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941.
Thomas M. F. Case G. S. Bland J. Herring A. D. F. Stirling W. G. Tixier S. Boni P. Ward R. C. C. Wells M. R. Langridge S. 《Hyperfine Interactions》2002,141(1-4):471-476
Hyperfine Interactions - Multilayers of Ce/Fe and U/Fe were fabricated by sputtering and studied by X-ray diffraction and reflectivity, Mössbauer spectroscopy and polarised neutron... 相似文献
942.
943.
Ricardo L. Mancera Michalis Chalaris Jannis Samios 《Journal of Molecular Liquids》2004,110(1-3):147-153
We have carried out a molecular dynamics study of dimethyl sulfoxide (DMSO) in water at 298 K at two different densities by simulating two different concentrations: 0.055 and 0.19 mole fraction. We have found an enhancement in the structure of water, an effect that becomes more pronounced as the concentration of DMSO increases. At both concentrations there is a well-defined hydration structure around the oxygen atom of DMSO, which is able to establish strong hydrogen bonds with surrounding water molecules. An increase in the concentration of DMSO depletes the solution of bulk water molecules, reducing the number of hydrogen bonds that water can have in the immediate vicinity of DMSO but increasing the strength of the hydrogen bonds made between the oxygen atom of DMSO and water. There is clear evidence of ‘hydrophobic’ hydration around the methyl groups of DMSO, which is enhanced as the concentration of DMSO increases. 相似文献
944.
Benzildithiosemicarbazone (BDTSC) is proposed as a sensitive and selective analytical reagent for the extractive spectrophotometric determination of copper(II). BDTSC reacts with copper(II) in the pH range 1.0-7.0 to form a yellowish complex. Beer's law is obeyed in the concentration range 0.5-0.4 microg cm(-3). The yellowish Cu(II)-BDTSC complex in chloroform shows a maximum absorbance at 380 nm, with molar absorptivity and Sandell's sensitivity values of 1.63 x 10(4) dm3 mol(-1) cm(-1) and 0.00389 microg cm(-2), respectively. A repetition of the method is checked by finding the relative standard deviation (RSD) (n = 10), which is 0.6%. The composition of the Cu(II)-BDTSC complex is established as 1:1 by slope analysis, molar ratio and Asmus' methods. An excellent linearity with a correlation coefficient value of 0.98 is obtained for the Cu(II)-BDTSC complex. The instability constant of the complex calculated from Edmond and Birnbaum's method is 7.70 x 10(-4) and that of Asmus' method is 7.66 x 10(-4), at room temperature. The method is successfully employed for the determination copper(II) in pharmaceutical and environmental samples. The reliability of the method is assured by analyzing the standard alloys (BCS 5g, 10g, 19e, 78, 32a, 207 and 179) and by inter-comparison of experimental values, using an atomic absorption spectrometer. 相似文献
945.
We show that the complex projection of a completely positive quaternionic map of quaternionic density matrices is a positive
map in the space of complex density matrices, and we briefly outline some of its properties. To illustrate this result, we
study the complex projection of a one-parameter quaternionic unitary dynamics of a spin-1/2 quantum system.
__________
Translated from Teoreticheskaya i Matematicheskaya Fizika, Vol. 151, No. 3, pp. 360–370, June, 2007. 相似文献
946.
F. Klappenberger K. N. Alekseev K. F. Renk R. Scheuerer E. Schomburg S. J. Allen G. R. Ramian J. S. S. Scott A. Kovsh V. Ustinov A. Zhukov 《The European Physical Journal B - Condensed Matter and Complex Systems》2004,39(4):483-489
We report an experimental study indicating ultrafast creation and annihilation of space-charge domains in a semiconductor superlattice under the action of a THz field. Our experiment was performed for an InGaAs/InAlAs superlattice with the conduction electrons undergoing miniband transport. We applied to a superlattice a dc bias that was slightly smaller than a critical bias necessary for the formation of space-charge domains caused by a static negative differential conductivity. Additionally subjecting the superlattice to a strong THz field, resulted in a dc transport governed by the formation of domains if the frequency of the field was smaller than an upper frequency limit (~3 THz). From this frequency limit for the creation and annihilation of domains we determined the characteristic time of the domain buildup. Our analysis shows that the buildup time of domains in a wide miniband and heavily doped superlattice is limited by the relaxation time due to scattering of the miniband electrons at polar optic phonons. Our results are of importance for both an understanding of ultrafast dynamics of pattern formation in nanostructures and the development of THz electronic devices.Received: 25 March 2004, Published online: 23 July 2004PACS:
72.20.Ht High-field and nonlinear effects - 72.30. + q High-frequency effects; plasma effects - 73.21.Cd SuperlatticesK.N. Alekseev: Permanent address: Department of Physical Sciences, P.O. Box 3000, University of Oulu FIN-90014, Finland. 相似文献
947.
An experimental apparatus and related procedures for the determination of the effective thermal conductivity of sintered powder-metal
plates saturated with distilled water at temperatures in the range 20–150°C are discussed. The apparatus and procedures are
applied to two samples of sintered powder-metal plates, one made of nickel 200 and the other of stainless steel 316, with
porosities of 28.10 and 46.45%, respectively, and each of nominal dimensions 127 mm × 127 mm × 6.35 mm. The experimental
results are compared with corresponding predictions yielded by several correlations available in the literature. The correlations
based on experimental data for packed beds of spherical particles and also porous plates made of cold-pressed (but not sintered)
particles of angular shapes do not apply well to sintered powder-metal plates. A new correlation, which is based on extensions
of ideas contained in earlier works and provides improved predictions, is proposed. 相似文献
948.
Grafov B. M. Davydov A. D. Damaskin B. B. Lazorenko-Manevich R. M. 《Russian Journal of Electrochemistry》2003,39(4):439-440
Russian Journal of Electrochemistry - 相似文献
949.
950.
L. G. Smirnova Yu. B. Grunin S. V. Krasil'nikova M. A. Zaverkina D. R. Bakieva E. V. Smirnov 《Colloid Journal》2003,65(6):778-781
The pulsed NMR, isopiestic and pycnometric methods are applied to investigate the physicochemical properties of softwood [GOST (State Standard) 9571-89] and hardwood [GOST 28172-89] celluloses, as well as flax cellulose [GOST 10330-76, 9394-76], both in the initial state and subjected to chemical treatment. Possible changes occurring in the supramolecular structure of a polymer are analyzed. The structural and sorption characteristics of the investigated samples are calculated. Their water absorption capacities are determined. 相似文献