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851.
The 2D Rancieite type manganic acid was prepared by reduction of KMnO4 in acidic medium. Its ion exchange behavior allows to prepare alkali derivatives. All compounds were characterized with use of a combination of X-ray diffraction, chemical analyses, TGA, magnetic measurements and spectroscopic techniques. The evolution of their chemical composition versus temperature was studied between 180 and 400 °C. It shows that the dehydration process is partly reversible in these compounds whereas the weak reduction is irreversible. The 2D Rancieite-type manganic acid is readily different from a Birnessite-type phyllomanganate, as shown by several features: the interlayer distance, the ion exchange capacity, the thermal behavior, the interlayer cation content, the manganese average oxidation state, the magnetic behavior and the IR spectrum. 相似文献
852.
W. A. Rodrigues Jr. Q. A. G. de Souza J. Vaz Jr. P. Lounesto 《International Journal of Theoretical Physics》1996,35(9):1849-1900
In this paper we study Dirac-Hestenes spinor fields (DHSF) on a four-dimensional Riemann-Cartan spacetime (RCST). We prove that these fields must be defined as certain equivalence classes of even sections of the Clifford bundle (over the RCST), thereby being certain particular sections of a new bundle named the spin-Clifford bundle (SCB). The conditions for the existence of the SCB are studied and are shown to be equivalent to Geroch's theorem concerning the existence of spinor structures in a Lorentzian spacetime. We introduce also the covariant and algebraic Dirac spinor fields and compare these with DHSF, showing that all three kinds of spinor fields contain the same mathematical and physical information. We clarify also the notion of (Crumeyrolle's) amorphous spinors (Dirac-Kähler spinor fields are of this type), showing that they cannot be used to describe fermionic fields. We develop a rigorous theory for the covariant derivatives of Clifford fields (sections of the Clifford bundle, CB) and of Dirac-Hestenes spinor fields. We show how to generalize the original Dirac-Hestenes equation in Minkowski spacetime for the case of RCST. Our results are obtained from a variational principle formulated through the multiform derivative approach to Lagrangian field theory in the Clifford bundle. 相似文献
853.
854.
G. Carelli N. Ioli A. Messina A. Moretti S. Schepis F. Strumia 《International Journal of Infrared and Millimeter Waves》1998,19(9):1191-1199
We measured the dependence of the reflectivity of InSb crystals upon temperature in the submillimeter region using monochromatic radiation from an optically pumped far infrared (FIR) laser. The measures allowed us to determine the value of the electron effective mass at low temperatures with radiations of different frequencies. Our measurements extend the results obtained recently on pure crystals with magneto-optical methods to the low temperatures region where only old measures were available. 相似文献
855.
DAndrea A. Tomassini N. Ferrari L. Righini M. Selci S. Bruni M. R. Simeoni G. 《Il Nuovo Cimento D》1995,17(11):1423-1427
Il Nuovo Cimento D - Normalized reflection spectra in GaInAs/GaAs quantum wells are shown for two sets of samples with different alloy concentration (x=9% and 18.5%) and well thickness ranging from... 相似文献
856.
In this paper we describe a method for separating a combination of a chaotic time series and a discrete-valued signal. The method uses a feedback technique stabilised using knowledge of the chaotic system and the discrete nature of the signal. It is not based on a linearization of the dynamics, and therefore, unlike previously proposed separation methods, does not require that the signal be small. Nor does it make any assumptions about the relative timescales of the signal and the chaotic time series. 相似文献
857.
Robert W. Baker Geoffrey R. Pocock Melvyn V. Sargent Edi Twiss 《Tetrahedron: Asymmetry》1993,4(12):2423-2426
Introduction of a 2-isopropoxycarbonyl or 2-NN-dimethylcarbamoyl group into homochiral 1-p-tolyl- or 1-t-butyl-sulfinylnaphthalenes, via directed metalation reaction, followed by ligand coupling reaction with 1-naphthylmagnesium bromide, furnished atropisomeric 1,1′-binaphthyls in 82–95% enantiomeric excess (e.e.). 相似文献
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