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991.
Uyen Tu Thi Doan Duy Khanh Le Truong Lam Huynh Tung Thanh Ngo Trieu Quang Vo Dr. Minh Thu Tran Thi Anh Tuan Thanh Pham Vinh Cao Tran Phuong Tuyet Nguyen Ngoc Kim Pham 《Chemphyschem》2023,24(18):e202300210
In this study, the features of resistive random access memory (RRAM) employing a straightforward Cr/MAPbI3/FTO three-layer structure have been examined and clarified. The device displays various resistance switching (RS) behavior at various sweep voltages between 0.5 and 5 V. The RS effect has a conversion in the direction of the SET and RESET processes during sweeping for a number of cycles at a specific voltage. The directional change of the RS processes corresponds to the dominant transition between the generation/recombination of iodide ion and vacancy in the MAPbI3 perovskite layer and the electrochemical metallization of the Cr electrode under the influence of an electric field, which results in the conductive filament (CF) formation/rupture. At each stage, these processes are controlled by specific charge conduction mechanisms, including Ohmic conduction, space-charge-limited conduction (SCLC), and variable-range hopping (VRH). By identifying the biased voltage and the quantity of voltage sweep cycles, one can take a new approach to control or modulate the pathways for effective charge transport. This new approach is made possible by an understanding of the RS characteristics and the corresponding mechanisms causing the variation of RS behavior in the structure. 相似文献
992.
Jui Hung Chen Chi‐An Dai Wen‐Yen Chiu 《Journal of polymer science. Part A, Polymer chemistry》2008,46(5):1662-1673
Poly(3,4‐ethylenedioxythiophene)s (PEDOT) represent a class of conjugated polymers that can be potentially used as an electrode material for flexible organic electronics due to their superior conductivity and transparency. In this study, we demonstrate that the conductivity of a PEDOT containing copolymer film can be further enhanced by the oxidative chemical in situ copolymerization of a liquid film spun coated from monomer mixture (3,4‐ethylenedioxythiophene (EDOT) and 3‐thienyl ethoxybutanesulfonate (TEBS)), oxidant (iron(III) p‐toluenesulfonate (Fe(OTs)3)), weak base (imidazole), and solvent (methanol). We investigated that the effect of the processing parameters such as the molar ratios TEBS/EDOT, IM/EDOT, and Fe(OTs)3/EDOT on the surface morphology, optical property, and the conductivity of the resulting copolymer films. These parameters have been optimized to achieve conductivities for the copolymer films as high as 170 S/cm compared with a conductivity of 30 S/cm for the pure PEDOT film synthesized using the same fabrication method. This conductivity enhancement for the copolymer films was found to be resulted from the fact that the addition of TEBS monomer reduces the copolymerization rate, leading to the formation of much more uniform film surface without defects and copolymers of higher molecular weight which increase the conductivity of the resulting copolymer film. The composition of two monomers in the copolymer film is not related to the variation of conductivity. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 1662–1673, 2008 相似文献
993.
Kwo Ray Chu Han-Ying Chen Chien-Lung Hung Tsun-Hsu Chang Barnett L.R. Shih-Hung Chen Tz-Te Yang Dialetis D.J. 《IEEE transactions on plasma science. IEEE Nuclear and Plasma Sciences Society》1999,27(2):391-404
Physics and technology issues of importance to the high-gain gyrotron traveling wave amplifier (gyro-TWT) are investigated in theory and experiment. The gyro-TWT is known to be highly susceptible to spurious oscillations, especially in high gain operations. In the current study, oscillations of various origins are classified and characterized with detailed theoretical modeling. They are shown to be intricately connected to the interplay between the absolute/convective instabilities, circuit losses, and reflective feedback. Knowledge of these processes leads to the concept of an ultra high gain scheme which employs distributed wall losses for the suppression of spurious oscillations. A proof-of-principle Ka-band gyro-TWT experiment stable at zero drive has produced 93 kW saturated peak power at 26.5% efficiency and 70 dB gain, with a 3 dB saturated output power bandwidth of 3 GHz. The saturated gain is more than 30 dB beyond that previously achieved 相似文献
994.
Hung‐Yi Lin Guey‐Sheng Liou Wen‐Ya Lee Wen‐Chang Chen 《Journal of polymer science. Part A, Polymer chemistry》2007,45(9):1727-1736
A new high‐molecular‐weight poly(triarylamine), poly[di(1‐naphthyl)‐4‐anisylamine] (PDNAA), was successfully synthesized by oxidative coupling polymerization from di(1‐naphthyl)‐4‐anisylamine (DNAA) with FeCl3 as an oxidant. PDNAA was readily soluble in common organic solvents and could be processed into freestanding films with high thermal decomposition and softening temperatures. Cyclic voltammograms of DNAA and PDNAA exhibited reversible oxidative redox couples at the potentials of 0.85 and 0.85 V, respectively, because of the oxidation of the main‐chain triarylamine unit. This suggested that PDNAA is a hole‐transporting material with an estimated HOMO level of 5.19 eV. The absorption maximum of a PDNAA film appeared at 370 nm, with an estimated band gap of 2.86 eV from the absorption edge. Unusual multiple photoluminescence maxima were observed at 546 nm, and this suggested its potential application in white‐light‐emission devices. Nearly white‐light‐emission devices could be obtained with either a bilayer‐structure approach {indium tin oxide/poly(ethylenedioxythiophene):poly(styrene sulfonate)/PDNAA/poly[2,7‐(9,9‐dihexylfluorene)] (PF)/Ca} or a polymer‐blend approach (PF/PDNAA = 95:5). The luminance yield and maximum external quantum efficiency of the light‐emitting diode with the PF/PDNAA blend as the emissive layer were 1.29 cd/A and 0.71%, respectively, and were significantly higher than those of the homopolymer. This study suggests that the PDNAA is a versatile material for electronic and optoelectronic applications. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 1727–1736, 2007 相似文献
995.
996.
The bilinear transformation is used to establish a direct relationship between a discrete-time algebraic Riccati inequality (DARI) and an associated continuous-time algebraic Riccati inequality (CARI). It is shown that under mild conditions, the DARI is solvable if and only if the corresponding CARI is solvable. The relationship between the DARI and the CARI is then used to translate the general solvability conditions for a CARI given by Scherer into analogous conditions for the DARI. It is shown how such conditions can be applied to determine the solvability of a discrete-time H∞ control problem whose solution set is characterized by two DARIs. 相似文献
997.
Ching Hsuan Lin Chu Nan Hsiao Chun Hung Li Chun Shan Wang 《Journal of polymer science. Part A, Polymer chemistry》2004,42(16):3986-3995
A 2,6‐dimethylphenol‐dipentene dicyanate ester ( DPCY ) was synthesized from the reaction of 2,6‐dimethylphenol‐dipentene adduct and cyanogen bromide. The proposed structure was confirmed by Fourier transform infrared (FTIR), elemental analysis, mass, and nuclear magnetic resonance (NMR) spectra. DPCY was then cured by itself or cured with bisphenol A dicyanate ester ( BADCY ). Thermal properties of cured epoxy resins were studied using differential scanning calorimetry (DSC), dynamic mechanical analysis (DMA), dielectric analysis (DEA), and thermogravimetric analysis (TGA). These data are compared with those of BADCY . The cured DPCY exhibits a lower dielectric constant (2.61 at 1 MHz), dissipation factor (29.3 mU at 1 MHz), thermal stability (5% degradation temperature and char yield are 429 °C and 17.64%, respectively), glass transition temperature (246 °C by TMA and 258 °C by DMA), coefficient of thermal expansion (33.6 ppm before Tg and 134.1 ppm after Tg), and moisture absorption (0.95% at 48 h) than those of BADCY , but higher moduli (5.12 GPa at 150 °C and 4.60 GPa at 150 °C) than those of the bisphenol A system. The properties of cured cocyanate esters lie between cured BADCY and DPCY , except for moduli. Moduli of some cocyanate esters are even higher than those of cured BADCY and DPCY . A positive deviation from the Fox equation was observed for cocyanate esters. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 3986–3995, 2004 相似文献
998.
The core-modified 5,20-phenyl-10,15-tolyl-thia-p-benziporphyrin (SBzP) can be prepared from the condensation of 1,4-bis(α-hydroxyl-benzyl)benzene with 5,10-ditolyl-16-thia-5,10,15,17-tetrahydrotripyrrin using BF3·OEt2 as catalyst. Spectroscopic studies suggest an aromatic macrocycle with a rapid flipping phenylene ring. SBzP exhibits a tilted phenylene ring and crystal packing shows dimeric structure with two SBzP rings linked by hydrogen bonding and π-π interaction. TFA acidified SBzPH22+ has a saddle-shaped dication porphyrin ring with two solvated trifluoroacetate and two solvated trifluoroacetic acid linked by hydrogen bondings. 相似文献
999.
Albert Y. C. Hung 《Journal of Polymer Science.Polymer Physics》2003,41(7):679-686
The effect of the repeated unit length on the substantially increasing molecular motion and entropy change (?TΔSm) of polymer blends was investigated with solid‐state 13C NMR and differential scanning calorimetry within a miscible window. The hydrogen‐bonding strength, from the formation of the phenolic–polyester interaction, was not high enough to overcome the breaking‐off of the self‐association of the phenolic. With respect to the increasing repeated unit length, the polyester resonance intensity of the solid‐state 13C NMR spectra was weakened because of the reduction in the cross‐polarization efficiency in highly mobile samples. The glass‐transition temperature of the blend and the proton spin–lattice relaxation time from NMR experiments were also reduced. The effect of the reduced hydrogen‐bonding strength on blending brought about a tendency of higher entropy (?TΔSm) and higher molecular mobility of the blend. Accordingly, poly(decamethylene adipate) possessed the longest repeated unit length and exhibited the most mobile one in this phenolic/polyester blend family. The molecular segmental motion and entropy progressively increased while the repeated unit length of the guest polymers increased within a miscible window. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 679–686, 2003 相似文献
1000.
Zhengchun Xu Yueguang Jiao Shien-Kuei Liaw Fu-Chun Hung TAO Qin Hanyi Zhang Yili Guo Xiaoping Zheng 《光学学报》2003,23(Z1)
Two array waveguide grating (AWGs) based fiber ring lasers are experimentally demonstrated. Either of them achieves wavelength discrete tuning of 32 nm, or yields simultaneously lasing up to four channels with -7 dBm output power for each channel. 相似文献