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61.
In this report, it is demonstrated that chiral vinyl aziridines can be stereospecifically ring expanded. This synthetic approach allows controlled access to chiral 2,5-cis- or 2,5-trans-3-pyrroline products from starting materials with the appropriate aziridine geometry. Twenty three ring expansion examples, most of which feature a stereospecific cyclization, are presented. 相似文献
62.
Mauricio Firmino Silva Lima 《Applied mathematics and computation》2011,217(24):9985-9996
The subject of this paper concerns with the bifurcation of limit cycles and invariant cylinders from a global center of a linear differential system in dimension 2n perturbed inside a class of continuous and discontinuous piecewise linear differential systems. Our main results show that at most one limit cycle and at most one invariant cylinder can bifurcate using the expansion of the displacement function up to first order with respect to a small parameter. This upper bound is reached. For proving these results we use the averaging theory in a form where the differentiability of the system is not needed. 相似文献
63.
Leopoldo Eduardo Cárdenas-Barrón Hui-Ming Wee Mauricio F. Blos 《Mathematical and Computer Modelling》2011,53(5-6):991-997
In the past, economic order quantity (EOQ) and economic production quantity (EPQ) were treated independently from the viewpoints of the buyer or the vendor. In most cases, the optimal solution for one player was non-optimal to the other player. In today’s competitive markets, close cooperation between the vendor and the buyer is necessary to reduce the joint inventory cost and the response time of the vendor–buyer system. The successful experiences of National Semiconductor, Wal-Mart, and Procter and Gamble have demonstrated that integrating the supply chain has significantly influenced the company’s performance and market share (Simchi-Levi et al. (2000) [1]). Recently, Yang et al. (2007) [2] presented an inventory model to determine the economic lot size for both the vendor and buyer, and the number of deliveries in an integrated two stage supply chain. In this paper, we present an alternative approach to determine the global optimal inventory policy for the vendor–buyer integrated system using arithmetic–geometric inequality. 相似文献
64.
Saraví Cisneros H Erben MF Della Védova CO Laurella S Allegretti PE Furlong JJ 《European journal of mass spectrometry (Chichester, England)》2011,17(2):125-143
Tautomerism of some nitriles has been studied by mass spectrometry. The analysis of the corresponding mass spectra has allowed to assign some fragmentations to specific tautomers and to determine heats of tautomerization through temperature effects and electron energy studies. Experimental determinations are supported by theoretical calculations. The joint analysis of mass spectrometry and DFT-B3LYP data indicate that this tautomeric equilibrium can be studied by the experimental spectrometric strategy employed. 相似文献
65.
José Fernando Gonçalves Mauricio G. C. Resende Jorge J. M. Mendes 《Journal of Heuristics》2011,17(5):467-486
This paper presents a biased random-key genetic algorithm for the resource constrained project scheduling problem. The chromosome
representation of the problem is based on random keys. Active schedules are constructed using a priority-rule heuristic in
which the priorities of the activities are defined by the genetic algorithm. A forward-backward improvement procedure is applied
to all solutions. The chromosomes supplied by the genetic algorithm are adjusted to reflect the solutions obtained by the
improvement procedure. The heuristic is tested on a set of standard problems taken from the literature and compared with other
approaches. The computational results validate the effectiveness of the proposed algorithm. 相似文献
66.
Huddling is a grouping behavior where animals maintain close bodily contact and save energy. We tested the hypothesis that this thermoregulatory behavior behaves as a system with continuous (second‐order phase) transition called critical when the environmental temperature (driving parameter) is near a critical value. To do so, we followed theoretical and experimental approaches, examining data from geometrical models, metabolic rate during huddling in small mammals, and also conducting an experiment on thermoregulatory huddling behavior with white mice. Our results support all predictions for systems under continuous‐phase transition triggered by low temperatures, a phenomenon reported for first time in a biological system. We suggest that huddling behavior in social animals, a recognized adaptive behavior, may be considered a self‐organized system coupled with an external driving parameter. © 2011 Wiley Periodicals, Inc. Complexity, 2011 相似文献
67.
Richard S. Barr Bruce L. Golden James P. Kelly Mauricio G. C. Resende William R. Stewart Jr. 《Journal of Heuristics》1995,1(1):9-32
This article discusses the design of computational experiments to test heuristic methods and provides reporting guidelines
for such experimentation. The goal is to promote thoughtful, well-planned, and extensive testing of heuristics, full disclosure
of experimental conditions, and integrity in and reproducibility of the reported results. 相似文献
68.
Pickering emulsions with controllable stability 总被引:1,自引:0,他引:1
We prepare solid-stabilized emulsions using paramagnetic particles at an oil/water interface that can undergo macroscopic phase separation upon application of an external magnetic field. A critical field strength is found for which emulsion droplets begin to translate into the continuous-phase fluid. At higher fields, the emulsions destabilize, leading to a fully phase-separated system. This effect is reversible, and long-term stability can be recovered by remixing the components with mechanical agitation. 相似文献
69.
70.
Raimund Bü rger Aní bal Coronel Mauricio Sepú lveda. 《Mathematics of Computation》2006,75(253):91-112
We prove the convergence of a semi-implicit monotone finite difference scheme approximating an initial-boundary value problem for a spatially one-dimensional quasilinear strongly degenerate parabolic equation, which is supplied with two different inhomogeneous flux-type boundary conditions. This problem arises in the modeling of the sedimentation-consolidation process. We formulate the definition of entropy solution of the model in the sense of Kru kov and prove convergence of the scheme to the unique entropy solution of the problem, up to satisfaction of one of the boundary conditions.