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791.
13C NMR study of the reaction between 3-isopropyl indene and trifluoromethane sulfonic acid in methylene chloride solution at ?70° shows the presence of 1-isopropyl indanyl cation. Proposed assignments of the chemical shifts show charge delocalisation due to the aromatic ring. 相似文献
792.
Hung I Macdonald CL Schurko RW 《Chemistry (Weinheim an der Bergstrasse, Germany)》2004,10(23):5923-5935
The correlation between anisotropic 9Be NMR (quadrupolar and chemical shielding) interactions and the structure and dynamics in [Cp2Be], [Cp2*Be], and [(C5Me4H)2Be] is examined by solid-state 9Be NMR spectroscopy, as well as by ab initio and hybrid density functional theory calculations. The 9Be quadrupole coupling constants in the three compounds correspond well to the relative degrees of spherical ground-state electronic symmetry of the environment about beryllium. Theoretical computations of NMR interaction tensors are in excellent agreement with experimental values and aid in understanding the origins of NMR interaction tensors and their correlation to molecular symmetry. Variable-temperature (VT) 9Be and 13C NMR experiments reveal a highly fluxional structure in the condensed phase of [Cp2Be]. In particular, the pathway by which the Cp rings of [Cp2Be] 'invert' coordination modes is examined in detail using hybrid density functional theory in order to inspect variations of the 9Be NMR interaction tensors. The activation energy for the 'inversion' process is found to be 36.9 kJ mol(-1) from chemical exchange analysis of 13C VT CP/MAS NMR spectra. The low-temperature (ca. -100 degrees C) X-ray crystal structures of all three compounds have been collected and refined, and are in agreement with previously reported structures. In addition, the structure of the same Cp2Be crystal was determined at 20 degrees C and displays features consistent with increased intramolecular motion, supporting observations by 9Be VT NMR spectroscopy. 相似文献
793.
[C(4)H(3)N(CH(2)NMe(2))-2]AlMe(2) (1) is prepared in 88% yield by the reaction of substituted pyrrole [C(4)H(4)N(CH(2)NMe(2))-2] with 1 equiv of AlMe(3) in methylene chloride. Reaction of compound 1 with 1 equiv of phenyl isocyanate in toluene generates a seven-membered cycloaluminum compound [C(4)H(3)N[CH(2)NPh(CONMe(2))]-2] AlMe(2) (2). The phenyl isocyanate was inserted into the aluminum and dimethylamino nitrogen bond and induced an unusual rearrangement which results in C-N bond breaking and formation. A control experiment shows that the reaction of substituted pyrrole [C(4)H(4)N(CH(2)NMe(2))-2] with 1 equiv of phenyl isocyanate in diethyl ether yields a pyrrolyl attached urea derivative [C(4)H(3)N(CH(2)NMe(2))-2-[C(=O)NHPh]-1] (3). The demethanation reaction of AlMe(3) with 1 equiv of 3 in methylene chloride at 0 degrees C afforded O-bounded and N-bounded aluminum dimethyl compounds [C(4)H(3)N(CH(2)NMe(2))-2-[C(=O)NPh]-1]AlMe(2) (4a) and [C(4)H(3)N(CH(2)NMe(2))-2-[CO(=NPh)]-1]AlMe(2) (4b) in a total 78% yield after recrystallization. Both 4a and 4b are observed in (1)H NMR spectra; however, the relative ratio of 4a and 4b depends on the solvent used. Two equivalents of AlMe(3) was reacted with 3 in methylene chloride to yield a dinuclear aluminum compound AlMe(3)[C(4)H(3)N(CH(2)NMe(2))-2-[C(=O)NPh]-1] AlMe(2) (5). Reaction of 5 with another equivalent of ligand 3 results in the re-formation of compounds 4a and 4b. 相似文献
794.
The reaction of 1,3-diphenylbarbituric and 1,3-diphenyl-2-thiobarbituric acids with diazotized sulfaniiimides gives 1,3-diphenylalloxan and 1,3-diphenyl-2-thioalloxan phenylhydrazones.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 9, pp. 1276–1279, September, 1971. 相似文献
795.
Perfluoroolefins reacted with I-Cl and ClSO(3)H under mild conditions to give R(F)CFICF(2)OSO(2)Cl, which could be readily converted into various alpha-iodo-perfluorocarboxylic acid derivatives or telomerized with tetrafluoroethylene to I(CF(2)CF(2))(n)()OSO(2)Cl. Ring-opening reaction of perfluoroalkoxypentafluorocyclopropane with iodine at 240 degrees C produced ICF(2)CF(2)COF, which was quenched by alcohol, water, or NH(3) to give beta-iodo-alpha,alpha,beta,beta-tetrafluorocarboxylic acid derivatives. These functional fluorinated iodides can be used as building blocks for making selectively fluorinated compounds. 相似文献
796.
Armunanto R Schwenk CF Tran HT Rode BM 《Journal of the American Chemical Society》2004,126(8):2582-2587
Structure and dynamics of hydrated Au(+) have been investigated by means of molecular dynamics simulations based on ab initio quantum mechanical molecular mechanical forces at Hartree-Fock level for the treatment of the first hydration shell. The outer region of the system was described using a newly constructed classical three-body corrected potential. The structure was evaluated in terms of radial and angular distribution functions and coordination number distributions. Water exchange processes between coordination shells and bulk indicate a very labile structure of the first hydration shell whose average coordination number of 4.7 is a mixture of 3-, 4-, 5-, 6-, and 7-coordinated species. Fast water exchange reactions between first and second hydration shell occur, and the second hydration shell is exceptionally large. Therefore, the mean residence time of water molecules in the first hydration shell (5.6 ps/7.5 ps for t*= 0.5 ps/2.0 ps) is shorter than that in the second shell (9.4 ps/21.2 ps for t*= 0.5 ps/2.0 ps), leading to a quite specific picture of a "structure-breaking" effect. 相似文献
797.
[reaction: see text] Introduction of a sugar unit at either the O5 or O6 position of various neamine derivatives in excellent selectivity and yields is described here. Application to the synthesis of kanamycin analogues is also highlighted. 相似文献
798.
Ong SY Zhu P Poon YF Leung KH Fang WH Phillips DL 《Chemistry (Weinheim an der Bergstrasse, Germany)》2002,8(9):2163-2171
We report time-resolved resonance Raman spectra for 2-fluorenylnitrene and its dehydroazepine products acquired after photolysis of 2-fluorenylnitrene in acetonitrile. The experimental Raman band frequencies exhibit good agreement with the calculated vibrational frequencies from UBPW91/cc-PVDZ density functional calculations for the singlet and triplet states of the 2-fluorenylnitrene as well as BPW91/cc-PVDZ calculations for the two dehydroazepine ring-expansion product species. The decay of the 2-fluorenylnitrene Raman signal and the appearance of the dehydroazepine products suggest the presence of an intermediate species (probably an azirine) that does not absorb very much at the 416 nm probe wavelength used in the time-resolved resonance Raman experiments. Comparison of the singlet 2-fluorenylnitrene species with the singlet 2-fluorenylnitrenium ion species indicates that protonation of the nitrene to give the nitrenium ion leads to a significant enhancement of the cyclohexadienyl character of the phenyl rings without much change of the C-N bond length. 相似文献
799.
[reaction: see text] A highly regioselective borane-reductive ring opening of the 4,6-O-benzylidene-D-hexopyranosides to the corresponding 6-alcohols in excellent yields at room temperature via various metal trifluoromethanesulfonates as catalysts is described here. Its application in the synthesis of 1,4-dideoxy-1,4-imino-L-xylitol is also highlighted. 相似文献
800.
The synthesis of monodispersed Ag nanosphere particles from silver nitrite in ethylene glycol at room temperature essentially promoted with the use of an electrochemical method was demonstrated. Poly(N-vinylpyrrolidone) (PVP) behaves electrochemically stable and facilitates the formation of well-defined Ag nanospheres of average size in the range of 11 nm. Further characterization by high-resolution transmission electron microscopy (HRTEM) image and nano-beam electron diffraction (NBED) pattern indicate that the growth direction of Ag nanosphere particles is the 1 1 1 direction. The time evolution of absorption spectra by UV–Vis spectroscopy illustrates that silver nanoparticles in the electrolyte increase rapidly upon electrochemical process. 相似文献