首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   1450773篇
  免费   29928篇
  国内免费   7791篇
化学   741095篇
晶体学   20629篇
力学   77071篇
综合类   108篇
数学   250200篇
物理学   399389篇
  2021年   13580篇
  2020年   16057篇
  2019年   16213篇
  2018年   15731篇
  2017年   14081篇
  2016年   29470篇
  2015年   21272篇
  2014年   30766篇
  2013年   74936篇
  2012年   44347篇
  2011年   46108篇
  2010年   40791篇
  2009年   42069篇
  2008年   43465篇
  2007年   40430篇
  2006年   43105篇
  2005年   36896篇
  2004年   36427篇
  2003年   33390篇
  2002年   33508篇
  2001年   34286篇
  2000年   28455篇
  1999年   24265篇
  1998年   21708篇
  1997年   21554篇
  1996年   21486篇
  1995年   19475篇
  1994年   18953篇
  1993年   18570篇
  1992年   19212篇
  1991年   19368篇
  1990年   18558篇
  1989年   18581篇
  1988年   18177篇
  1987年   18023篇
  1986年   17023篇
  1985年   23365篇
  1984年   24320篇
  1983年   20356篇
  1982年   21935篇
  1981年   21124篇
  1980年   20480篇
  1979年   20964篇
  1978年   22046篇
  1977年   21717篇
  1976年   21551篇
  1975年   20276篇
  1974年   19982篇
  1973年   20414篇
  1972年   14662篇
排序方式: 共有10000条查询结果,搜索用时 62 毫秒
871.
Methods for phase stabilization of ammonium nitrate were sought for in order to considerably expand the application area of this oxidizing agent in various-purpose self-combustible formulations, including that in a new generation of gas-generating formulations for automobile air bags. New methods for stabilization of ammonium nitrate were studied and, in particular, a search was made for organic compounds that can stabilize ammonium nitrate even at their low content. The mechanism of phase state stabilization of ammonium nitrate by compounds of this kind was examined.  相似文献   
872.
873.
In this work, the variation of the magnetic moments of the Ni/Pt multilayers are studied using the linearized augmented plane waves (LAPW) method in the framework of the density functional theory (DFT) implemented in the version of WIEN2K program. The systems have been modeled by seven layers slab separated in z direction by a vacuum region of four substrate layers. We present the results of the dependence of the magnetic properties with respect to the thickness variation of the different multilayers. The modeling of these systems finds an important empirical support. Experiment and theory show the same trends for the magnetic moments: hybridization effects between Ni and Pt are mostly localized at the interface.  相似文献   
874.
Results from 5D induced-matter and membrane theory with null paths are extended to show that a particle obeys the 4D Klein-Gordon equation but with a variable mass. The Dirac equation also follows, but raises concerns about 4D quantization in the two natural 5D gauges, and reopens the question of a Regge-like trajectory for the spin angular momenta and squared masses of gravitationally-dominated systems.  相似文献   
875.
In this work the results of the statistical topometric analysis of fracture surfaces of soda-lime-silica glass with and without ionic exchange treatment are reported. In this case, the mechanism of substitution is K+-Na+. atomic force microscopy (AFM) was employed to record the topometric data from the fracture surface. The roughness exponent (ζ) and the correlation length (ξ) were calculated by the variable bandwidth method. The analysis for both glasses (subjected and non-subjected to ionic exchange) for ζ shows a value ∼0.8, this value agrees well with that reported in the literature for rapid crack propagation in a variety of materials. The correlation length shows different values for each condition. These results, along with those of microhardness indentations suggest that the self-affine correlation length is influenced by the complex interactions of the stress field of microcracks with that resulting from the collective behavior of the point defects introduced by the strengthening mechanism of ionic exchange.  相似文献   
876.
Holographic sensors for monitoring ionic strength have been fabricated from charged sulphonate and quaternary ammonium monomers, incorporated into thin, polymeric hydrogel films which were transformed into volume holograms. The diffraction wavelength or reflected colour of the holograms was used to characterise their swelling or de-swelling behaviour as a function of ionic strength in various media. The effects of co-monomer structure, buffer composition, ion composition, pH and temperature were evaluated, whilst the reversibility and reproducibility of the sensor was also assessed. An acrylamide-based hologram containing equal molar amounts of negatively and positively charged monomers was shown to be able to quantify ionic strength independent of the identity of the ionic species present in the test solution. The sensor was fully reversible, free of hysteresis and exhibited little response to pH between 3 and 9 and temperature within the range 20-45 °C. The system was successfully used to quantify the ionic strength of milk solutions, which contain a complex mixture of ions and biological components.  相似文献   
877.
Using the simplest (sinusoidal) corrugation profile in the approximation of absence of losses in the material as an example, we study the regimes of complete transformation of an incident wave to the diffraction lobe by a corrugated metal surface or a corrugated interface of two dielectric media. A numerical-intuitive pattern of appearance and evolution of such regimes with increasing corrugation amplitude is revealed. It is shown that the regimes of complete transformation of an incident wave to the diffraction lobe are possible in both the case of autocollimation and the case of a considerable deviation from it. The examination is based on a numerical method of solving the integral equation by means of a specially created interactive processing system in Visual Fortran.  相似文献   
878.
879.
The possibility of realizing SASE Free Election Laser in x-ray waveband with EM-wave wiggler is studied in this paper. SASE effect including saturation length, saturation power and nonlinear process is explored through a 3-D simulation code. A utilization of seed light from laser plasma x-ray is also analyzed, which demonstrates the feature of shortening the interaction length for saturation. The results show that sizeable output power of x-ray laser would be generated with a middle energy electron beam.  相似文献   
880.
    
The reaction of [{(η5-C5Me5)M(μ-Cl)Cl}2] {where M = Rh (1), Ir (2)} with functionalized phosphine viz., diphenyl-2-pyridylphosphine (PPh2Py) in dichloromethane solvent yield neutral ϰ1-P-coordinated rhodium and iridium complexes [(η5-C5Me5)RhCl21-P-PPh2Py)]3 and [(η5-C5Me5) IrCl21-P-PPh2Py)]4. Reaction of complexes 1 and 2 with the ligand PPh2Py in methanol under reflux give bis-substituted complexes such as [(η5-C5Me5)RhCl(ϰ1-P-PPh2Py)2]+ 5 and [(η5-C5Me5)IrCl(ϰ1-P-PPh2Py)2]+ 6, whereas stirring in methanol at room temperature gives P-, N-chelating complexes of the type [(η5-C5Me5)RhCl(ϰ2-P-N-PPh2Py)]+ 7 and [(η5-C5Me5)IrCl(ϰ2-P-N-PPh2Py)]+ 8. Neutral ϰ1-P-coordinated complexes [(η5-C5Me5)RhCl21-P-PPh2Py)]3 and [(η5-C5Me5)IrCl21-P-PPh2Py)]4 easily undergo conversion to the cationic P-, N-chelating complexes [(η5-C5Me5)RhCl(ϰ2-P-N-PPh2Py)]+ 7 and [(η5-C5Me5) IrCl(ϰ2-P, N-PPh2Py)]+ 8 on stirring in methanol at room temperature. These complexes are characterized by FT-IR and FT-NMR spectroscopy as well as analytical methods. The molecular structures of the representative complexes [(η5-C5Me5)RhCl21-P-PPh2Py)]3, [(η5-C5Me5)IrCl21-P-PPh2Py)]4 and hexafluorophosphate salt of complex [(η5-C5Me5)IrCl(ϰ2-P-PPh2Py)2]+ 6 are established by single-crystal X-ray diffraction methods  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号