光束通过硬边光阑的推广光束传输M2因子

给出部分相干光通过硬边光阑后的强度二阶矩的计算公式，由此可得到部分相干光通过硬边光阑后的推广光束传输M^2因子。以部分相干高斯－谢尔模型光束为例，推导出相应的M^2因子，并作了数值计算和分析讨论。     

新疆红景天红色素的提取及理化性质的研究

对用索氏提取法和乙醇浸取法提取红景天红色素进行了比较，并探讨浸取的浓度，浸取温度等因素，指出了最佳生产工艺条件，从红景天中提取的天红色素是一种安全无毒的食用色素，本文还研究了几种食品添加剂对红景天红色素稳定性的影响，并对色素的耐氧化性进行了探讨，旨在为红景天红色素的开发利用提供有实用价值的信息。     

Schrodinger 方程的广义 Dirichlet 问题

在本文中,{B(t),t≥0}是 d(d≥1)维标准 Brown 运动,\mathcal{F}_t=σ{B(s),s≤t},P_x 是自 x 出发的 Brown 运动所产生的 Wiener 测度,E_x 表示关于 P_x 的积分.D 是R~d 中的一个区域,对 D 上的有界函数 c,令...     

气体放电等离子体特性测量I-V曲线不对称性的研究

利用气体放电双探针法研究了等离子体的I-V曲线中的电流I相对于电压V轴交点的不对称性,并提出2种可能的解释:一认为是由于两探针表面积不同引起的;二认为是由于探针所在处等离子体电位不等引起的.本文利用仪器的工艺误差和调换放电管电压的方法,对提出的2种可能原因分别进行验证,并指出第二种解释的合理性,并对其进行了理论分析.     

稀土氟化物Y0.97Er0.03F3纳米材料的制备及上转换发光

通过燃烧法和控温热反应法制备了稀土氟化物纳米材料，利用XRD和TEM对样品进行了分析和表征。测量了发射波长为980nm激光二极管激发下所得纳米材料的上转换发光性质。     

Solutions in Sobolev spaces of vector refinement equations with a general dilation matrix

In this paper, we present a necessary and sufficient condition for the existence of solutions in a Sobolev space W_p^k(ℝ^s) (1≤p≤∞) to a vector refinement equation with a general dilation matrix. The criterion is constructive and can be implemented. Rate of convergence of vector cascade algorithms in a Sobolev space W_p^k(ℝ^s) will be investigated. When the dilation matrix is isotropic, a characterization will be given for the L_p (1≤p≤∞) critical smoothness exponent of a refinable function vector without the assumption of stability on the refinable function vector. As a consequence, we show that if a compactly supported function vector φ∈L_p(ℝ^s) (φ∈C(ℝ^s) when p=∞) satisfies a refinement equation with a finitely supported matrix mask, then all the components of φ must belong to a Lipschitz space Lip(ν,L_p(ℝ^s)) for some ν>0. This paper generalizes the results in R.Q. Jia, K.S. Lau and D.X. Zhou (J. Fourier Anal. Appl. 7 (2001) 143–167) in the univariate setting to the multivariate setting. Dedicated to Professor Charles A. Micchelli on the occasion of his 60th birthday Mathematics subject classifications (2000) 42C20, 41A25, 39B12. Research was supported in part by the Natural Sciences and Engineering Research Council of Canada (NSERC Canada) under Grant G121210654.     

用峰面积判据改善Delsuc法预测的谱

基于Prony算法的Delsuc谱预测是目前NMR LPSVD(Linear Prediction SingularValue Decomposition)法中比较实用的方法。但在高噪声的条件下,时有失峰和假峰出现且要事先知道谱的峰数。本文通过跟踪迭代过程发现Delsuc法的判别因子r_(mis) 很难选定。如果它太小会失峰,而过大又会出现假峰。同时,由于噪声的影响,弱信号的采样点之间的相关性比强信号小,从而在迭代过程中会增加数值不稳定性。文中引入峰面积判据来改善Delsuc法,经模拟与实验均证明结果有效。     

An Economical Magnetocardiogram System Based on High-To SQUIDs

An economical magnetocardiogram （MCG） system is built in our laboratory. It mainly consists of a MCG data acquisition stage equipped with two high-To superconducting quantum interference device （SQUID） magnetometers, a data processing stage with digital filtering and a one-layer μ-metal magnetically shielded room in conjunction with a high-Tc SQUID based active compensation. Experimental results show that a noise level of pico-tesla in MCG profiles, which is necessary for clinical applications, may be achieved with the system. Moreover, stable and convenient operations of the system are demonstrated with simulating MCG measurements.     

Photodecomposition of several compounds commonly used as sunscreen agents

The photolysis reactions of three compounds commonly used as a sunscreen agents, Parsol 1789 (1-[4-(1,1-dimethylethyl)phenyl]-3-(4-methoxyphenyl)-1,3- propanedione), Oxybenzone ((2-hydroxy-4-methoxyphenyl)phenyl-methanone) and Padimate O (2-ethylhexyl-4-(dimethylamino)benzoate), were investigated to provide a chemical background to aid in the understanding of the photosensitization of the sunscreen agents. Photolysis was carried out in cyclohexane for 70–140 h using a mercury vapor lamp (450W) without excluding oxygen.

Irradation of Parsol 1789 in cyclohexane yielded tert-butylbenzene, p-tert-butylbenzoic acid and p-methoxybenzoic acid; products obtained from the combination of the sunscreen with the solvent included the cyclohexyl esters of p-methoxybenzoic acid, p-tert-butylbenzoic acid and methanoic acid; products obtained from the solvent included cyclohexanol, cyclohexanone and dicyclohexyl ether.

Irradiation of Oxybenzone in the cyclohexane for 100 h produced no detectable products by either gas or liquid chromatographic analysis. Oxybenzone was recovered unchanged and no products were observed from the photoinitiated reaction of oxygen with the solvent.

Irradiation of Padimate O in cyclohexane yielded the ethylhexyl esters of p-aminobenzoic acid, p-monomethylaminobenzoic acid and p-dimethylamino (o/m)-methylbenzoic acid, as well as products from the photoinitiated reaction of oxygen with the solvent.