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101.
Pinkerton RG Barberi EA Menon RS 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2004,171(1):151-156
The use of multiple radiofrequency (RF) surface coil elements has applications in both fast parallel imaging and conventional imaging techniques. Through implementation of a simple magnetic decoupling network, 50 Omega matching can be achieved in both the transmitter and receiver chains, enabling the use of conventional RF power amplifiers and preamplifiers for transceive applications. Unlike phased array coil arrangements using low impedance preamplifiers for decoupling, the noise correlation between 50 Omega coils decoupled with discrete components has not been characterized. We have measured the dependence of coil quality factor (Q-factor) and noise correlation on coil separation and shown these quantities to be consistent with theoretical arguments, at least at 4 T (170 MHz). Our results suggest that a coil system for transmission and reception of NMR signals with 50 Omega coils can be built to take advantage of all the benefits of conventional array coils and with the added advantages of using conventional amplifiers. 相似文献
102.
Relative importance of hydrogen bonding and coordinating groups in modulating the zinc-water acidity
Mareque-Rivas JC Prabaharan R de Rosales RT 《Chemical communications (Cambridge, England)》2004,(1):76-77
The presence of second-sphere -NH(2) groups in the proximity of a zinc(ii)-bound water molecule enhances its acidity by ca. 2 pK(a) units. 相似文献
103.
We consider the following system of discrete equations
. Criteria for the existence of three constant-sign solutions of the system will be developed. To illustrate the generality of the results obtained, we include applications to several well-known boundary value problems. Parallel results are also established for a system on {0,1,...}
. 相似文献
104.
Karajanagi SS Vertegel AA Kane RS Dordick JS 《Langmuir : the ACS journal of surfaces and colloids》2004,20(26):11594-11599
We have examined the structure and function of two enzymes, alpha-chymotrypsin (CT) and soybean peroxidase (SBP), adsorbed onto single-walled carbon nanotubes (SWNTs). SBP retained up to 30% of its native activity upon adsorption, while the adsorbed CT retained only 1% of its native activity. Analysis of the secondary structure of the proteins via FT-IR spectroscopy revealed that both enzymes undergo structural changes upon adsorption, with substantial secondary structural perturbation observed for CT. Consistent with these results, AFM images of the adsorbed enzymes indicated that SBP retains its native three-dimensional shape while CT appears to unfold on the SWNT surface. This study represents the first in depth investigation of protein structure and function on carbon nanotubes, which is critical in designing optimal carbon nanotube-protein conjugates. 相似文献
105.
The Integrating Sphere Integrating Nephelometer is a novel and unique reciprocal nephelometer that uses an integrating sphere with attached truncation-reduction tubes to contain the sample volume and to integrate the scattered light. Its main advantage compared with current integrating nephelometers is a sevenfold reduction in truncation angle, which reduces errors in measured scattering from large particles. Additional features include improved sampling efficiency for large particles and a well-defined operating wavelength. 相似文献
106.
Ravi P. Agarwal Said R. Grace Donal O'Regan 《Proceedings of the American Mathematical Society》2003,131(1):129-140
This paper introduces a nonoscillatory theory for differential inclusions based on fixed point theory for multivalued maps.
107.
Twin solutions to singular boundary value problems 总被引:5,自引:0,他引:5
Ravi P. Agarwal Donal O'Regan 《Proceedings of the American Mathematical Society》2000,128(7):2085-2094
In this paper we establish the existence of two nonnegative solutions to singular and singular focal boundary value problems. Our nonlinearity may be singular at , and/or .
108.
The effect of tetravalent Ti+4 substitution in Mg0.95Mn0.05Fe2O4 on its magnetic and electrical properties has been studied using X-ray diffraction, Mössbauer spectroscopy, isothermal dc magnetization and dielectric measurements. X-ray diffraction studies have shown the structural transformation from cubic to tetragonal with the Ti+4 substitution. The Mössbauer spectra of Mg0.95Mn0.05Fe1.0Ti1.0O4 recorded in the temperature range 20-300 K shows the presence of the magnetic as well as quadrupole interactions. The isothermal hysteresis loop infers that the system exhibits a ferrimagnetic ordering at room temperature. The Zero-field-cooled (ZFC) and field-cooled (FC) magnetization studies support ferrimagnetic ordering of Mg0.95Mn0.05Fe1.0Ti1.0O4 at room temperature. Signatures of ferroelectric transition have been observed in the temperature range 200-300 K from dielectric measurements. The observed magnetic and dielectric behaviour indicate that this material exhibits multiferroic behaviour. 相似文献
109.
Ravi Aggarwal Durairaj Baskaran 《Journal of polymer science. Part A, Polymer chemistry》2011,49(23):5049-5056
Hydrated sodium montmorillonite (Na‐clay) has been used as a catalyst support for the heterogeneous atom transfer radical polymerization of benzyl methacrylate in the presence of various concentrations of water, reducing agent, and CuBr2 in anisole at ambient temperature. The polymerization was promoted via reduction of CuII to CuI through the addition of sodium ascorbate (NaAsc) as a reducing agent in aqueous solution. The polymerizaton proceeded in a controlled manner and produced poly(benzyl methacylate) with moderately narrow molecular weight distribution (MWD) when performed under optimum conditions of hydration (10 wt % ≤ H2O/Na‐clay ≤ 21 wt %) and reducing agent (0.15 ≤ [NaAsc]/[I] ≤ 0.23). The polymerization was uncontrolled if hydration and NaAsc exceed above their optimum range of concentrations. Apparent rate of the polymerization (kapp) increased in the presence of decane–anisole (1/3, v/v) mixture solvent. Selective adsorption of decane at the interfaces of the hydrated clay was attributed for the rate enhancement due to increased polymer and hydrophobic interface interaction. The polymerization progressed in a controlled manner as confirmed by the first‐order time‐conversion plot, linear increase in molecular weights, and moderately narrow MWDs over conversion. © 2011 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2011 相似文献